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How does the hydrogen bonding give changes to valence electrons?

Research Project

Project/Area Number 22750019
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionKwansei Gakuin University

Principal Investigator

MORISAWA Yusuke  関西学院大学, 理工学研究科, 博士研究員 (60510021)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords電子状態 / 液体 / 液相分子ダイナミクス / 減衰全反射遠紫外分光法 / 電子励起状態 / 凝縮相 / 水素結合
Research Abstract

Effect of intermolecular interaction, such as hydrogen bonds and van der Waals forces to valence electrons were investigated by using an attenuated total reflection spectrometer in far-UV(ATR-FUV). After developing the ATR-FUV equipment for measurements in low temperature(~-70℃), ATR-FUV spectra of liquid acetone and, solid and liquid alkanes were observed. Comparing the results of electronic states in low-temperature liquids and high level quantum chemical calculations, we got a new insight about the effect of intermolecular interaction to valence electrons.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (47 results)

All 2012 2011 2010 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (31 results) Remarks (5 results)

  • [Journal Article] Far-Ultraviolet Spectroscopy in the Solid and Liquid States : A Review2012

    • Author(s)
      Yukihiro Ozaki, Yusuke Morisawa, Akifumi Ikehata, Noboru Higashi
    • Journal Title

      Applied Spectroscopy

      Volume: Vol.66 Pages: 1-25

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Far-Ultraviolet Spectroscopy in the Solid and Liquid States : A Review2012

    • Author(s)
      森澤勇介、尾崎幸洋
    • Journal Title

      Applied Spectroscopy

      Volume: 66 Issue: 1 Pages: 1-25

    • DOI

      10.1366/11-06496

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 液体・固用遠紫外分光法の開発とそ分析化学へ応用2012

    • Author(s)
      森澤勇介、立花慎
    • Journal Title

      分析化学

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-n Rydberg Transitions of Liquid Ketones Studied by Attenuated Total Reflection Far-Ultraviolet Spectroscopy2011

    • Author(s)
      Yusuke Morisawa, Akifumi Ikehata, Higashi Noboru, Ozaki Yukihiro
    • Journal Title

      Journal of Physical Chemistry A

      Volume: Vol.115 Pages: 562-568

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Far-Ultraviolet Spectra of n-Alkanes and Branched Alkanes in the Liquid Phase Observed by an Attenuated Total Reflectance-Far Ultraviolet Spectrometer2011

    • Author(s)
      Shin Tachibana, Yusuke Morisawa, Akifumi Ikehata, Harumi Sato, Noboru Higashi, Yukihiro Ozaki
    • Journal Title

      Applied Spectroscopy

      Volume: Vol.65 Pages: 221-223

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-n Rydberg Transitions of Liquid Ketones Studied by Attenuated Total Reflection Far-Ultraviolet Spectroscopy2011

    • Author(s)
      森澤勇介
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 115 Pages: 562-568

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Far-Ultraviolet Spectra of n-Alkanes and Branched Alkanes in the Liquid Phase Observed by an Attenuated Total Reflectance-Far Ultraviolet Spectrometer2011

    • Author(s)
      立花慎
    • Journal Title

      Applied Spectroscopy

      Volume: 65 Pages: 221-226

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative Analysis of Ions in Spring Water in Three Different Areas of Hyogo Prefecture in Japan by Far Ultraviolet Spectroscop2011

    • Author(s)
      光岡基樹
    • Journal Title

      Analytical Science

      Volume: 27 Pages: 177-182

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 遠紫外分光法による水及び水溶液の分析2011

    • Author(s)
      池羽田晶文
    • Journal Title

      分析化学

      Volume: 60 Pages: 19-31

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 減衰全反射遠紫外(ATR-FUV)分光法を用いた有機液体の許容遷移の実験的研究と量子化学計算を用いた遷移の帰属2011

    • Author(s)
      森澤勇介
    • Journal Title

      日本化学会第91春季年会(2011)講演予稿集

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Effect of Cations on Absorption Bands of First Elecronic Transition of Liquid Water2010

    • Author(s)
      池羽田晶文
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 114 Pages: 8319-8322

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 減衰全反射遠紫外分光法による凝縮相における飽和アルカンの電子遷移の研究2012

    • Author(s)
      森澤勇介、立花慎、江原正博、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水溶液溶存アミノ酸の減衰全反射遠紫外スペクトル2011

