High sensitivity spectroscopy of molecules adsorbed on oxide surfaces using enhancement effect of defect states

• Project/Area Number: 22655004
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Single-year Grants
• Research Field: Physical chemistry
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: ONDA Ken 東京工業大学, 大学院・総合理工学研究科, 特任准教授 (60272712)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥3,460,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥360,000); Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2010: ¥1,900,000 (Direct Cost: ¥1,900,000)
• Keywords: 表面・界面 / 酸化物 / 表面分光 / 非線形分光 / 表面界面 / 振動和周波発生法 / 光触媒

Research Abstract

Aiming at developing high sensitivity spectroscopy of molecules adsorbed on oxide surfaces, vibrational sum frequency generation(VSFG) spectra on various oxide surfaces were measured. We discovered extraordinary strong signal located at 1600cm-1, which is three orders of magnitude stronger than ordinal signals, on a TiO2single crystal surface in air. In order to reveal the origin of this strong signal, we measured VSFG spectra of various molecules on various modified surfaces. The results implied that the enhancement effect is attributed to the resonance effect to the mixing state between surface water and defect states of the oxide surface.

Research Products

• [Journal Article] Charge and structural dynamics in photoinduced phase transition of(EDO-TTF)_2PF_6examined by picosecond time-resolved vibrational spectroscopy (2012)
  • Author(s): Naoto Fukazawa, Minoru Shimizu, Tadahiko Ishikawa, Yoichi Okimoto, Shin-ya Koshihara, Takaaki Hiramatsu, Yoshiaki Nakano, Hideki Yamochi, Gunzi Saito, and Ken Onda
  • Journal Title: J. Phys. Chem. C Volume: 116 Pages: 5892-5899
  • Peer Reviewed
• [Journal Article] Photoinduced Ionic to Neutral Phase Transition in TTF-CA Studied by Time-resolved Infrared Vibrational Spectroscopy (2012)
  • Author(s): Yoshitaka Matsubara, Tatsushi Yoshida, Tadahiko Ishikawa, Yoichi Okimoto, Shin-ya Koshihara, and Ken Onda
  • Journal Title: Acta Physica Polonica A Volume: 121 Pages: 340-342
  • Peer Reviewed
• [Journal Article] Photo-induced Structural Changes at a Surface of Organic Single Crystals Observed by Vibrational Sum Frequency Generation Spectroscopy (2012)
  • Author(s): K. Fukumoto, S. Koshihara, N. Fukazawa, T. Ishikawa, H. Yamamoto, R. Kato, and K. Onda
  • Journal Title: Acta Physica Polonica A Volume: 121 Pages: 313-315
  • Peer Reviewed
• [Journal Article] Charge and structural dynamics in the photoinduced phase transition process of (EDO-TTF)_2PF_6 studied by picosecond time-resolved vibrational spectroscopy (2012)
  • Author(s): N.Fukazawa, M.Shimizu, T.Ishikawa, Y.Okimoto, S.Koshihara, T.Hiramatsu, Y.Nakano, H.Yamochi, G.Saito, K.Onda
  • Journal Title: The Journal of Physical Chemistry C Volume: 116 Issue: 9 Pages: 5892-5899
  • DOI: 10.1021/jp210708q
  • Peer Reviewed
• [Journal Article] Photoinduced Neutral-to-Ionic Phase Transition in Tetrathiafulvalene-p-Chloranil Studied by Time-resolved Vibrational Spectroscopy (2011)
  • Author(s): Yoshitaka Matsubara, Yoichi Okimoto, Tatsushi Yoshida, Tadahiko Ishikawa, Shin-ya Koshihara, and Ken Onda
  • Journal Title: J. Phys. Soc. Jpn Volume: 80
  • NAID: 210000109318
  • Peer Reviewed
• [Journal Article] Ultrafast Spectral Weight Transfer in RBaCo2O6.δ(R=Sm, Gd, and Tb): A Role of Electronic Correlation in Photoinduced Phase Transition (2011)
