Design of novel Ag catalysts for green organic synthesis and automotive emission control

• Project/Area Number: 22686075
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Catalyst/Resource chemical process
• Research Institution: Hokkaido University
• Principal Investigator: SHIMIZU Ken-ichi 北海道大学, 触媒化学研究センター, 准教授 (60324000)
• Project Period (FY): 2010 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥25,740,000 (Direct Cost: ¥19,800,000、Indirect Cost: ¥5,940,000); Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2011: ¥14,300,000 (Direct Cost: ¥11,000,000、Indirect Cost: ¥3,300,000); Fiscal Year 2010: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
• Keywords: 銀ナノクラスター / 有機合成 / 自動車排ガス浄化 / 白金代替触媒 / 触媒設計 / 銀触媒 / ナノクラスター / 固体触媒 / 反応機構 / 低温燃焼

Research Abstract

I developed heterogeneous Ag catalysts for green organic reactions having higher performance than platinum-group-metal complexes. Also, I developed Ag catalysts for automotive emission control having higher activity and sintering-resistance than platinum-group-metal catalysts. Mechanistic and structural studies established catalyst design concepts on the basis of cooperative catalysis of metal cluster metal oxides at metal-support interface.

Research Products

• [Journal Article] 銀クラスター触媒による環境調和型有機合成 (2013)
  • Author(s): 清水研一
  • Journal Title: ペテロテック Volume: 36 Pages: 12-12
  • NAID: 10031166846
• [Journal Article] Acceptor-free dehydrogenation of secondary alcohols by heterogeneous cooperative catalysis between Ni nanoparticles and acid-base sites of aluminasupports (2013)
  • Author(s): Ken-ichi Shimizu, Kenichi Kon, Katsuya Shimura, Siddiki S.M.A. Hakim
  • Journal Title: J. Catal Volume: 300 Pages: 242-249
  • DOI: 10.1016/j.jcat.2013.01.005
  • Peer Reviewed
• [Journal Article] Heterogeneous cobalt catalyst for accepterless dehydrogenation of alcohols (2013)
  • Author(s): Ken-ichi Shimizu, Kenichi Kon, Mayumi Seto, Katsuya Shimura, Hiroshi Yamazaki, Junko N. Kondo
  • Journal Title: Green Chem. Volume: 15 Issue: 2 Pages: 418-424
  • DOI: 10.1039/c2gc36555c
  • Peer Reviewed
• [Journal Article] Heterogeneous Ni catalyst for Direct Synthesis of Primary Amines from Alcohols and Ammonia (2013)
  • Author(s): Ken-ichi Shimizu, Kenichi Kon, Wataru Onodera, Hiroshi Yamazaki, Junko N. Kondo
  • Journal Title: ACS Catal Volume: 3 Issue: 1 Pages: 112-117
  • DOI: 10.1021/cs3007473
  • Peer Reviewed
• [Journal Article] Surface Oxygen Atom as Cooperative Ligand in Pd Nanoparticles Catalysis for Selective Hydration of Nitriles to Amides in Water: Experimental and Theoretical Studies (2012)
  • Author(s): K. Shimizu et al
  • Journal Title: ACS Catalysis Volume: 2 Issue: 12 Pages: 2467-2474
  • DOI: 10.1021/cs3006154
  • Peer Reviewed
• [Journal Article] Transfer hydrogenation of ketones by ceria-supported Ni catalyst (2012)
  • Author(s): Katsuya Shimura, Ken-ichi Shimizu
  • Journal Title: Green Chem Volume: 14 Issue: 11 Pages: 2983-2985
