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Development of next-generation external-field-responsive ionic liquids utilizing metal oxide nanosheets and metal complexes

Research Project

Project/Area Number 22685015
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionMeijo University

Principal Investigator

YOSHIDA Yukihiro  名城大学, 農学部, 助教 (10378870)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Keywordsイオンソフトマテリアル / イオン液体 / 有機-無機ナノコンポジット / 金属酸化物 ナノシート / 外場応答 / プロトン伝導 / 粘弾性 / 金属酸化物ナノシート / プルシアンブルー / ナノ粒子 / 磁性 / 金属錯体 / 発光特性 / レオロジー
Research Abstract

We demonstrated that negatively-charged metal oxide nanosheets can be utilized for development of novel functional ionic soft materials, by regarding them as “inorganic polymeric anions”. For example, viscoelastic ionic nanocomposite was obtained by virtue of the formation of ammonium-containing siloxane network on the titania nanosheet. The shape deformability allows us to process the thin film with a thickness of less than 100 nm, and the proton conductivity shows the multiple sensitivities to temperature, humidity, and photo-irradiation.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (37 results)

All 2013 2012 2011 2010 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (13 results) Book (7 results) Remarks (1 results)

  • [Journal Article] MolecularRotors of Coronene in the Charge-TransferSolids2013

    • Author(s)
      Y. Yoshida
    • Journal Title

      Chem. Eur. J.

      Volume: (印刷中) Issue: 37 Pages: 12313-12324

    • DOI

      10.1002/chem.201300578

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Charge-Transfer Solids Using Nucleobase: Supramolecular Architectures Composed of Cytosine and [Ni(dmit)2] Assembled by Multiple Hydrogen Bonds and Heteroatomic Contacts2013

    • Author(s)
      Y. Yoshida, 他6名
    • Journal Title

      Chem. Eur.J.

      Volume: (印刷中) Issue: 37 Pages: 12325-12335

    • DOI

      10.1002/chem.201300865

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Exploration of Charge-Transfer Solids Utilizing Nucleobases: Nanoarchitectures by Hydrogen-Bonds in the Ionic Assemblies of Guanine and TCNQ Derivatives2013

    • Author(s)
      T. Murata, G. Saito, K. Nakamura, M.Maesato, T. Hiramatsu, Y. Yoshida
    • Journal Title

      Cryst.Growth Des.

      Volume: (印刷中) Issue: 7 Pages: 2778-2792

    • DOI

      10.1021/cg400059h

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Formation Mechanism of a n-Butylammonium/MnO2 Layered Hybrid via a One-Pot Synthesis under Moderate Condition2012

    • Author(s)
      Kazuya Kai, Yukihiro Yoshida, Yoji Kobayashi, Hiroshi Kageyama, Gunzi Saito
    • Journal Title

      Journal of Chemical Society, Dalton Transaction

      Volume: 41 Issue: 3 Pages: 825-830

    • DOI

      10.1039/c1dt11145k

    • Related Report
      2012 Annual Research Report 2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot Synthesis of Co-Substituted Manganese Oxide Nanosheets and PhysicalProperties of Lamellar Aggregates2012

    • Author(s)
      K. Kai, M. Cuisinier, Y. Yoshida, 他
    • Journal Title

      Mater. Res. Bull.

      Volume: 47 Issue: 11 Pages: 3855-3859

    • DOI

      10.1016/j.materresbull.2012.08.008

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of charge-transfer solids with cluster units [Mo6X14]2- (X = Br, I)2012

    • Author(s)
      Gunzi Saito, et.al.
    • Journal Title

      J. Mater. Chem.

      Volume: 22 Issue: 37 Pages: 19774-19791

    • DOI

      10.1039/c2jm33086e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Magnetic Ionic Liquids Composed of Hybrid-Type Anions2012

    • Author(s)
      Y. Takagi, Y. Kusunoki, Y. Yoshida, H. Tanaka, G. Saito, K. Katagiri, T. Oshiki
    • Journal Title

      Aust. J. Chem.