  • Author(s): Y. Okimoto, T. Miyata, M. S. Endo, M. Kurashima, K. Onda, T. Ishikawa, S. Koshihara1, M. Lorenc, E. Collet, H. Cailleau, and T. Arima
  • Journal Title: Phys. Rev. B Volume: 84 Pages: 121102-121102
  • Peer Reviewed
• [Journal Article] Acceleration of domain wall movement by photoirradiation in perovskite-type cobaltite (2011)
  • Author(s): Y. Okimoto, M. Kurashima, K. Seko, T. Ishikawa, K. Onda, S. Koshihara, T. Kyomen, and M. Itoh
  • Journal Title: Phys. Rev. B Volume: 83
  • Peer Reviewed
• [Journal Article] Photoinduced Dynamics of a Quasi-1DOrganic Conductor over a Range from 10 fsto 100 ps (2011)
  • Author(s): Ken Onda, Sho Ogihara, Jiro Itatani, Tadahiko Ishikawa, Yoichi Okimoto, Shinya Koshihara, Xiangfeng Shao, Yoshiaki Nakano, Hideki Yamochi, and Gunzi Saito
  • Journal Title: Ultrafast Phenomena XVII Pages: 188-190
  • Peer Reviewed
• [Journal Article] Photoinduced Neutral-to-Ionic Phase Transition in Tetrathiafulvalene-p-Chloranil Studied by Time-resolved Vibrational Spectroscopy (2011)
  • Author(s): Y.Matsubara, 他
  • Journal Title: J.Phys.Soc.Jpn Volume: 80 Issue: 12 Pages: 124711-124711
  • DOI: 10.1143/jpsj.80.124711
  • Peer Reviewed
• [Journal Article] Ultrafast spectral weight transfer in RBaCo206-δ (R=Sm, Gd, and Tb) : Role of electronic correlation in a photoinduced phase transition (2011)
  • Author(s): Y.Okimoto
  • Journal Title: Phys.Rev Volume: B 84, (No.12) Issue: 12
  • DOI: 10.1103/physrevb.84.121102
  • Peer Reviewed
• [Journal Article] Light-driven modulation of fluorescence color from azobenzene derivatives containing electron-donating and electron-withdrawing groups (2010)
  • Author(s): Mina Han, Yasuo Norikane, Ken Onda, Yoko Matsuzawa, Masaru Yoshida, and Masahiko Hara
  • Journal Title: New J. Chem Volume: 34 Pages: 2892-2896
  • Peer Reviewed
• [Journal Article] Ultrafast and large reflectivity change by ultraviolet excitation of the metallic phase in the organic conductor(EDO-TTF)_2PF_6 (2010)
  • Author(s): K. Onda, M. Shimizu, F. Sakaguchi, S. Ogihara, T. Ishikawa, Y. Okimoto, S. Koshihara, X. F. Shao, Y. Nakano, H. Yamochi, and G. Saito
  • Journal Title: Physica B Volume: 405
  • Peer Reviewed
• [Journal Article] Photoinduced Dynamics of a Quasi-1D Organic Conductor over a Range from 10 fs to 100 ps (2010)
  • Author(s): K.Onda, 他
  • Journal Title: Ultrafast Phenomena XVII Pages: 188-190
  • Peer Reviewed
• [Journal Article] Light-driven modulation of fluorescence color from azobenzene derivatives containing electron-donating and electron-withdrawing groups (2010)
  • Author(s): M.Han, 他
  • Journal Title: New J.Chem. Volume: 34 Pages: 2892-2896
  • Peer Reviewed
• [Journal Article] Ultrafast and large reflectivity change by ultraviolet excitation of the metallic phase in the organic conductor (EDO-TTF)_2PF_6 (2010)
  • Author(s): K.Onda, 他
  • Journal Title: Physica B Volume: 405
  • Peer Reviewed
• [Journal Article] Acceleration of domain wall movement by photoirradiation in perovskite-type cobaltite
  • Author(s): Y.Okimoto, 他
  • Journal Title: Phys.Rev B Volume: (in press)
  • Peer Reviewed
• [Presentation] 非線形分光法を用いた酸化物表面吸着種の反応ダイナミクス (2012)
  • Author(s): 恩田健
  • Organizer: 第72回表面科学研究会「和周波発生分光法による表面・界面計測」(招待講演)
  • Place of Presentation: 東京理科大、東京都
  • Year and Date: 2012-03-19
• [Presentation] 非線形分光法を用いた酸化物表面吸着種の反応ダイナミクス (2012)
  • Author(s): 恩田健
  • Organizer: 第72回表面科学研究会「和周波発生分光法による表面・界面計測」
  • Place of Presentation: 東京理科大、東京都(招待講演)
  • Year and Date: 2012-03-19
• [Presentation] 非線形振動分光法の光触媒、有機電子デバイスへの応用 (2012)
