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Enzyme-immobilized nanoporous metals for functionalization

Research Project

Project/Area Number 22656155
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionKyoto University

Principal Investigator

MABUCHI Mamoru  京都大学, 大学院・エネルギー科学研究科, 教授 (00358061)

Co-Investigator(Kenkyū-buntansha) NAKANO Hiromi  豊橋技術科学大学, 研究基盤センター, 准教授 (00319500)
Co-Investigator(Renkei-kenkyūsha) HAKAMADA Masataka  京都大学, 大学院・エネルギー科学研究科, 助教 (30462849)
Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,550,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥2,900,000 (Direct Cost: ¥2,900,000)
Keywordsナノ材料 / 酵素反応 / 構造・機能材料 / ナノバイオ / 表面・界面物性
Research Abstract

Enzymes were immobilized on nanoporous metals for stabilization. Laccase immobilized on nanoporous Au exhibited higher thermal stability than free laccase. Decoration of nanoporous Au with self-assembled monolayer(SAM) also enhanced the thermal stability of the immobilized laccase. SAM decoration also facilitated electron transfer between electrolyte and electrode through enzymes. A prototype biofuel cell successfully operated using enzyme-immobilized SAM-modified nanoporous Au electrodes.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (7 results)

All 2012 2011 2010

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (1 results)

  • [Journal Article] Enzyme electrodes stabilized by monolayer-modified nanoporous Au for biofuel cells2012

    • Author(s)
      M. Hakamada, M. Takahashi, M. Mabuchi
    • Journal Title

      Gold Bulletin

      Volume: 45 Issue: 1 Pages: 9-15

    • DOI

      10.1007/s13404-011-0038-1

    • NAID

      120006540270

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced thermal stability of laccase immobilized on monolayer-modified nanoporous Au2011

    • Author(s)
      M. Hakamada, M. Takahashi, M. Mabuchi
    • Journal Title

      Mater. Lett.

      Volume: 66 Issue: 1 Pages: 4-6

    • DOI

      10.1016/j.matlet.2011.08.017

    • NAID

      120006596504

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical stability of self-assembled monolayers on nanoporous Au2011

    • Author(s)
      M. Hakamada, M. Takahashi, T. Furukawa, K. Tajima, K. Yoshimura, Y. Chino, M.
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 13 Issue: 26 Pages: 12277-12784

    • DOI

      10.1039/c0cp02553d

    • NAID

      120004225523

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Nanoporous Structure on Pt Plate Surface by Alloying/Dealloying Technique2011

    • Author(s)
      袴田昌高、千野靖正、馬渕守
    • Journal Title

      Journal of the Japan Institute of Metals and Materials

      Volume: 75 Issue: 1 Pages: 42-46

    • DOI

      10.2320/jinstmet.75.42

    • NAID

      10027672790

    • ISSN
      0021-4876, 1880-6880, 2433-7501
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous surface fabricated on metal sheets by alloying/dealloying technique2010

    • Author(s)
      M. Hakamada, Y. Chino, M. Mabuchi
    • Journal Title

      Mater. Lett

      Volume: 64 Issue: 21 Pages: 2341-2343

    • DOI

      10.1016/j.matlet.2010.07.046

    • NAID

      120002484954

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous surface fabricated on metal sheets by alloying/dealloying technique2010

    • Author(s)
      Masataka Hakamada, Yasumasa Chino, Mamoru Mabuchi
    • Journal Title

      Materials Letters

      Volume: 64 Pages: 2341-2343

    • NAID

      120002484954

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] ナノポーラス金表面における自己組織化単分子膜の安定性2010

    • Author(s)
      高橋真生、平嶋芙美、山本太応、袴田昌高、田嶌一樹、吉村和記、千野靖正、馬渕守
    • Organizer
      日本金属学会2010年秋期(第147回)大会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-26
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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