Synthesis of Sulfur-Containing Fused Heteroaromatic Compounds via Oxidative Coupling
| Project/Area Number |
22550101
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
SATOH Tetsuya 大阪大学, 大学院・工学研究科, 准教授 (40273586)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
|
|---|
| Keywords | 縮合へテロ環 / π共役分子 / 酸化的カップリング / 炭素-水素結合活性化 / ルテニウム触媒 / ロジウム触媒 / パラジウム触媒 / 炭素―水素結合切断 / 縮合環形成 / パイ共役分子合成 / 炭素-水素結合切断 / アルケニル化 / π共役分子合成 |
|---|
| Research Abstract |
The oxidative coupling reactions of various aromatic substrates with alkynes and alkenes under transition-metal catalysis such as rhodium, palladium, and ruthenium were investigated. As a result, I succeeded in finding a number of new coupling reactions involving C-H bond cleavage. Furthermore, it was successfully shown that a wide range of sulfu- or other heteroatom-containing fused heteroaromatic compounds can be efficiently prepared by using these new reactions.
|
Report
(4 results)
Research Products
(42 results)
