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Development of high performance transparent organic redox couples for increasing conversion efficiency of white see-through dye sensitized solar cells

Research Project

Project/Area Number 22550171
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionGifu University

Principal Investigator

FUNABIKI Kazumasa  岐阜大学, 工学部, 准教授 (50273123)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords色素増感型太陽電池 / 有機レドックス対 / 近赤外吸収色素 / チオール / ヨウ素フリーレドックス対 / 有機色素 / 有機電解質
Research Abstract

Transparent organic redox couples which have a great advantages, such as low sublimation, low corrosiveness, and transparent, are essential for white see-through dye sensitized solar cells (DSSC). However, the use of the organic redox couples resulted in decreasing conversionefficiency of the DSSC. In this study, high performance transparent organic redox couples have been developed for increasing conversionefficiency of white see-through DSSC.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (26 results)

All 2013 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (11 results) Remarks (1 results) Patent(Industrial Property Rights) (9 results) (of which Overseas: 2 results)

  • [Journal Article] Design of NIR-Absorbing Simple Asymmetrical Squaraine Dyes Carrying Indoline Moieties for Use in Dye-Sensitized Solar Cells with Pt-Free Electrodes2012

    • Author(s)
      K. Funabiki, H. Mase, Y. Saito, A. Otsuka, A. Hibino, N. Tanaka, H. Miura, Y. Himori, T. Yoshida, Y. Kubota, M. Matsui
    • Journal Title

      Org. Lett

      Volume: 14, No. 5 Pages: 1246-1249

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design of NIR-Absorbing Simple Asymmetrical Squaraine Dyes Carrying Indoline Moieties for Use in Dye-Sensitized Solar Cells with Pt-Free Electrodes2012

    • Author(s)
      K.Funabiki, H.Mase, Y.Saito, A.Otsuka, A.Hibino, N.Tanaka, H.Miura, Y.Himori, T.Yoshida, Y.Kubota, M.Matsui
    • Journal Title

      Organic Letters

      Volume: 14 Pages: 1246-1249

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a novel heptamethine-cyanine dye for use innear-infrared active dye-sensitized solar cells with porous zinc oxide prepared at low temperature2011

    • Author(s)
      K. Funabiki, H. Mase, A. Hibino, N. Tanaka, N. Mizuhata, Y. Sakuragi, A. Nakashima, T. Yoshida, Y. Kubota, M. Matsui
    • Journal Title

      Energ. Environ. Sci.

      Volume: vol.4, No.6 Pages: 2186-2192

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Anchoring Groups on Electrochemical Self-assembly of ZnO/xanthene Dye Hybrid Thin Film2010

    • Author(s)
      J.Zhang, L.Sun, K.Ichinose, K.Funabiki, T.Yoshida
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 12 Pages: 7405-7410

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a Novel Heptamethine-Cyanine Dye for Use in Near-Infrared Active Dye-Sensitized Solar Cells with Porous Zinc Oxide Prepared at Low Temperature

    • Author(s)
      K.Funabiki, H.Mase, A.Hibino, N.Tanaka, N.Mizuhata, Y.Sakuragi, A.Nakashima, T.Yoshida, Y.Kubota, M.Matsui
    • Journal Title

      Energy & Environmental Science

      Volume: (In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機レドックス対を用いた色素増感型太陽電池2013

    • Author(s)
      船曳一正・吉川友悟・土井南美・日比野温彦・齊藤恭輝・窪田裕大・松居正樹
    • Organizer
      日本化学会第93 春季年会、(3B2-35)
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-24
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機レドックス対を用いた色素増感型太陽電池2013

    • Author(s)
      船曳一正(代表者)・吉川友悟・土井南美・日比野温彦・齊藤恭輝・窪田裕大・松居正樹
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学 草津キャンパス
    • Related Report
      2012 Annual Research Report
  • [Presentation] 近赤外光を選択的に吸収する有機色素を用いた色素増感型太陽電池2012

    • Author(s)
      船曳一正、日比野温彦、齊藤恭輝、加藤和幸、窪田裕大、松居正樹
    • Organizer
      日本化学会第92春季年会、(1C4-13)
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 近赤外光を選択的に吸収する有機色素を用いた色素増感型太陽電池2012

    • Author(s)
      船曳一正、日比野温彦、齊藤恭輝、加藤和幸、窪田裕大、松居正樹
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学日吉キャンパス
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 近赤外光を選択的に吸収する5位置換ヘプタメチンシアニン色素の合成とその太陽電池特性2011

    • Author(s)
      船曳一正、日比野温彦、窪田裕大、松居正樹、吉田司、齋藤恭輝、加藤和幸
    • Organizer
      2011 年電気化学秋季大会、p.272(2N01)
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-10
    • Related Report
      2012 Final Research Report
  • [Presentation] 近赤外光吸収色素を用いた色素増感型太陽電池におけるアルキル基の効果2011