  • DOI: 10.1039/c2gc35836k
  • Peer Reviewed
• [Journal Article] Heterogeneous Nickel Catalyst for Selective Hydration of Silanes to Silanols (2012)
  • Author(s): Ken-ichi Shimizu, Katsuya Shimura, Naomichi Imaiida, Atsushi Satsuma
  • Journal Title: J. Mol.Catal. A Volume: 365 Pages: 50-54
  • DOI: 10.1016/j.molcata.2012.08.007
  • Peer Reviewed
• [Journal Article] Volcano-Curves for Dehydrogenation of2-Propanol and Hydrogenation of Nitrobenzene by SiO2-Supported Metal Nanoparticles Catalysts As Described in Terms of a d-Band Model (2012)
  • Author(s): Masazumi Tamura, Kenichi Kon, Atsushi Satsuma, Ken-ichi Shimizu
  • Journal Title: ACS Catal Volume: 2 Issue: 9 Pages: 1904-1909
  • DOI: 10.1021/cs300376u
  • Peer Reviewed
• [Journal Article] Comprehensive IR study on acid/base properties of metal oxides (2012)
  • Author(s): Masazumi Tamura, Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Appl. Catal Volume: A 433-434 Pages: 135-145
  • DOI: 10.1016/j.apcata.2012.05.008
  • Peer Reviewed
• [Journal Article] The average Pd oxidation state in Pd/SiO2 quantified by L3-edge XANES analysis and its effects on catalytic activity for CO oxidation (2012)
  • Author(s): Ken-ichi Shimizu, Yuichi Kamiya, Kaoru Osaki, Hisao Yoshda, Atsushi Satsuma
  • Journal Title: Catal. Sci. Technol Volume: 2 Issue: 4 Pages: 767-772
  • DOI: 10.1039/c2cy00422d
  • Peer Reviewed
• [Journal Article] Size-and support-dependent selective amine cross-coupling with platinum nanocluster catalysts (2012)
  • Author(s): Ken-ichi Shimizu, Keiichiro Ohshima, Yutaka Tai, Masazumi Tamura, Atsushi Satsuma
  • Journal Title: Catal. Sci.Technol Volume: 2 Issue: 4 Pages: 730-738
  • DOI: 10.1039/c2cy00476c
  • Peer Reviewed
• [Journal Article] CeO2-catalysed one-pot selective synthesis of esters from nitriles and alcohols (2012)
  • Author(s): Masazumi Tamura, Takuya Tonomura, Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: GreenChem Volume: 14 Issue: 4 Pages: 984-991
  • DOI: 10.1039/c2gc16424h
  • Peer Reviewed
• [Journal Article] Hydration of nitriles to amides in water by SiO_2-supported Ag catalysts promoted by adsorbed oxygen atoms (2012)
  • Author(s): Ken-ichi Shimizu, Naomichi Imaiida, Kyoichi Sawabe, Atsushi Satsuma
  • Journal Title: Appl Catal A Volume: 421-422 Pages: 114-120
  • DOI: 10.1016/j.apcata.2012.02.007
  • Peer Reviewed
• [Journal Article] Transamidation of amides with amines under solvent-free conditions using a CeO_2 catalyst (2012)
  • Author(s): Masazumi Tamura, Takuya Tonomura,Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Green Chem Volume: 14 Issue: 3 Pages: 717-724
  • DOI: 10.1039/c2gc16316k
  • Peer Reviewed
• [Journal Article] Surface Oxygen-Assisted Pd Nanoparticle Catalysis for Selective Oxidation of Silanes to Silanols (2012)
  • Author(s): Ken-ichi Shimizu, Takahiro Kubo, Atsushi Satsuma
  • Journal Title: Chem. Eur.J Volume: 18 Issue: 8 Pages: 2226-2229
  • DOI: 10.1002/chem.201103088
