Studies on the Regioselective Carbon-Carbon Formation Reactions via the Vinylidenemetal Comlexes as a Key Intermediate
| Project/Area Number |
22550100
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
FUKUMOTO Yoshiya 大阪大学, 工学(系)研究科(研究院), 准教授 (50273595)
|
|---|
| Project Period (FY) |
2010-04-01 – 2013-03-31
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
|---|
| Keywords | ビニリデン金属錯体 / 炭素－炭素結合生成 / レニウム / 末端アルキン / イミン / アリルアミン / レニウム触媒 / ロジウム錯体 / ヒドラゾン / ニトリル / 炭素-炭素結合生成 / レジオ選択的反応 / ビニリデン金属錯 / 水素移動 |
|---|
| Research Abstract |
I have studied the new carbon-carbon bond reactions via the formation of the vinylidenemetal complex as a key intermediate. For example, I found the reaction of terminal alkynes with imines in the presence of rhenium complex as a catalyst leading to the formation of allylamines. Mechanistic studies for the present reaction were consistent with the proposed reaction mechanism involving the vinylidenerhenium intermediate.
|
Report
(4 results)
Research Products
(36 results)
