Photo-triggered formation of molecular aggregate composed of p-conjugated compounds with photo-induced peri-cyclization reaction.
Project/Area Number |
22655042
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Single-year Grants |
Research Field |
Functional materials chemistry
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Research Institution | Nara Institute of Science and Technology |
Principal Investigator |
KAWAI Tsuyoshi 奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)
|
Project Period (FY) |
2010 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥3,460,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,900,000 (Direct Cost: ¥1,900,000)
|
Keywords | 分子素子 / π共役縮環構造 / 1次元分子ワイヤー / 会合構造形成 / 光制御 / 分子エレクトロニクス材料 |
Research Abstract |
Photochromic terarylenes which shows photo-induced peri-cyclization reactions was modified with photo-leaving groups. Photo-triggered formation of molecular aggregates was successfully achieved and the pai-stacked structures were confirmed in the aggregated particles. Photo-induced reaction mechanism was studied by preparing a series of related compounds.
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Report
(3 results)
Research Products
(18 results)