  • Peer Reviewed
• [Journal Article] CeO2-catalyzed one-pot selective synthesis of N-alkyl amides from nitriles, amines and water (2012)
  • Author(s): Masazumi Tamura, Takuya Tonomura, Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Appl. Catal. A Volume: 417-418 Pages: 6-12
  • DOI: 10.1016/j.apcata.2011.12.004
  • Peer Reviewed
• [Journal Article] Sulfur promoted Pt/SiO2 catalyzed cross-coupling of anilines and amines (2012)
  • Author(s): Ken-ichi Shimizu, Katsuya Shimura, Naoko Tamagawa, Masazumi Tamura, Atsushi Satsuma
  • Journal Title: Appl.Catal. A Volume: 417-418 Pages: 37-42
  • DOI: 10.1016/j.apcata.2011.12.019
  • Peer Reviewed
• [Journal Article] Electronic effect of Na promotion for selective mono-N-alkylation of aniline with di-iso-propylamine by Pt/SiO_2 catalysts (2012)
  • Author(s): Ken-ichi Shimizu, Katsuya Shimura, Kazuo Kato, Naoko Tamagawa, Masazumi Tamura, Atsushi Satsuma
  • Journal Title: J. Mol. Catal. A Volume: 353-354 Pages: 171-177
  • DOI: 10.1016/j.molcata.2011.11.021
  • Peer Reviewed
• [Journal Article] Quantitative determination of average rhodium oxidation state by a simple XANES analysis (2012)
  • Author(s): Ken-ichi Shimizu, Tomonori Oda, Yoshinori Sakamoto, Yuichi Kamiya, Hisao Yoshida, Atsushi Satsuma
  • Journal Title: Appl.Catal. B Volume: 111-112 Pages: 509-514
  • DOI: 10.1016/j.apcatb.2011.11.002
  • Peer Reviewed
• [Journal Article] CeO2-catalyzed Transformations of Nitriles and Amides (2012)
  • Author(s): M. Tamura, K. Shimizu, A. Satsuma
  • Journal Title: Chem. Lett Volume: 41 Issue: 11 Pages: 1397-1405
  • DOI: 10.1246/cl.2012.1397
  • NAID: 10031126543
  • Peer Reviewed
• [Journal Article] 自動車排ガス浄化用自己再生型Agナノクラスター触媒 (2012)
  • Author(s): 清水研一,沢邊恭一,薩摩篤
  • Journal Title: 化学工業 Volume: 63 Pages: 312-312
  • NAID: 130007008133
• [Journal Article] 自動車排ガス浄化用Ag触媒 (2012)
  • Author(s): 清水研一,沢邊恭一,薩摩篤
  • Journal Title: 高活性化とシンタリング抑制の方策 Volume: 54 Pages: 228-228
• [Journal Article] Silver Cluster Catalysts for Green Organic Synthesis (2011)
  • Author(s): Ken-ichi Shimizu and Atsushi Satsuma
  • Journal Title: Journal of the Japan PetroleumInstitute Volume: 54 Pages: 347-360
  • NAID: 10030180479
  • Peer Reviewed
• [Journal Article] Toward a rational control of solid acid catalysis for green synthesis and biomass conversion (2011)
  • Author(s): Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Energy Environ. Sci Volume: 4 Issue: 9 Pages: 3140-3153
  • DOI: 10.1039/c1ee01458g
  • Peer Reviewed
• [Journal Article] Unique catalytic features of Ag nanoclusters for selective NOx reduction and green chemical reactions (2011)
  • Author(s): Kenichi Shimizu, Kyoichi Sawabe, Atsushi Satsuma
  • Journal Title: Catal. Sci.Technol Volume: 1 Issue: 3 Pages: 331-341
  • DOI: 10.1039/c0cy00077a
  • Peer Reviewed
• [Journal Article] Direct Synthesis of N-Substituted Anilines from Nitroaromatics and Alcohols under H_2 by Alumina-Supported Silver Cluster Catalyst (2011)
