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Organic-inorganic hybrid films with photo and stimuli responsive micro structures

Research Project

Project/Area Number 22655071
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

TAKAHASHI Masahide  大阪府立大学, 工学研究科, 教授 (20288559)

Co-Investigator(Kenkyū-buntansha) TOKUDOME Yasuaki  大阪府立大学, 工学研究科, 助教 (50613296)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,490,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥390,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,800,000 (Direct Cost: ¥1,800,000)
Keywords光分子集合性 / 褶曲構造 / 有機-無機ハイ / 環境応答性 / 形状記憶材料 / 微細周期構造 / 選択吸着 / 有機-無機ハイブリッド材料 / ハイブリッドコーティング / 形態記憶微細構造 / スマート材料 / 階層的微細構造 / ロボオンチップ / 微小流路回路 / 湿度応答性 / 自己組織化
Research Abstract

Smart hybrid thin films have been realized which exhibit sitimuli-repsonsive micro ordered structures. Surface periodic wrinkles in micro meter scale were fabricated through self-organizing processes under photo-illumination on the films. The stimuli-responsive thin films were mounted in micro fluidic system, and established the size-selective catch and release surfaces for micro particles.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (47 results)

All 2012 2011 2010 Other

All Journal Article (26 results) (of which Peer Reviewed: 12 results) Presentation (20 results) Remarks (1 results)

  • [Journal Article] Magnetic Framework Composites for Polycyclic Aromatic Hydrocarbon Sequestration2012

    • Author(s)
      Doherty C.M., Knystautas E., Buso. D, Villanova L., Konstas. K, Hill A.J., Takahashi M., Falcaro P.
    • Journal Title

      J. Mater. Chem.

      Volume: 22(23) Issue: 23 Pages: 11470-11474

    • DOI

      10.1039/c2jm31798b

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Titanate nanofunnel brushes : toward functional interfacial applications2012

    • Author(s)
      Okada K., Tokudome Y., Falcaro P., Takamatsu Y., Nakahira A., Takahashi M.
    • Journal Title

      Chem. Commun.

      Volume: 48(49) Issue: 49 Pages: 6130-6132

    • DOI

      10.1039/c2cc32081a

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly oriented growth of titanate nanotubes(TNTs) in micro and confinement spaces on sol. gel derived amorphous TiO_2 thin films under moderate hydrothermal condition2012

    • Author(s)
      Okada K., Takamatsu Y., Nakahira A., Tokudome Y., Takahashi M.*
    • Journal Title

      J. Sol-Gel Sci. Technol

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of diphenyldiethoxysilane on the self-organized formation of nanocrystalline layered organosilicates in organic-inorganic hybrid films2011

    • Author(s)
      Figus C., Takahashi M., Casula M., Innocenzi P
    • Journal Title

      J. Sol-Gel Sci. Technol.

      Volume: 60 Pages: 275-282

    • Related Report
      2011 Final Research Report
  • [Journal Article] Structural Evolution during Evaporation of a 3-Glycidoxypropyltrimethoxysilane Film Studied in Situ by Time Resolved Infrared Spectroscopy2011

    • Author(s)
      Innocenzi P., Figus C., Takahashi M., Piccinini M., Malfatti L.
    • Journal Title

      J. Phys. Chem. A

      Volume: 115(38) Pages: 10438-10444

    • Related Report
      2011 Final Research Report
  • [Journal Article] Dynamic control of MOF-5 crystal positioning using a magnetic field2011

    • Author(s)
      Falcaro P., Normandin F., Takahashi M., Scopece P., Amenitsch H., Costacurta S., Doherty C. M., Liard J., Lay M. D. H., Lisi F., Hill A. J., Buso D.
    • Journal Title

      Adv. Mater

      Volume: 23(34) Pages: 3867-3871

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of Porous TiO2 Thin Films via Sol-gel Method and Their Phototocatalyst Performances2011

    • Author(s)
      Jianxi Yao, Zhihua Tian, Mina Guli, Masahide Takahashi, Toshinobu Yoko
    • Journal Title

      Mater. Sci. Forum

      Volume: 687 Pages: 765-770

    • Related Report
      2011 Final Research Report
  • [Journal Article] Crystallization in hybrid organic. inorganic materials through self-organization from 3-glycidoxypropyltrimethoxysilane2011

    • Author(s)
      Innocenzi P., Figus C., Kidchob T., Takahashi M.
    • Journal Title

      J. Cer. Soc. Jpn

      Volume: 119(6) Pages: 387-392

    • NAID

      130000784596

    • Related Report
      2011 Final Research Report
  • [Journal Article] Sol-Gel Preparation, Characterization, and Photocatalytic Activity of Macroporous TiO_2 Thin Films"2011

    • Author(s)
      Yao JX, Bai YM, Chen NF, Takahashi M, Yoko T
    • Journal Title

      J. Am. Cer. Soc

      Volume: 94(4) Pages: 1191-1197

    • Related Report
      2011 Final Research Report
  • [Journal Article] Fabrication of inverse opal films of titania-polymer hybrid with a high refractive index modulation2011

