Development of next-generation external-field-responsive ionic liquids utilizing metal oxide nanosheets and metal complexes
| Project/Area Number |
22685015
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | Meijo University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
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| Keywords | イオンソフトマテリアル / イオン液体 / 有機-無機ナノコンポジット / 金属酸化物 ナノシート / 外場応答 / プロトン伝導 / 粘弾性 / 金属酸化物ナノシート / プルシアンブルー / ナノ粒子 / 磁性 / 金属錯体 / 発光特性 / レオロジー |
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| Research Abstract |
We demonstrated that negatively-charged metal oxide nanosheets can be utilized for development of novel functional ionic soft materials, by regarding them as “inorganic polymeric anions”. For example, viscoelastic ionic nanocomposite was obtained by virtue of the formation of ammonium-containing siloxane network on the titania nanosheet. The shape deformability allows us to process the thin film with a thickness of less than 100 nm, and the proton conductivity shows the multiple sensitivities to temperature, humidity, and photo-irradiation.
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Report
(4 results)
Research Products
(37 results)
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[Journal Article] Preparation, Structures, and Physical Properties of Tetrakis(alkylthio)tetraselenafulvalene (TTC_n-TSeF, n=1-15)2010
Author(s)
G.Saito, Y.Yoshida, H.Murofushi, N.Iwasawa, T.Hiramatasu, A.Otsuka, H.Yamochi, K.Isa, E.Mineo, M.Konno, T.Mori, K.Imaeda, H.Inokuchi
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Journal Title
Bulletin of the Chemical Society of Japan
Volume: 83
Pages: 335-344
NAID
Related Report
Peer Reviewed
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[Journal Article] Ionicity Phase Diagram of Trifluoromethyl-TCNQ (CF_3TCNQ)Charge Transfer Solids2010
Author(s)
G.Saito, H.Ikegami, Y.Yoshida, O.O.Drozdova, K.Nishimura, S.Horiuchi, H.Yamochi, A.Otsuka, T.Hiramatsu, M.Maesato, T.Nakamura, T.Akutagawa, T.Yumoto
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Journal Title
Bulletin of the Chemical Society of Japan
Volume: 83
Pages: 1462-1480
NAID
Related Report
Peer Reviewed
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