| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Research Abstract |
Terminal metal nitrides(M≡N) and imides(M=NR) have been invoked as intermediates in synthetic or biological transformations. We focused on the iron-nitrogen multiple bond chemistry. First, new ligands consisted of aryloxides were prepared as supporting ligands for the iron complexes. Iron complexes with bulky aryloxides can be applied for synthesis of highly reactive iron nitrides, which were structurally characterized by X-ray crystallographic analysis.
|