    • Author(s)
      後藤剛喜、池羽田晶文、森澤勇介、東昇、尾崎幸洋
    • Organizer
      日本分光学会平成23年度年次講演会
    • Place of Presentation
      理化学研究所横浜研究所
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水溶液の減衰全反射遠紫外分光2011

    • Author(s)
      池羽田晶文、後藤剛喜、森澤勇介、東昇、尾崎幸洋
    • Organizer
      日本分光学会平成23年度年次講演会
    • Place of Presentation
      理化学研究所横浜研究所
    • Year and Date
      2011-12-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水分子の価電子遷移に対するカチオンの影響に関する遠紫外分光分析2011

    • Author(s)
      後藤剛喜、池羽田晶文、森澤勇介、尾崎幸洋
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Solvent and Temperature Dependences of Attenuated Total Reflection Far-Ultraviolet Spectra for N-methylacetamide and N, N-dimethylacetamid2011

    • Author(s)
      泰永愛佳、森澤勇介、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      FACSS2011
    • Place of Presentation
      Reno NV(アメリカ合衆国)
    • Year and Date
      2011-10-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液体ハロアルカンの減衰全反射遠紫外スペクトル-スペクトルの炭素骨格依存性-2011

    • Author(s)
      立花慎、森澤勇介、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 遠紫外分光法によるランタノイドカチオンが水分子の電子遷移に及ぼす影響に関する考察2011

    • Author(s)
      後藤剛喜、池羽田晶文、森澤勇介、東昇、尾崎幸洋
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] ATR遠紫外分光装置の開発とその産業応用2011

    • Author(s)
      東昇、池羽田晶文、森澤勇介、尾崎幸洋
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] 液体アルコールの減衰全反射遠紫外スペクトルの帰属2011

    • Author(s)
      森澤勇介、立花慎、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] 遠紫外分光法による水分子の電子遷移に対する水和カチオンの影響に関する考察2011

    • Author(s)
      後藤剛喜、池羽田晶文、森澤勇介、東昇、尾崎幸洋
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] A Study of Allowed Electronic Transition of Organic liquid by using Attenuated Total Reflection in Far-Ultraviolet region.~ structure of liquid and electronic transition2011

    • Author(s)
      Yusuke Morisawa, Akifumi Ikehata, Takeyoshi Goto, Noboru Higashi, Yukihiro Ozaki
    • Organizer
      32nd International Conference on Solution Chemistry(oral presentation)
    • Place of Presentation
      Reno, NV, USA
    • Year and Date
      2011-08-30
    • Related Report
      2011 Final Research Report
  • [Presentation] A Study of Allowed Electronic Transition of Organic liquid by using Attenuated Total Reflection in Far-Ultraviolet region : ~structure of liquid and electronic transition~2011

    • Author(s)
      森澤勇介、池羽田晶文、後藤剛喜、東昇、尾崎幸洋
    • Organizer
      ICSC2011
    • Place of Presentation
      La-Grande Motto(フランス)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] Experimental and Theoretical Study of Allowed Electronic Transitions of Organic Liquids in Far-Ultraviolet Region with Attenuated Total Reflection Technique2011

    • Author(s)
      Yusuke Morisawa, Akifumi Ikehata, Noboru Higashi, Yukihiro Ozaki
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Attenuated Total Reflection for Ultraviolet Spectroscopy : A New Analytical Method for Liquid Samples2011

    • Author(s)
      池羽田晶文、東昇、森澤勇介、後藤剛喜、尾崎幸洋
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Concentrative Effects of Acids on Electronic Transition of Aqueous Solution2011

    • Author(s)
      後藤剛喜、池羽田晶文、森澤勇介、東昇、尾崎幸洋
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spectral Correction for ATR-FUV Spectra Based on Kramers-Kronig Transformation Using CTTS Band of Halide Ions2011

    • Author(s)
      池羽田晶文、後藤剛喜、森澤勇介、東昇、尾崎幸洋
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Study of Concentration Dependence on Solvent Effect of N-methylacetoamide and N, N-dimethylacetoamide by Attenuated Total Reflection-Far Ultraviolet Spectroscopy2011

