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Development of Scanning Probe Electron-Enhanced Raman Scattering Microscope and its Application to Interfacial Chemistry

Research Project

Project/Area Number 22685009
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionTokyo University of Science

Principal Investigator

YUI Hiroharu  東京理科大学, 理学部・第一部化学科, 准教授 (20313017)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥23,920,000 (Direct Cost: ¥18,400,000、Indirect Cost: ¥5,520,000)
Fiscal Year 2012: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2010: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Keywords走査型プローブ顕微鏡 / 電子・ラマン散乱 / 増強 / 界面 / 走査型顕微鏡 / レーザー / ラマン散乱 / 水 / 分光 / 走査プロープ顕微鏡 / 走査プローブ顕微鏡
Research Abstract

Scanning probe electron-enhanced Raman scattering microscope has been developed. Various methods for the generation of electrons from a metal tip by laser excitation were investigated experimentally. We found that the optimal method was the introduction of the tip to the near-field area excited by total internal reflection of laser beam. This is because it is appropriate for the illumination under spatially restricted sample chamber and is easy for the application to various samples in water. In addition, the combination of the FM modewith the optimized optical arrangement allowed us high-resolution measurements at single molecular resolution level. We have applied the instrument developed here to the measurements on carbon materials, lipid or protein self-assemblies for the test of the Raman enhancement factor and of the ability to measure the mechanical responses

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (24 results)

All 2013 2012 2011 2010

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (12 results) (of which Invited: 1 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Microscopic Optical Discharge Cell for Micro-Spectroscopic Measurements of Plasma in Solutions and Its Chemical-contrasted Imaging2013

    • Author(s)
      H. Yui, Y. Someya, Y. Kusama, K. Kannoand H. Takakuwa
    • Journal Title

      Bunsekikagaku

      Volume: vol.62 Pages: 19-24

    • NAID

      10031139085

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fine Structures in Vibrational Circular Dichroism Spectra of Chiral Molecules with Rotatable Hydroxyl Groups and Their Application in the Analysis of Local Intermolecular Interactions2013

    • Author(s)
      K. Konno, I. Shiina, H. Yui
    • Journal Title

      Journal of Molecular Structure

      Volume: 1035 Pages: 260-266

    • DOI

      10.1016/j.molstruc.2012.11.025

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Optical Discharge Cell for Micro-Spectroscopic Measurements of Plasma in Solutions and Its Chemical-contrasted Imaging2013

    • Author(s)
      H Yui, Y. Someya, Y. Kusama, K. Kanno and H. Takakuwa
    • Journal Title

      Bunsekikagaku

      Volume: 62 Pages: 19-24

    • NAID

      10031139085

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Capacity Si-Graphite Composite Electrodes with Self-Formed Porous Structure by a Partially Neutralized Polyacrylate for Li-ion Batteries2012

    • Author(s)
      Z -J. Han, N. Yabuuchi, K. Shimomura, M. Murase, H. Yui, and S. Komaba
    • Journal Title

      Energy Environ. Sci.

      Volume: 5 Issue: 10 Pages: 9014-9020

    • DOI

      10.1039/c2ee22292b

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Generation of laser-induced plasma in supercritical water and vibrational spectroscopic study of accompanying stimulated Raman scattering2011

    • Author(s)
      H. Yui,T. Tomai, M. Sawada, and K. Terashima
    • Journal Title

      Appl. Phys. Lett

      Volume: vol.99 Pages: 091504-091504

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Generation of laser-induced plasma in supercritical water and vibrational spectroscopic study of accompanying stimulated Raman scattering2011

    • Author(s)
      H.Yui, T.Tomai, M.Sawada, K.Terashima
    • Journal Title

      Appl.Phys.Lett.

      Volume: 99 Pages: 0915041-3

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-enhanced Raman scattering: a history of its discovery and spectroscopic applications to solution chemistry and interfacial chemistry2010

    • Author(s)
      H. Yui
    • Journal Title

      Anal. Bioanal. Chem

      Volume: vol.397 Pages: 1181-1190

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence lifetime probe for solvent microviscosity utilizing anilinonaphthalene sulfonate2010

    • Author(s)
      Y. Someya and H.Yui
    • Journal Title

      Anal. Chem

      Volume: vol.82 Pages: 5470-5476

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electron-enhanced Raman scattering : a history of its discovery and spectroscopic applications to solution chemistry and interfacial chemistry2010

    • Author(s)
      Hiroharu Yui
    • Journal Title

      Anal.Bioanal.Chem.

