Preparation and Application of High refractive and TransparentInorganic/Organic Hybrid

• Project/Area Number: 22550199
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Nagasaki University (2011-2012); Kyushu Institute of Technology (2010)
• Principal Investigator: YOSHINAGA Kohji 長崎大学, 大学院・工学研究科, 教授 (00040436)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: 高屈折 / 透明 / ポリマーミセル / ハイブリッド材料 / ナノ粒子 / ブロックポリマー

Research Abstract

Preparation of high transparent and refractive hybrid materials from inorganic nano-particles synthesized in hydrophilic cores of block copolymer micelles in organic solvent was investigated. A convenient and efficient method for the preparation was developed by incorporation of metal oxide nano-particles, synthesized in the polymer micelles, into polymer matrix by casting.

Research Products

• [Journal Article] Effective Dispersion of Fullerene with Methacrylate Copolymer in Organic Solvent and Poly(methyl methacrylate) (2012)
  • Author(s): K.Yoshinaga, S.Motokucho, K.Kojio, A.Nakai
  • Journal Title: Colloid and Polymer Science Volume: 290 Issue: 12 Pages: 1221-6
  • DOI: 10.1007/s00396-012-2707-x
  • Peer Reviewed
• [Journal Article] 材料表面へのポリマーグラフトによる界面制御 (2012)
  • Author(s): 吉永耕二
  • Journal Title: 成形加工 Volume: 24 Pages: 233-235
  • NAID: 130007960498
• [Journal Article] 亜臨界または超臨界二酸化炭素中でのポリウレアのメタノールを用いた分解 (2012)
  • Author(s): 本九町 卓, 向井真吾, 古川睦久, 小椎尾 謙, 吉永耕二
  • Journal Title: 日本ゴム協会誌 Volume: 85(5) Pages: 157-61
  • Peer Reviewed
• [Journal Article] 共重合ポリカーボネートグルコールの側鎖アルキル基含有率がポリウレタンエラストマーの凝集構造と力学的物性へ及ぼす影響 (2012)
  • Author(s): 小椎尾 謙, 古川睦久, 本九町 卓, 溝上元規, 吉永耕二
  • Journal Title: 日本ゴム協会誌 Volume: 85(5) Pages: 151-156
  • Peer Reviewed
• [Journal Article] Basic Discussion for Coating of Epoxy Resin with Carbon Nano-tube Dispersion (2012)
  • Author(s): 小迫雅裕,中津秀行,戸田弘明,山田修平,吉永耕二,匹田政幸,平田大裕,宮本剛寿,武井雅文
  • Journal Title: IEEJ Transactions on Fundamentals and Materials Volume: 132 Issue: 9 Pages: 773-779
  • DOI: 10.1541/ieejfms.132.773
  • NAID: 10031019090
  • ISSN: 0385-4205, 1347-5533
  • Peer Reviewed
• [Journal Article] 共重合ポリカーボネートグリコールの側鎖アルキル基含有率がポリウレタンエラストマーの凝集構造と力学物性へ及ぼす影響 (2012)
  • Author(s): 小椎尾 謙
  • Journal Title: 日本ゴム協会誌 Volume: 85 Pages: 151-156
  • Peer Reviewed
• [Journal Article] 亜臨界または超臨界二酸化炭素中でのポリウレアのメタノールを用いた分解反応 (2012)
  • Author(s): 本九町 卓
  • Journal Title: 日本ゴム協会誌 Volume: 85 Pages: 157-161
  • Peer Reviewed
• [Journal Article] 材料表面へのポリマーグラフトによる界面制御 (2012)
  • Author(s): 吉永 耕二
  • Journal Title: 成形加工 Volume: 24 Pages: 232-234
  • NAID: 130007960498
• [Journal Article] Smultaneous Small-angle X-ray Scattering/Wide-angle X-ray Diffraction Study of the Microdomain Structure of Polyurethane Elastlers during Mechanical Deformation (2011)
  • Author(s): K.Kojio, K.Matsuo, S.Motokucho, K.Yoshinaga, Y.Shimodaira, K.Kimura
  • Journal Title: Polymer Journal Volume: 43 Issue: 8 Pages: 692-9
  • DOI: 10.1038/pj.2011.48
  • Peer Reviewed
• [Journal Article] Effects of Particle Volume Fraction on Distortion of Particle-Arrayed Structure During Immobilization of Colloidal Crystals Formed by Poly(methyl methacrylate)-Grafted Silica in Acetonirile (2011)
  • Author(s): Z.Ma, M.Watanabe, E.Mouri, A.Nakai, K.Yoshinaga
  • Journal Title: Colloid and Polymer Science Volume: 289 Issue: 1 Pages: 85-91
  • DOI: 10.1007/s00396-010-2326-3