  • Author(s): Kenichi Shimizu, Katsuya Shimura, Masanari Nishimura, Atsushi Satsuma
  • Journal Title: ChemCatChem Volume: 3 Issue: 11 Pages: 1755-1758
  • DOI: 10.1002/cctc.201100171
  • Peer Reviewed
• [Journal Article] Silver Cluster-Promoted Heterogeneous Copper Catalyst for N-Alkylation of Amines with Alcohols (2011)
  • Author(s): Kenichi Shimizu, Katsuya Shimura, Masanari Nishimura, and Atsushi Satsuma
  • Journal Title: RSC Advances Volume: 1 Issue: 7 Pages: 1310-1317
  • DOI: 10.1039/c1ra00560j
  • Peer Reviewed
• [Journal Article] Selective cross-coupling of amines by alumina-supported palladium nanocluster catalysts (2011)
  • Author(s): Ken-ichi Shimizu, Katsuya Shimura , Keiichiro Ohshima, Masazumi Tamura Atsushi Satsuma
  • Journal Title: Green Chem Volume: 13 Issue: 11 Pages: 3096-3100
  • DOI: 10.1039/c1gc15835j
  • Peer Reviewed
• [Journal Article] Efficient and Substrate-Specific Hydration of Nitriles to Amides in Water by CeO_2Catalyst (2011)
  • Author(s): Masazumi Tamura, Hiroko Wakasugi, Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Chem. Eur. J Volume: 17 Issue: 41 Pages: 11428-11431
  • DOI: 10.1002/chem.201101576
  • Peer Reviewed
• [Journal Article] Sintering-resistant and self-regenerative properties of Ag/SnO_2 catalyst for soot oxidation (2011)
  • Author(s): Ken-ichi Shimizu, Makoto Katagiri, Shigeo Satokawa, Atsushi Satsuma
  • Journal Title: Appl. Catal. B Volume: 108-109 Pages: 39-46
  • DOI: 10.1016/j.apcatb.2011.08.003
  • Peer Reviewed
• [Journal Article] Carbon oxidation with Ag/ceria prepared by self-dispersion of Ag powder into nano-particles (2011)
  • Author(s): Ken-ichi Shimizu, Hiroshi Kawachi, Shin-ichi Komai, Kaname Yoshida, Yukichi Sasaki, Atsushi Satsuma
  • Journal Title: Catal.Today Volume: 175 Issue: 1 Pages: 93-99
  • DOI: 10.1016/j.cattod.2011.03.053
  • Peer Reviewed
• [Journal Article] Self-Regenerative Silver Nanocluster Catalyst for CO oxidation (2011)
  • Author(s): Ken-ichi Shimizu, Kyoichi Sawabe, Atsushi Satsuma
  • Journal Title: ChemCatChem Volume: 3 Issue: 8 Pages: 1290-1293
  • DOI: 10.1002/cctc.201100122
  • Peer Reviewed
• [Journal Article] Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime by alumina-supported gold cluster catalysts (2011)
  • Author(s): Ken-ichi Shimizu, Takumi Yamamoto, Yutaka Tai, Atsushi Satsuma
  • Journal Title: J. Mol. Catal. A Volume: 345 Issue: 1-2 Pages: 54-59
  • DOI: 10.1016/j.molcata.2011.05.018
  • Peer Reviewed
• [Journal Article] Addition of olefins to acetylacetone catalyzed by cooperation of Bronsted acid site of zeolite and gold cluster (2011)
  • Author(s): Ken-ichi Shimizu, Takumi Yamamoto, Yutaka Tai, Kazu Okumura, Atsushi Satsuma
  • Journal Title: Applied Catalysis A : General Volume: 400 Issue: 1-2 Pages: 171-175
  • DOI: 10.1016/j.apcata.2011.04.029
  • Peer Reviewed
• [Journal Article] Density functional theory calculation on the promotion effect of H_2 in the selective catalytic reduction of NOx over Ag-MFI zeolite (2010)