      Volume: 397 Pages: 1181-1190

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Spectroscopic Study on Aqueous Solution Plasma with Graphite Electrodes2013

    • Author(s)
      K. Akaike, K. Kanno, H. Takakuwa, M. Banno and H. Yui
    • Organizer
      Thirteenth International Symposium on Biomimetic Materials Processing
    • Place of Presentation
      Takayama, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Elasticity Changes in Peptide Lipid Self-Assemblies Induced by Removing Hydration Water2013

    • Author(s)
      D. Saito, M. Kogiso, T. Shimizu and H. Yui
    • Organizer
      Thirteenth International Symposium on Biomimetic Materials Processing
    • Place of Presentation
      Takayama, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Spectroscopic Characterization of the Thermal Collapse in Collagens2013

    • Author(s)
      Y. Sohara, T. Morisaku, K. Yasuda and H. Yui
    • Organizer
      Thirteenth International Symposium on Biomimetic Materials Processing
    • Place of Presentation
      Takayama, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Spectroscopic Study on Aqueous Solution Plasma with Graphite Electrodes2013

    • Author(s)
      K. Akaike, K. Kanno, H. Takakuwa, M. Banno, H. Yui
    • Organizer
      1st INTERNATIONAL WORKSHOP ON SOLUTION PLASMA AND MOLECULAR TECHNOLOGIES
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] Micro-Spectroscopic Investigation on Solution Plasma2013

    • Author(s)
      H. Yui, K. Kanno, H. Takakuwa, K. Akaike, M. Banno
    • Organizer
      1st INTERNATIONAL WORKSHOP ON SOLUTION PLASMA AND MOLECULAR TECHNOLOGIES
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Transient Formation of Plasma/Solution Interfaces - Its Micro-Spectroscopic Imaging and Applications toward New Reaction Fields2012

    • Author(s)
      H. Yui, Y. Someya, Y. Kusama, K. Kanno, H. Takakuwa
    • Organizer
      2th International Symposium on Biomimetic Materials Processing
    • Place of Presentation
      Nagoya University, Nagoya, Japan
    • Year and Date
      2012-01-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Transient Formation of Plasma/Solution Interfaces-Its Micro-Spectroscopic Imaging and Applications toward New Reaction Fields-2012

    • Author(s)
      H.Yui, Y.Someya, Y.Kusama, K.Kanno, H.Takakuwa
    • Organizer
      12th International Symposium on Bioiomimetic Materials Processing
    • Place of Presentation
      Nagoya University
    • Year and Date
      2012-01-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Spectroscopic Approaches to Plasma / Solution Interfaces2011

    • Author(s)
      H. Yu
    • Organizer
      IUPAC International Congress on Analytical Sciences (ICAS2011)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] プラズマと溶液の界面を利用した新しい計測技術を目指して2011

    • Author(s)
      由井宏治
    • Organizer
      硫酸協会第50回分析分科会
    • Place of Presentation
      東京
    • Related Report
      2012 Final Research Report
  • [Presentation] Spectroscopic Studies on Peptide Lipid Self-Assemblies2011

    • Author(s)
      H. Yui
    • Organizer
      11th International Symposium on Biomimetic Materials Processing (BMMP-11)
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2012 Final Research Report
  • [Presentation] プラズマ/溶液界面の分光計測・分析化学の新展開2010

    • Author(s)
      由井宏治
    • Organizer
      日本分析化学会第59 年会
    • Place of Presentation
      東北大学
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] プラズマ/溶液界面の分光計測・分析化学の新展開2010

    • Author(s)
      由井宏治
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学(招待講演)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Book] 化学と教育 「プラズマと溶液の界面が創り出す新しい化学反応場とその分光計測」2011

    • Author(s)
      由井宏治
    • Publisher
      日本化学会誌
    • Related Report
      2012 Final Research Report
  • [Book] 化学と工業 「プラズマと溶液の界面を利用した新しい計測技術を目指して」2010

    • Author(s)
      由井宏治
    • Publisher
      日本化学会誌
    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] 光干渉計、情報取得装置、及び情報取得方法2011

    • Inventor(s)
      由井宏治
    • Industrial Property Rights Holder
      由井宏治, 東京理科大学
    • Industrial Property Number
      2011-218220
    • Filing Date
      2011-09-30
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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