  • Peer Reviewed
• [Journal Article] 固体表面へのポリマーグラフトによる界面の制御・創製 (2011)
  • Author(s): 吉永耕二
  • Journal Title: 高分子 Volume: 60 Pages: 661-664
  • NAID: 10029472550
  • URL: http://main.spsj.or.jp/c5/kobunshi/kobunshi.php
• [Journal Article] Incorporation of Titanium Dioxide Particles into Polymer Matrix using Block Copolymer Micelles for Fabrication of High Refractive and Transparent Organic-Inorganic Hybrid Materials (2011)
  • Author(s): S.Yamada, E.Mouri, K.Yoshinaga
  • Journal Title: Journal Polymer Science: Part A Volume: 49 Issue: 3 Pages: 712-8
  • DOI: 10.1002/pola.24483
  • Peer Reviewed
• [Journal Article] 固体表面へのポリマーグラフトによる界面制御・創製 (2011)
  • Author(s): 吉永耕二
  • Journal Title: 高分子 Volume: 60 Pages: 661-664
• [Journal Article] Simultaneous Small-angle X-ray Scattering/Wide-angle X-ray Diffraction Study of the Microdomein Structure of Polyuretane Elastmers during Mechanical Deformation (2011)
  • Author(s): K.Kojio
  • Journal Title: Polymer Journal Volume: 43 Pages: 692-699
  • Peer Reviewed
• [Journal Article] Incorporation of Titanium Dioxide Particles into Polymer Matrix using Block Copolymer Micelles for Fabrication of High Refractive and Transparent Organic-Inorganic Hybrid Materials (2011)
  • Author(s): S.Yamada
  • Journal Title: Journal Polymer Science, Part A Volume: 49 Pages: 712-718
  • Peer Reviewed
• [Journal Article] Effects of Particle Volume Fraction on Distortion of Particle-Arrayed Structure During Immobilization of Colloidal Crystals Formed by Poly(methyl methacrylate)-Grafted Silica in Acetonirile (2011)
  • Author(s): Z.Ma
  • Journal Title: Colloid Polymer Science Volume: 289 Pages: 85-91
  • Peer Reviewed
• [Journal Article] Drying Dissipative Structures of Lycopodium Spore Particles in Aqueous Dispersion (2010)
  • Author(s): T.Okubo, E.Kokufuta, M.Nakamuro, K.Yoshinaga, M.Mizutani, A.Tsuchida
  • Journal Title: Colloids and Surfaces B: Biointerfaces Volume: 80 Pages: 193-9
  • Peer Reviewed
• [Journal Article] Particle Monolayer Formation with Arrayed Structure by PMMA-Gtafted Polystyrene Latex at the Air-Warter Interface (2010)
  • Author(s): E.Mouri, M.Terada, R.Koga, H.Karakawa, K.Yo shinaga
  • Journal Title: Journal of Nanoscience and Nanotechnology Volume: 10 Pages: 5838-46
  • Peer Reviewed
• [Journal Article] Structural Estimation of Particle Arrays at Air-Water Interface Based on Silica Particles with Well-Defined and Highly Grafted Poly(methyl methacrylate) (2010)
  • Author(s): J-M Moon,B-S Kim,H-J Paik,J-O Lee,E.Mouri,K.Yoshinaga
  • Journal Title: Polymer Engineering and Science Volume: 50 Issue: 6 Pages: 1067-74
  • DOI: 10.1002/pen.21639
  • Peer Reviewed
• [Journal Article] Controlled Crystallization of Titanium Dioxide Particles in the Presence of Poly(vinyl alcohol) from Peroxytitanic acid (2010)
  • Author(s): Z.Wang, S.Yamad a, M.Zhang, H.Kanzaki, K.Yoshinaga
  • Journal Title: Colloid and Polymer Science Volume: 288 Issue: 4 Pages: 433-8
  • DOI: 10.1007/s00396-009-2141-x
  • Peer Reviewed
• [Journal Article] Effects of Ferrocenyl Group on Refractive Index of Colloidal Crystal System Formed by Polymer-grafted Silica in Organic Solvent (2010)
  • Author(s): Z.Ma, M.Watanabe, E.Mouri, K.Yoshinaga
  • Journal Title: Colloid and Polymer Science Volume: 288 Issue: 5 Pages: 519-25