    • Author(s)
      泰永愛佳、森澤勇介、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spectra Analysis for Liquid Alkanes in Far Ultraviolet Eegion ; Attenuated Total Reflectance-Far Ultraviolet Spectra and Ab-initio Calculation2011

    • Author(s)
      立花慎、森澤勇介、池羽田晶文、東昇、尾崎幸洋
    • Organizer
      IUPAC International Congress on Analytical Sciences
    • Place of Presentation
      京都国際会館
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ATR遠紫外分光法を用いたN-メチルアセトアミドおよびN,N-ジメチルアセトアミドの電子遷移エネルギーの溶媒依存性2010

    • Author(s)
      森澤勇介
    • Organizer
      平成22年度日本分光学会年次講演会
    • Place of Presentation
      京都大学(京都府)
    • Year and Date
      2010-11-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Effects of hydrogen bondings on an electronic state of acetone studied by using attenuated total reflection-far ultraviolet spectroscopy2010

    • Author(s)
      Yusuke Morisawa, Akifumi Ikehata, Noboru Higashi, Yukihiro Ozaki
    • Organizer
      FACSS2010
    • Place of Presentation
      Raleigh Conventional Center, USA
    • Year and Date
      2010-10-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Spectroscopic study of the electronic states of liquid ketones and ethers by using attenuated total reflection-far ultraviolet spectroscopy2010

    • Author(s)
      森澤勇介
    • Organizer
      FACSS2010, Tommorrow's Analytical Sciences Today!
    • Place of Presentation
      Raleigh Conventional Center (Raleigh, NC)
    • Year and Date
      2010-10-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Effects of hydrogen bondings on an electronic state of acetone studied by using attenuated total reflection-far ultraviolet spectroscopy2010

    • Author(s)
      森澤勇介
    • Organizer
      FACSS2010, Tommorrow's Analytical Sciences Today!
    • Place of Presentation
      Raleigh Conventional Center (Raleigh, NC)
    • Year and Date
      2010-10-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Novel observations of absorption bands of liquid alkanes and polyethylene by attenuated total reflectance-far UV2010

    • Author(s)
      立花慎
    • Organizer
      FACSS2010, Tommorrow's Analytical Sciences Today!
    • Place of Presentation
      Raleigh Conventional Center (Raleigh, NC)
    • Year and Date
      2010-10-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Study of electronic states of N-methylacetamide and N,N-dimethylacet-amid in the Liquid phase by using ATR-FUV Spectroscopy2010

    • Author(s)
      森澤勇介
    • Organizer
      Molecular Photoscience Research Center International Symposium "New Horizons of Cluster Chemistry"
    • Place of Presentation
      神戸大学(兵庫県)
    • Year and Date
      2010-10-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水溶性有機分子の遠紫外光分解に関するATR-FUV分光分析2010

    • Author(s)
      後藤剛喜
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 時間分解ATR-FUV分光システムの開発2010

    • Author(s)
      森澤勇介
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 減衰全反射遠紫外分光法による各種液体アルカンの分光研究2010

    • Author(s)
      立花慎
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] ハロゲン化物イオンが溶媒の第一遷移吸収帯に及ぼす影響2010

    • Author(s)
      池羽田晶文
    • Organizer
      日本分析化学会第59年会
    • Place of Presentation
      東北大学(宮城県)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] ケトン類・エーテル類の遠紫外減衰全反射スペクトルの解析2010

    • Author(s)
      森澤勇介、東昇、池羽田晶文、尾崎幸洋
    • Organizer
      第71会分析化学討論会
    • Place of Presentation
      島根大学(島根県)
    • Year and Date
      2010-05-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 遠紫外減衰全反射分光法による液体アルカンとポリエチレンの電子状態研究2010

    • Author(s)
      立花慎
    • Organizer
      第71会分析化学討論会
    • Place of Presentation
      島根大学(島根県)
    • Year and Date
      2010-05-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジメチルスルフォキシドを利用したOHラジカルの分光測定方法2010

    • Author(s)
      苅山直美
    • Organizer
      第71会分析化学討論会
    • Place of Presentation
      島根大学(島根県)
    • Year and Date
      2010-05-15
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://sci-tech.ksc.kwansei.ac.jp/~ozaki/FUVmenu.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      https://www.kwansei.info/html/37125.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://sci-tech.ksc.kwansei.ac.jp/~ozaki/FUVmenu.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      https://www.kwansei.info/html/37125.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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