Development of innovative carbon-carbon bond forming reactions using triolborate salts
Project/Area Number |
22550092
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Synthetic chemistry
|
Research Institution | Hokkaido University |
Principal Investigator |
YAMAMOTO Yasunori 北海道大学, 大学院・工学研究院, 特任准教授 (30271646)
|
Project Period (FY) |
2010 – 2012
|
Project Status |
Completed (Fiscal Year 2012)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | 選択的合成・反応 / 有機ホウ素化学 / 遷移金属触媒反応 / 有機トリオールボレート塩 / 有機ホウ素化合物 / 機能材料開発 / クロスカップリング / 不斉付加反応 |
Research Abstract |
We have developed ate-complexes, cyclic aryltriolborate salts that haveexceptionally high levels of stability in air and water and reasonable solubility in organic solvents. Wehave newly synthesized heteroaryltriolborate salts for palladium-catalyzed cross-coupling reactions,copper-catalyzed N-arylation reactions, and catalyzed asymmetric addition reactions.
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Report
(4 results)
Research Products
(88 results)