  • DOI: 10.1007/s00396-009-2143-8
  • Peer Reviewed
• [Journal Article] Particle Monolayer Formation with Arrayed Structure by PMMA-Gtafted Polystyrene Latex at the Air-Warter Interface (2010)
  • Author(s): E.Mouri
  • Journal Title: Journal of Nanoscience and Nanotechnology Volume: 10 Pages: 5838-5846
  • Peer Reviewed
• [Journal Article] Structural Estimation of Particle Arrays at Air-Water Interface Based on Silica Particles with Well-Defined and Highly Grafted Poly(methyl methacrylate) (2010)
  • Author(s): J-M Moon
  • Journal Title: Polymer Engineering and Science Volume: 50 Pages: 1067-1074
  • Peer Reviewed
• [Journal Article] Drying Dissipative Structures of Lycopodium Spore Particles in Aqueous Dispersion (2010)
  • Author(s): T.Okubo
  • Journal Title: Colloids and Surfaces B : Biointerfaces Volume: 80 Pages: 193-199
  • Peer Reviewed
• [Presentation] ブロックコポリマーの逆ミセル中での無機ナノ粒子の合成とハイブリッド化 (2013)
  • Author(s): 吉永耕二
  • Organizer: ポリウレタンフォーラム(招待講演)
  • Place of Presentation: 長崎
  • Year and Date: 2013-02-01
• [Presentation] ブロックコポリマーの逆ミセル中での無機酸化物ナノ粒子の合成とPMMAとのハイブリッド化 (2012)
  • Author(s): 中村将章, 吉永耕二,他5名
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2012-09-20
• [Presentation] Fabrication of Transparent and High Refractive Index Hybrid Materials Incorporated with Metal Oxide Nano-particles, Formed in Reversible Micelles of Block Copolymer (2012)
  • Author(s): K.Yoshinaga
  • Organizer: Interface 21
  • Place of Presentation: Kyoto
  • Year and Date: 2012-08-07
• [Presentation] 金ナノ粒子/ポリマーグラフトシリカ複合粒子の調製 (2012)
  • Author(s): 吉永耕二,他2名
  • Organizer: 繊維学会年次大会
  • Place of Presentation: 東京
  • Year and Date: 2012-06-07
• [Presentation] ブロックコポリマーの逆ミセル中でのZnOナノ粒子の合成とPMMAとのハイブリッド化 (2012)
  • Author(s): 中村将章, 吉永耕二, 他5名
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2012-05-29
• [Presentation] ブロックコポリマーの逆ミセル中でのZnOナノ粒子の合成とPMMAとのハイブリッド化 (2012)
  • Author(s): 中村 将章
  • Organizer: 第61回高分子年次大会
  • Place of Presentation: 横浜
• [Presentation] 金ナノ粒子／ポリマーグラフトシリカ複合粒子の調製 (2012)
  • Author(s): 吉永 耕二
  • Organizer: 繊維学会年次大会
  • Place of Presentation: 東京
• [Presentation] Fabrication of Transparent and High Refractive Index Hybrid Materials Incorporated with Metal Oxide Nano-particles, Formed in Reversible Micelles of Block Copolymer (2012)
  • Author(s): Kohji Yoshinaga
  • Organizer: Interface 21
  • Place of Presentation: 京都
• [Presentation] Synthesis of ZnO Nanoparticles by Using Micelle of Block Copolymer and Incorporation into PMMA (2011)
  • Author(s): Y.Shimomura, E.Mouri, T.Ohno, K.Yoshinaga
  • Organizer: Pusan-Gyeonhnam/Kyushu-Seibu Joint Symposium on High Polymers(15th) and Fibers(13th)
  • Place of Presentation: Pusan
  • Year and Date: 2011-10-28
• [Presentation] Synthesis of ZnO Nanoparticles by Using Micelle of Block Copolymer and Incorporation into PMMA (2011)
  • Author(s): K.Yoshinaga
  • Organizer: Pusan-Gyeonhnam/Kyushu-Seibu Joint Symposium on High Polymers(15th) and Fibers(13th)
  • Place of Presentation: 釜山大学(韓国)
  • Year and Date: 2011-10-28
• [Presentation] 高分子ミセルを用いたZnOナノ粒子の合成とPMMAとの複合化 (2011)
  • Author(s): 下村侑輝,吉永耕二,他1名
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山
  • Year and Date: 2011-09-30
• [Presentation] 高分子ミセルを用いた酸化ジルコニウム微粒子の合成とPMMAとの複合化 (2011)
  • Author(s): 高原 宰,吉永耕二,他3名
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山