    • Author(s)
      Ueno S., Takahashi M.
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 58(5) Pages: 297-300

    • NAID

      10028293187

    • Related Report
      2011 Final Research Report
  • [Journal Article] Photo-induced formation and humidity response of micro wrinkled structures on titania-polymer hybrid films2011

    • Author(s)
      Kitanaga T., Inoue M., Takahashi M.
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 58(5) Pages: 301-306

    • Related Report
      2011 Final Research Report
  • [Journal Article] Structure manufacturing of proton-conducting organic-inorganic hybrid silicophosphite membranes by solventless synthesis2011

    • Author(s)
      Tokuda Y., Oku S., Yamada T., Takahashi M., Yoko T., Kitagawa H., Ueda Y.
    • Journal Title

      J. Mater. Res

      Volume: 26(6) Pages: 796-803

    • NAID

      120003534361

    • Related Report
      2011 Final Research Report
  • [Journal Article] Fabrication and characterization of macroporous TiO2 films by photo polymerization-induced phase separation method2011

    • Author(s)
      Yao JX, Tian HX, Takahashi M, Yoko T.
    • Journal Title

      Mater. Lett

      Volume: 64(19) Pages: 2049-2052

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of diphenyldiethoxysilane on the self-organized formation of nanocrystalline layered organosilicates in organic-inorganic hybrid films2011

    • Author(s)
      Figus C., Takahashi M., Casula M., Innocenzi P.
    • Journal Title

      J.Sol-Gel Sci.Technol.

      Volume: 60 Pages: 275-282

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Evolution dviring Evaporation of a 3-Glycidoxypropyltrimethoxy silane Film Studied in Situ by Time Resolved Infrared Spectroscopy2011

    • Author(s)
      Innocenzi P., Figus C., Takahashi M., Piccinini M., Malfatti L.
    • Journal Title

      J.Phys.Chem.A

      Volume: 115 Pages: 10438-10444

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic control of MOF-5 crystal positioning using a magnetic field2011

    • Author(s)
      Falcaro F., Normandin R, Takahashi M., Scopece P., Amenitsch H., Costacurta S., Doherty C.M., Liard J., Lay M.D.H., Lisi F., Hill A.J., Buso D.
    • Journal Title

      Adv.Mater.

      Volume: 23 Pages: 3867-3871

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sol-Gel Preparation, Characterization, and Photocatalytic Activity of Macroporous TiO_2 Thin Films2011

    • Author(s)
      Yao JX, Bai YM, Chen NF, Takahashi M, Yoko T
    • Journal Title

      J.Am.Cer.Soc.

      Volume: 94 Pages: 1191-1197

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of photo-curable borosiloxane thin-film material and fabricatoin of microstructures2010

    • Author(s)
      Ihara R., Takahashi M.
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 57 Pages: 537-541

    • Related Report
      2011 Final Research Report
  • [Journal Article] Photo-fabrication of titania hybrid films with tunable hierarchical structures and stimuli responsive properties2010

    • Author(s)
      Takahashi M., Inoue M., Ihara R., Yoko T., Nemoto T., Isoda S., Malfatti L., Costacurta S., Innocenzi P.
    • Journal Title

      Adv. Mater

      Volume: 22 Pages: 3303-3306

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of photo-curable borosilicate thin-film materials and fabrication of micro structures2010

    • Author(s)
      Ihara R., Takahashi M
    • Journal Title

      J.Jpn.Powder Powder Metallurgy

      Volume: 57 Pages: 537-541

    • NAID

      10026872144

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 交互共重合型の有機修飾酸化物を用いた光機能性開拓2010

    • Author(s)
      高橋雅英
    • Journal Title

      セラミックス

      Volume: 45 Pages: 636-640

    • NAID

      10026496491

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization and solventless growth of salicylic acid macro-crystals involving a nitrogen gas flow2010

    • Author(s)
      Menaa B., Takahashi M., Tokuda Y., Yoko T.
    • Journal Title

      Cryst.Res.Technol.

      Volume: 45 Pages: 341-346

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo-fabrication of titania hybrid films with tunable hierarchical structures and stimuli responsive properties2010

    • Author(s)
      Takahashi M., Inoue M., Ihara R., Yoko T., Nemoto T., Isoda S., Malfatti L., Costacurta S., Innocenzi P.
    • Journal Title

      Adv.Mater.

      Volume: 22 Pages: 3303-3306

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photo-curable organically modified silicate-phosphate alternating copolymer for photonics applications2010

    • Author(s)
      Takahashi M., Suzuki M., Miyagawa Y., Ihara R., Tokuda Y, Yoko T., Nemoto T., Isoda S.
    • Journal Title

      J.Sol-Gel Sci.Technol.

      Volume: 54 Pages: 319-324

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and characterization of macroporous TiO2 films by photo polymerization-induced phase separation method2010

    • Author(s)
      Yao JX, Tian HX, Takahashi M, Yoko T
    • Journal Title

      Mater.Lett.