      Volume: 65 Issue: 11 Pages: 1557-1560

    • DOI

      10.1071/ch12331

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionic Liquids Based on Diethylmethyl(2-methoxyethyl)ammoniuin Cation and Bis(perfluoroalkanesulfonyl)amide Anions : Influence of Anion Structure on Liquid2011

    • Author(s)
      Y.Yoshida, G.Saito
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 13 Issue: 45 Pages: 20302-20310

    • DOI

      10.1039/c1cp21783f

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelastic Nanocomposite Composed of Titania Nanosheets : Multiple Conductometric Sensitivities2011

    • Author(s)
      Yukihiro Yoshida, Kazuya Kai, Hiroshi Kageyama, Gunzi Saito
    • Journal Title

      Journal of Chemical Society, Dalton Transaction

      Volume: 40 Issue: 28 Pages: 7291-7294

    • DOI

      10.1039/c1dt10686d

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shape Deformable Nanocomposite Composed of Manganese Oxide Nanosheets2011

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Journal Title

      J. Mater. Chem

      Volume: 21 Issue: 16 Pages: 5863-5866

    • DOI

      10.1039/c1jm10594a

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shape Deformable Nanocomposite Composed of Manganese Oxide Nanosheets2011

    • Author(s)
      Y.Yoshida, K.Kai, H.Kageyama, G.Saito
    • Journal Title

      Journal of Materials Chemistry

      Volume: 21 Pages: 5863-5866

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Superconductors2011

    • Author(s)
      G.Saito, Y.Yoshida
    • Journal Title

      The Chemical Record

      Volume: 11(印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of Functional Ionic Liquids Using Magneto- and Luminescent-Active Anions2010

    • Author(s)
      Y. Yoshida, G. Saito
    • Journal Title

      Phys. Chem.Chem. Phys.

      Volume: 12 Issue: 8 Pages: 1675-1684

    • DOI

      10.1039/b920046k

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Structures, and Physical Properties of Tetrakis(alkylthio) tetraselenafulvalene(TTC_n-TSeF, n=1-15)2010

    • Author(s)
      G. Saito, Y. Yoshida, 他11名
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 83 Issue: 4 Pages: 335-344

    • DOI

      10.1246/bcsj.20090240

    • NAID

      130004152704

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Structures, and Physical Properties of Tetrakis(alkylthio)tetraselenafulvalene (TTC_n-TSeF, n=1-15)2010

    • Author(s)
      G.Saito, Y.Yoshida, H.Murofushi, N.Iwasawa, T.Hiramatasu, A.Otsuka, H.Yamochi, K.Isa, E.Mineo, M.Konno, T.Mori, K.Imaeda, H.Inokuchi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 83 Pages: 335-344

    • NAID

      10027173110

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionicity Phase Diagram of Trifluoromethyl-TCNQ (CF_3TCNQ)Charge Transfer Solids2010

    • Author(s)
      G.Saito, H.Ikegami, Y.Yoshida, O.O.Drozdova, K.Nishimura, S.Horiuchi, H.Yamochi, A.Otsuka, T.Hiramatsu, M.Maesato, T.Nakamura, T.Akutagawa, T.Yumoto
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 83 Pages: 1462-1480

    • NAID

      10027653446

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 新規κ型BEDT-TTF塩の結晶構造ならびに電子物性2013

    • Author(s)
      吉田幸大
    • Organizer
      京都大学低温物質科学研究センター第11回講演会・研究交流会
    • Place of Presentation
      京都大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Functional Soft Materials-Ionic Liquids, Viscoelastic Nanocomposites, and Plastic Crystals2012

    • Author(s)
      Y.Yoshida
    • Organizer
      Half-day workshop : Development of Electronic Multifunction Based on Organic Triangular Spin Lattice
    • Place of Presentation
      名城大学
    • Year and Date
      2012-01-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] 芳香族炭化水素コロネンを用いた電荷移動型分子ローターの開発2012

    • Author(s)
      吉田幸大
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Presentation] Viscoelastic Nanocomposites Composed of Transition-Metal Oxide Nanosheets2012

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Organizer
      The International Conference on Science and Technology of Synthetic Metals (ICSM 2012)
    • Place of Presentation
      米国ジョージア州
    • Related Report
      2012 Final Research Report
  • [Presentation] Viscoelastic Nanocomposites Composed of Transition-metal Oxide Nanosheets2012

    • Author(s)
      吉田幸大
    • Organizer
      International Conference on Science and Technology of Synthetic Metals
    • Place of Presentation
      米国ジョージア州
    • Related Report
      2012 Annual Research Report
  • [Presentation] tifunctional Soft Materials-Ionic Liquids, Viscoelastic Nanocomposites, and Molecular Ro2012