  • Author(s): 恩田健
  • Organizer: 第5回SFG研究会(招待講演)
  • Place of Presentation: 東北大学、宮城県
  • Year and Date: 2012-03-10
• [Presentation] 非線形振動分光法の光触媒、有機電子デバイスへの応用 (2012)
  • Author(s): 恩田健
  • Organizer: 第5回SFG研究会
  • Place of Presentation: 東北大学、宮城県(招待講演)
  • Year and Date: 2012-03-10
• [Presentation] フェムト秒時間分解フォノン分光による有機電荷移動錯体TTF-CA結晶の光誘起中性-イオン性相転移 (2011)
  • Author(s): 吉田樹史, 他
  • Organizer: 日本物理学会第66回年次大会
  • Place of Presentation: 震災の影響により概要集集、Webサイト上のみ
• [Presentation] (EDO-TTF)_<1-x>(MeEDO-TTF)_x]_2PF_6における金属絶縁体転移の赤外分光による研究 (2011)
  • Author(s): 松原圭孝, 他
  • Organizer: 日本物理学会第66回年次大会
  • Place of Presentation: 震災の影響により概要集集、Webサイト上のみ
• [Presentation] 時間分解分子振動分光法を用いたEt_2Me_2Sb[Pd(dmit)_2]_2完全電荷分離相における光誘起現象の解明 (2011)
  • Author(s): 深澤直人, 他
  • Organizer: 日本物理学会第66回年次大会
  • Place of Presentation: 震災の影響により概要集集、Webサイト上のみ
• [Presentation] ime-resolved infrared vibrational spectroscopy for studying dynamics of molecular crystals (2010)
  • Author(s): N.Fukazawa, 他
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: 米国ハワイ州 Honolulu
  • Year and Date: 2010-12-17
• [Presentation] ピコ秒VSFG法による単結晶二酸化チタン表面の大気中での観測 (2010)
  • Author(s): 恩田健
  • Organizer: 表面・界面スペクトロスコピー2010
  • Place of Presentation: つくば市筑波山京成ホテル
  • Year and Date: 2010-12-04
• [Presentation] ピコ秒VSFG法による単結晶二酸化チタン表面の大気中での観測 (2010)
  • Author(s): 恩田健, 他
  • Organizer: 表面・界面スペクトロスコピー2010
  • Place of Presentation: つくば市 筑波山京成ホテル
  • Year and Date: 2010-12-04
• [Presentation] Dynamics in air of monolayer water on a single crystal TiO2(110) surface using picosecond VSFG spectroscopy (2010)
  • Author(s): K. Onda
  • Organizer: 平成22年度日本分光学会年次講演
  • Place of Presentation: 京都市京都大学
  • Year and Date: 2010-11-18
• [Presentation] Dynamics in air of monolayer water on a single crystal TiO_2(110) surface using picosecond VSFG spectroscopy (2010)
  • Author(s): K.Onda, 他
  • Organizer: 平成22年度 日本分光学会年次講演会
  • Place of Presentation: 京都市 京都大学
  • Year and Date: 2010-11-18
• [Presentation] (EDO-TTF)_<1-x>(MeEDO-TTF)_x]_2PF_6における光誘起相転移:時間分解振動分光 (2010)
  • Author(s): 松原圭孝, 他
  • Organizer: 日本物理学会2010秋季大会
  • Place of Presentation: 大阪府堺市 大阪府立大
  • Year and Date: 2010-09-24
• [Presentation] 電荷移動型錯体(EDO-TTF)_2PF_6における10 fsから100 psにわたる光誘起ダイナミクス (2010)
  • Author(s): 恩田健, 他
  • Organizer: 第4回分子科学討論会
  • Place of Presentation: 大阪市 大阪大学
  • Year and Date: 2010-09-15
• [Presentation] 時間分解分子振動分光によるEt_2Me_2Sb[Pd(dmit)_2]_2の超高速光誘起現象の探索 (2010)
  • Author(s): 深澤直人, 他
  • Organizer: 第4回分子科学討論会
  • Place of Presentation: 大阪市 大阪大学
  • Year and Date: 2010-09-15
• [Presentation] Dynamics of Monolayer Water ona Single Crystalline TiO2 Surface in Airby VSFG Spectroscopy (2010)
  • Author(s): K. Onda
  • Organizer: 7th International Symposium on Ultrafast Surface Dynamics
  • Place of Presentation: クロアチアBrijuni Islands
  • Year and Date: 2010-08-26
• [Presentation] Dynamics of Monolayer Water on a Single Crystalline TiO_2 Surface in Air by VSFG Spectroscopy (2010)
  • Author(s): K.Onda, 他
  • Organizer: 7th International Symposium on Ultrafast Surface Dynamics
  • Place of Presentation: クロアチア Brijuni Islands
  • Year and Date: 2010-08-26
• [Presentation] Photoinduced Dynamics of a Quasi-1D Organic Conductor over a Range from 10 fs to 100 ps (2010)
  • Author(s): K.Onda, 他
  • Organizer: 17th International Conference on Ultrafast Phenomena
  • Place of Presentation: 米国 Snowmass Village
  • Year and Date: 2010-07-19
• [Remarks]
  • URL: http://www.cms.titech.ac.jp/~koshihara/member/onda/