  • Author(s): Kyoichi Sawabe, Taisuke Hiro, Ken-ichi Shimizu, Atsushi Satsuma
  • Journal Title: Catalysis Today Volume: 153 Issue: 3-4 Pages: 90-94
  • DOI: 10.1016/j.cattod.2010.03.078
  • Peer Reviewed
• [Journal Article] Study of active sites and mechanism for soot oxidation by silver-loaded ceria catalyst (2010)
  • Author(s): Ken-ichi Shimizu, Hiroshi Kawachi, Atsushi Satsuma
  • Journal Title: Appl. Catal. B Volume: 96 Issue: 1-2 Pages: 169-175
  • DOI: 10.1016/j.apcatb.2010.02.016
  • Peer Reviewed
• [Journal Article] Size-and support-dependent silver cluster catalysis for chemoselective hydrogenation of nitroaromatics (2010)
  • Author(s): Ken-ichi Shimizu, Yuji Miyamoto, and Atsushi Satsuma
  • Journal Title: J. Catal Volume: 270 Issue: 1 Pages: 86-94
  • DOI: 10.1016/j.jcat.2009.12.009
  • Peer Reviewed
• [Journal Article] Size- and support-dependent silver cluster catalysis for chemoselective hydrogenation of nitroaromatics (2010)
  • Author(s): Ken-ichi Shimizu, Yuji Miyamoto, Atsushi Satsuma
  • Journal Title: J.Catal. Volume: 270 Pages: 86-94
  • Peer Reviewed
• [Journal Article] Study of active sites and mechanism for soot oxidation by silver-loaded ceria catalyst (2010)
  • Author(s): Ken-ichi Shimizu, Hiroshi Kawachi, Atsushi Satsuma
  • Journal Title: Appl.Catal.B Volume: 96 Pages: 169-175
  • Peer Reviewed
• [Presentation] 非白金族固体触媒を用いたグリーン有機合成 (2012)
  • Author(s): 清水研一
  • Organizer: 石油学会北海道支部函館地区学術講演会
  • Place of Presentation: 北海道教育大学函館校
  • Year and Date: 2012-01-17
• [Presentation] 非白金族固体触媒を用いたグリーン有機合成 (2012)
  • Author(s): 清水研一
  • Organizer: 石油学会北海道支部函館地区学術講演会
  • Place of Presentation: 北海道教育大学函館校(函館市)(招待講演)
  • Year and Date: 2012-01-17
• [Presentation] Metal cluster catalysis for green organic reactions (2012)
  • Author(s): Kenichi Shimizu
  • Organizer: CRC-FHI Joint Meeting, Complex Surfaces in Material Science
  • Place of Presentation: Fritz Haber Institute, Berlin, Germany
• [Presentation] 自動車排ガス浄化とGreen 有機合成に有効な非白金族固体触媒の開発 (2012)
  • Author(s): 清水研一
  • Organizer: 第6回 分子科学会シンポジウム
  • Place of Presentation: 早稲田大学西早稲田キャンパス(東京都新宿区)
  • Invited
• [Presentation] Catalysis of metal cluster and nanoparticles for green organic reactions (2012)
  • Author(s): Ken-ichi Shimizu
  • Organizer: 14th Asian Chemical Congress
  • Place of Presentation: Putra World Trade Centre, Kuala Lumpur, Malaysia
  • Invited
• [Presentation] 自動車排ガス浄化用自己再生型Agナノクラスター触媒 (2011)
  • Author(s): 清水研一
  • Organizer: 第31回表面科学学術講演会
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2011-12-16
• [Presentation] 銀クラスター・卑金属ナノ粒子・酸化セリウムを固体触媒に用いた環境調和型有機合成 (2011)
  • Author(s): 清水研一
  • Organizer: 新化学技術推進協会先端化学・材料技術部会・高選択性反応分科会講演会
  • Place of Presentation: 新化学技術推進協会(JACI)
  • Year and Date: 2011-12-01
• [Presentation] 自己再生型Ag系燃焼触媒の発見と白金代替触媒の設計を指向した基礎研究 (2011)
  • Author(s): 清水研一
  • Organizer: 東京工業大学資源化学研究所講演
  • Place of Presentation: 東京工業大学
  • Year and Date: 2011-11-14