    • Author(s)
      Y.Yoshida
    • Organizer
      International workshop on Multifunctional Molecular Materials Based on Triangular Lattice
    • Place of Presentation
      京都大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] External-Field-Responsive Soft Materials: Ionic Liquid and Viscoelastic Nanocomposite2011

    • Author(s)
      Y. Yoshida, K. Kai, H. Kageyama, G. Saito
    • Organizer
      The 4th International Congress on IonicLiquids (COIL-4)
    • Place of Presentation
      米国バージニア州
    • Related Report
      2012 Final Research Report
  • [Presentation] プロトン化核酸塩基を用いたNi(dmit)_2分子の配列制御2011

    • Author(s)
      吉田幸大, 前里光彦, 西村一国, 平松孝章, 矢持秀起, 齋藤軍治
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Related Report
      2011 Annual Research Report
  • [Presentation] External-Field-Responsive Soft Materials : Ionic Liquid and Viscoelastic Nanocomposite2011

    • Author(s)
      Y.Yoshida, K.Kai, H.Kageyama, G.Saito
    • Organizer
      The 4th International Congress on Ionic Liquids (COIL-4)
    • Place of Presentation
      米国バージニア州
    • Related Report
      2011 Annual Research Report
  • [Presentation] Hydrogen-Bond Architectures of Protonated Nucleobases in Ni(dmit)_2 Salts2011

    • Author(s)
      Y.Yoshida, M.Maesato, T.Hiramatsu, H.Yamochi, G.Saito
    • Organizer
      The 9th International Symposium on Crystalline Organic Metals
    • Place of Presentation
      ポーランドポズナン
    • Related Report
      2011 Annual Research Report
  • [Presentation] Valence-Tautomeric Ionic Liquid-Thermal-Induced Magnetic and OpticalChanges2010

    • Author(s)
      Y. Yoshida, H. Tanaka, G. Saito, L. Ouahab
    • Organizer
      Pacifichem2010
    • Place of Presentation
      米国ハワイ州
    • Related Report
      2012 Final Research Report
  • [Presentation] Valence-Tautomeric Ionic Liquid Composed of Cobalt Bis(dioxolene) Complex Dianion2010

    • Author(s)
      Y. Yoshida, H. Tanaka, G. Saito, L. Ouahab, H. Yoshida, N. Sato
    • Organizer
      The International Conference on Science and Technology of Synthetic Metals (ICSM 2010)
    • Place of Presentation
      京都国際会館
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] Valence-tautomeric Ionic Liquid-Thermal-induced Magnetic and Optical Changes2010

    • Author(s)
      Y.Yoshida, H.Tanaka, G.Saito, L.Ouahab
    • Organizer
      Pacifichem2010
    • Place of Presentation
      米ハワイ州ホノルル
    • Related Report
      2010 Annual Research Report
  • [Book] Yoshida,TopicsofCurrentChemistry:UnimolecularandMacromolecularElectronics2012

    • Author(s)
      G.Saito,Y.
    • Publisher
      SpringerVerlag
    • Related Report
      2012 Final Research Report
  • [Book] Superconductors-Materials, Properties and Applications2012

    • Author(s)
      G. Saito, Y. Yoshida
    • Publisher
      InTech
    • Related Report
      2012 Final Research Report
  • [Book] Unimolecular and Supramolecular Electronics II: Chemistry and Physics Meet at Metal-Molecule Interfaces (Topics in Current Chemistry)2012

    • Author(s)
      G. Saito, Y. Yoshida
    • Total Pages
      60
    • Publisher
      Springer-Verlag
    • Related Report
      2012 Annual Research Report
  • [Book] Superconductors –Materials, Properties and Applications2012

    • Author(s)
      G. Saito, Yoshida
    • Total Pages
      32
    • Publisher
      INTECH
    • Related Report
      2012 Annual Research Report
  • [Book] Ionic Liquids -Theory, Properties, New Approaches2011

    • Author(s)
      Y. Yoshida, G. Saito
    • Publisher
      InTech
    • Related Report
      2012 Final Research Report
  • [Book] Ionic Liquids, Theory and Applications2011

    • Author(s)
      Y.Yoshida, G.Saito
    • Total Pages
      16
    • Publisher
      InTech
    • Related Report
      2010 Annual Research Report
  • [Book] Unimolecular and Supramolecular Electronics2011

    • Author(s)
      G.Saito, Y.Yoshida
    • Publisher
      Springer Verlag(印刷中)
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://saitolab.meijo-u.ac.jp/index.html

    • Related Report
      2011 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2019-07-29  

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