    • Author(s)
      船曳一正、田中なぎさ、水畑紀子、窪田裕大、松居正樹、吉田司、齋藤恭輝、加藤和幸
    • Organizer
      2011 年電気化学秋季大会、p.272(2N-02)
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-10
    • Related Report
      2012 Final Research Report
  • [Presentation] 各種アルキル基を有する近赤外吸収色素を用いた色素増感型太陽電池2011

    • Author(s)
      船曳一正、田中なぎさ、水畑紀子、窪田裕大、松居正樹、吉田司、齋藤恭輝、加藤和幸
    • Organizer
      日本化学会第91 春季年会、p.108、2G5‐42
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 近赤外光を吸収する5位置換ヘプタメチンシアニン色素の合成とその太陽電池性能2011

    • Author(s)
      船曳一正、日比野温彦、窪田裕大、松居正樹、吉田司、齋藤恭輝、加藤和幸
    • Organizer
      日本化学会第91 春季年会、p.108、2G5‐43
    • Place of Presentation
      神奈川
    • Year and Date
      2011-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 各種アルキル基を有する近赤外吸収色素を用いた色素増感型太陽電池2011

    • Author(s)
      船曳一正、田中なぎさ、水畑紀子、窪田裕大、松居正樹、吉田司、齋藤恭輝、加藤和幸
    • Organizer
      日本化学会 第91回春季年会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 近赤外光を吸収する5位置換ヘプタメチンシアニン色素の合成とその太陽電池性能2011

    • Author(s)
      船曳一正、日比野温彦、窪田裕大、松居正樹、吉田司、齊藤恭輝、加藤和幸
    • Organizer
      日本化学会 第91回春季年会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ヘプタメチンシアニン色素の合成と酸化亜鉛色素増感型太陽電池への利用2010

    • Author(s)
      船曳一正、日比野温彦、窪田裕大、松居正樹、吉田司
    • Organizer
      日本化学会第90春季年会、p. 958、2PC-157
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www1.gifu-u.ac.jp/~matsuila/

    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 酸化還元対およびそれを用いた光電変換素子2012

    • Inventor(s)
      齊藤恭輝、日比野温彦、船曳一正
    • Industrial Property Rights Holder
      第一工業製薬(株)、岐阜大学
    • Filing Date
      2012-11-15
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] ヘプタメチン構造を有する化合物、増感色素および光電変換素子2012

    • Inventor(s)
      齊藤恭輝、船曳一正、日比野温彦、田中なぎさ
    • Industrial Property Rights Holder
      第一工業製薬(株)、岐阜大学
    • Filing Date
      2012-03-01
    • Related Report
      2012 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] ヘプタメチン構造を有する化合物、増感色素および光電変換素子2012

    • Inventor(s)
      齊藤恭輝、船曳一正、日比野温彦、田中なぎさ
    • Industrial Property Rights Holder
      第一工業製薬(株)、岐阜大学
    • Filing Date
      2012-02-08
    • Related Report
      2012 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子に用いられる増感色素と該増感色素が用いられた色素増感型太陽電池2012

    • Inventor(s)
      船曳一正、松居正樹、吉田司、大塚淳弘
    • Industrial Property Rights Holder
      岐阜大学、積水樹脂(株)
    • Acquisition Date
      2012-12-14
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子に用いられる増感色素と該増感色素が用いられた色素増感型太陽電池2012

    • Inventor(s)
      船曳一正、松居正樹、吉田司、大塚淳弘
    • Industrial Property Rights Holder
      岐阜大学、積水樹脂(株)
    • Acquisition Date
      2012-08-17
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 色素増感型光電変換素子に用いられる増感色素と該増感色素が用いられた色素増感型太陽電池2012

    • Inventor(s)
      船曳一正、松居正樹、吉田司、杉山直之、大塚淳弘
    • Industrial Property Rights Holder
      岐阜大学、積水樹脂(株)
    • Acquisition Date
      2012-08-10
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 酸化還元対およびそれを用いた光電変換素子2012

    • Inventor(s)
      齊藤恭輝、日比野温彦、船曳一正
    • Industrial Property Rights Holder
      国立大学法人岐阜大学、第一工業製薬株式会社
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012-11-15
    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] ヘプタメチン構造を有する化合物、増感色素および光電変換素子2011

    • Inventor(s)
      齊藤恭輝、船曳一正、日比野温彦、田中なぎさ
    • Industrial Property Rights Holder
      第一工業製薬(株)、岐阜大学
    • Filing Date
      2011-07-06
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] ヘプタメチン構造を有する化合物、増感色素および光電変換素子2011

    • Inventor(s)
      齊藤恭輝、船曳一正、日比野温彦、田中なぎさ
    • Industrial Property Rights Holder
      第一工業製薬(株)、岐阜大学
    • Filing Date
      2011-03-10
    • Related Report
      2012 Final Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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