      Volume: 64 Pages: 2049-2052

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strain driven self-rolling of hybrid organic-inorganic microrolls : interfaces with self-assembled particles

    • Author(s)
      Takahashi M., Figus C., Malfatti L., Tokuda Y., Yamamoto K., Yoko T., Kitanaga T., Tokudome Y., Innocenzi P.
    • Journal Title

      Asia Materials

    • Related Report
      2011 Final Research Report
  • [Presentation] Stimuli responsive surface micro structures on oxide-polymer hybrid films by photo-induced self-organization2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      15th International Conference on Thin Films
    • Place of Presentation
      京都
    • Year and Date
      2011-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Stimuli responsive surface micro structures on oxide-polymer hybrid films by photo-induced self-organization2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      15th International Conference on Thin Films
    • Place of Presentation
      京都(京都テルサ)(招待講演)
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Rewritable Holographic Structures Formed in Organic-inorganic Hybrid Materials by Photothermal Processing2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      16th International Sol-Gel Conference
    • Place of Presentation
      杭州、中国
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 表面改質した有機-無機ハイブリッド薄膜における化学系ー機械系エネルギー変換2011

    • Author(s)
      高橋雅英
    • Organizer
      材料学会ナノ材料部門委員会
    • Place of Presentation
      京都
    • Year and Date
      2011-08-04
    • Related Report
      2011 Final Research Report
  • [Presentation] 表面改質した有機-無機ハイブリッド薄膜における化学系-機械系エネルギー変換2011

    • Author(s)
      高橋雅英
    • Organizer
      本材料学会ナノ材料部門委員会
    • Place of Presentation
      京都(京大会館)(招待講演)
    • Year and Date
      2011-08-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photo-induced formation of micro structures and simuli-response2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      ICCE2011
    • Place of Presentation
      上海、中国
    • Year and Date
      2011-07-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Photo-induced formation of micro structures and simuli-response2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      ICCE2011
    • Place of Presentation
      上海、中国(招待講演)
    • Year and Date
      2011-07-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photo-induced formation of environmental responsive moving micro structures on inorganic-organic hybrid thin films2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      PacRim9
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2011-07-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Photo-induced formation of environmental responsive moving micro structures on inorganic-organic hybrid thin films2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      PacRim9
    • Place of Presentation
      Cairns, Australia(招待講演)
    • Year and Date
      2011-07-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Optically-functional organic-inorganic hybrid materials from solvent-free condensation reactions2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      MRS Spring meeting
    • Place of Presentation
      San Francisco
    • Year and Date
      2011-04-29
    • Related Report
      2011 Final Research Report
  • [Presentation] optically-functional organic-inorganic hybrid materials from solvent-free condensation reactions2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      MRS Spring meeting
    • Place of Presentation
      San Francisco, U.S.A.
    • Year and Date
      2011-04-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Stimuli responsive surface micro structures on oxide-polymer hybrid films by photo-induced self-organization2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      4th International Workshop on Smart Materials & Structures
    • Place of Presentation
      AGADIR, Morocco
    • Related Report
      2011 Final Research Report
  • [Presentation] Stimuli responsive surface micro structures on oxide-polymer hybrid films by photo-induced self-organization2011

    • Author(s)
      Masahide Takahashi
    • Organizer
      4th International Workshop on Smart Materials & Structures
    • Place of Presentation
      AGADIR, Morocco(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photo-induced fabrication of titania hybrid films with tunable hierarchical structures and stimuli responsive properties2010

    • Author(s)
      Masahide Takahashi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル国際会議場(アメリカ)
    • Year and Date
      2010-12-01
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Photo-Induced Fabrication of Titania-Polymer Hybrid Films with Tunable Hierarchical Structures and Stimuli-Responsive Property2010

    • Author(s)
      Masahide Takahashi
    • Organizer
      International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2010-11-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Rewritable Holographic Structures Formed in Organic-Inorganic Hybrid Materials by Photothermal Processing2010

    • Author(s)
      Masahide Takahashi
    • Organizer
      International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2010-11-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Photo-Induced Fabrication of Titanic-Polymer Hybrid Films with Tunable Hierarchical Structures and Stimuli-Responsive Property2010

    • Author(s)
      Masahide Takahashi
    • Organizer
      International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      2010-11-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 無溶媒縮合法による機能性材料の創出2010

    • Author(s)
      高橋雅英
    • Organizer
      日本セラミックス協会ガラス部会若手セミナー
    • Place of Presentation
      サンロード吉備路(岡山)
    • Year and Date
      2010-08-05
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 光硬化性ホウケイ酸塩系ポリマーを利用した機能性薄膜の作製2010

    • Author(s)
      上野誠司、井原梨恵、高橋雅英
    • Organizer
      ゾル-ゲル討論
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2010-07-29
    • Related Report
      2011 Final Research Report
  • [Presentation] 光硬化性ホウケイ酸塩系ポリマーを利用した機能性薄膜の作製2010

    • Author(s)
      上野誠司、井原梨恵、高橋雅英
    • Organizer
      ゾルーゲル討論会
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2010-07-29
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.photomat.mtr.osakafu-u.ac.jp

    • Related Report
      2011 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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