  • Year and Date: 2011-09-30
• [Presentation] 高分子ミセルを用いた酸化ジルコニウム微粒子の合成とPMMAとの複合化 (2011)
  • Author(s): 吉永耕二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学(岡山)
  • Year and Date: 2011-09-30
• [Presentation] 高分子ミセルを用いたZnOナノ粒子の合成とPMMAとの複合化 (2011)
  • Author(s): 吉永耕二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学(岡山)
  • Year and Date: 2011-09-30
• [Presentation] 高分子ミセルを用いたZnO/PMMAハイブリッドフィルムの作製 (2011)
  • Author(s): 下村侑輝,吉永耕二,他1名
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪
  • Year and Date: 2011-05-25
• [Presentation] 高分子ミセルを用いたZnO/PMMAハイブリッドフィルムの作製 (2011)
  • Author(s): 吉永耕二
  • Organizer: 第60回高分子学会年次大会
  • Place of Presentation: 大阪国際会議場(大阪)
  • Year and Date: 2011-05-25
• [Presentation] Fabrication of High Refractive and Transparent PMMA/TiO2 Hybrid Film (2010)
  • Author(s): S.Ya ma d a, E.Mouri, K.Yoshinaga
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: ホノルル
  • Year and Date: 2010-12-19
• [Presentation] Fabrication of High Refractive and Transparent PMMA/TiO_2 Hybrid Film (2010)
  • Author(s): S.Yamada
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: ホノルル(アメリカ)
  • Year and Date: 2010-12-19
• [Presentation] 高分子ミセルを用いたZnO ナノ粒子の調製とPMMAとの複合化 (2010)
  • Author(s): 下村侑輝, 吉永耕二, 他1名
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 札幌
  • Year and Date: 2010-09-15
• [Presentation] 高分子ミセルを用いた金属酸化物ナノ粒子の調製と高分子との複合化 (2010)
  • Author(s): 山田修平, 吉永耕二, 他1名
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 札幌
  • Year and Date: 2010-09-15
• [Presentation] 高分子ミセルを用いたZnOナノ粒子の調製とPMMAとの複合化 (2010)
  • Author(s): 下村侑輝
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 札幌
  • Year and Date: 2010-09-15
• [Presentation] Synthesis of Mono-dispersed TiO2Particles from Polymer Micelles and their High Refractive and Transparent Hybrid Films (2010)
  • Author(s): S.Yamada, E.Mouri, K.Yoshinaga
  • Organizer: 3rd EuCheMS Chemistry Congress
  • Place of Presentation: ニュールンブルグ
  • Year and Date: 2010-08-30
• [Presentation] Synthesis of Mono-dispersed TiO_2 Particles from Polymer Micelles and their High Refractive and Transparent Hybrid Films (2010)
  • Author(s): K.Yoshinaga
  • Organizer: 3rd EuCheMS Chemistry Congress
  • Place of Presentation: ニュールンベルグ(ドイツ)
  • Year and Date: 2010-08-30
• [Presentation] 高分子ミセルを用いたZnOナノ粒子/PMMAハイブリッドフィルムの作製 (2010)
  • Author(s): 下村侑輝
  • Organizer: 第47回九州化学関連支部合同大会
  • Place of Presentation: 北九州
  • Year and Date: 2010-07-10
• [Presentation] ZnOナノ粒子/PMMA ハイブリッドフィルムの作製 (2010)
  • Author(s): 下村侑輝, 吉永耕二, 他1名
  • Organizer: 第59回高分子学会 年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2010-05-27
• [Presentation] ZnOナノ粒子/PMMAハイブリッドフィルムの作製 (2010)
  • Author(s): 下村侑輝
  • Organizer: 第59回高分子学会 年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2010-05-27
• [Presentation] ブロックコポリマーを用いたZnOナノ粒子の調製とPMMAとの複合化 (2010)
  • Author(s): 下村侑輝
  • Organizer: 第18回複合材料界面シンポジウム
  • Place of Presentation: 宮崎
  • Year and Date: 2010-04-22
• [Presentation] ブロックコポリマーの逆ミセル中での無機ナノ粒子の合成とハイブリッド化
  • Author(s): 吉永 耕二
  • Organizer: ポリウレタンフォーラム
  • Place of Presentation: 長崎
  • Invited
• [Book] コンポジット材料の混練・コンパウンド技術と分散・界面制御-第5章2節 ポリマー分散剤を用いたカーボンナノチューブの分散と帯電防止剤への応用(分筆) (2013)
  • Author(s): 吉永耕二, 他4名
  • Publisher: 情報技術協会
• [Book] 「分散」のための界面制御技術の条件設定とトラブル対策-第2章7節 ポリマーによる各種表面処理技術(分筆) (2012)
  • Author(s): 吉永耕二
  • Publisher: 技術情報協会