• [Presentation] 環境調和型銀クラスター触媒 (2011)
  • Author(s): 清水研一
  • Organizer: 第51回オーロラセミナー
  • Place of Presentation: ハイランドふらの(北海道富良野市)(招待講演)
  • Year and Date: 2011-07-24
• [Presentation] 担持銀クラスター触媒による環境調和型有機合成 (2011)
  • Author(s): 清水研一
  • Organizer: 第5回工業触媒研究会研修会
  • Place of Presentation: 和光純薬工業湯河原研修所
  • Year and Date: 2011-06-10
• [Presentation] 担持銀クラスター触媒による環境調和型有機合成 (2011)
  • Author(s): 清水研一
  • Organizer: 第5回工業触媒研究会研修会
  • Place of Presentation: 和光純薬工業湯河原研修所(静岡県)(招待講演)
  • Year and Date: 2011-06-10
• [Presentation] Heterogeneous catalysis of Ag nanoclusters for green synthesis (2011)
  • Author(s): Kenichi Shimizu
  • Organizer: 14th Asian Chemical Congress
  • Place of Presentation: Queen Sirikit National ConventionCenter, Bangkok, Thailand
• [Presentation] Heterogeneous catalysis of Ag nanoclusters for green synthesis (2011)
  • Author(s): Kenichi Shimizu
  • Organizer: 14ACC-Cambodia Satellite Meeting
  • Place of Presentation: Sofitel Angkor Hotel , SiemReap, Cambodia
• [Presentation] 若手研究者による講演,触媒 (2010)
  • Author(s): 清水研一
  • Organizer: 学会産学交流サロン
  • Place of Presentation: 中央大学駿河台記念館
  • Year and Date: 2010-12-03
• [Presentation] 銀触媒による脱硝および環境調和型有機合成反応に関する研究 (2010)
  • Author(s): 清水研一
  • Organizer: 触媒学会産学交流サロン
  • Place of Presentation: 中央大学駿河台記念館(招待講演)
  • Year and Date: 2010-12-03
• [Presentation] 有機合成用銀触媒設計のための作業仮説 (2010)
  • Author(s): 清水研一
  • Organizer: 第7回触媒相模セミナー
  • Place of Presentation: 公益財団法人相模中央化学研究所
  • Year and Date: 2010-11-18
• [Presentation] 有機合成用銀触媒設計のための作業仮説 (2010)
  • Author(s): 清水研一
  • Organizer: 第7回触媒相模セミナー
  • Place of Presentation: 相模中央化学研究所(招待講演)
  • Year and Date: 2010-11-18
• [Presentation] 銀クラスター触媒による脱硝および環境調和型有機合成反応に関する研究 (2010)
  • Author(s): 清水研一
  • Organizer: 第106回触媒討論会1A07
  • Place of Presentation: 山梨大学
  • Year and Date: 2010-09-15
• [Presentation] 銀クラスター触媒による脱硝および環境調和型有機合成反応に関する研究 (2010)
  • Author(s): 清水研一
  • Organizer: 第106回触媒討論会
  • Place of Presentation: 山梨大学(招待講演)
  • Year and Date: 2010-09-15
• [Presentation] 銀触媒による環境調和型有機合成における触媒設計の考え方 (2010)
  • Author(s): 清水研一
  • Organizer: 平成22年度第1回キャタリストクラブ例会
  • Place of Presentation: 大阪科学技術センター
  • Year and Date: 2010-05-07
• [Presentation] Catalysis of metal cluster and nanoparticles for green organic reactions (2010)
  • Author(s): Kenichi Shimizu
  • Organizer: 17th Malaysian Chemical Congress (17MCC)
  • Place of Presentation: Putra World Trade Centre, Kuala Lumpur, Malaysia
• [Presentation] Size- and Support-Dependent Silver Cluster Catalysis for Selective Hydrogenation of Nitroaromatics (2010)
  • Author(s): Kenichi Shimizu, Yuji Miyamoto, Atsushi Satsuma
  • Organizer: The Sixth Tokyo Conference on Advanced Catalytic Science and Technology & The Fifth Asia Pacific Congress on Catalysis
  • Place of Presentation: Sapporo Convention Center
• [Remarks]
  • URL: http://www.cat.hokudai.ac.jp/shimizu/
• [Remarks]
  • URL: http://www.cat.hokudai.ac.jp/shimizu/
• [Remarks]
  • URL: http://www.cat.hokudai.ac.jp/shimizu/