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Challenge to a Complete Separation of Carbon Dioxide Using Flexible Metal Complexes as Adsorbents

Research Project

Project/Area Number 22750114
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

NORO Shin-ichiro  北海道大学, 電子科学研究所, 准教授 (70373347)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords表面 / 界面 / 金属錯体 / 銅イオン / 二酸化炭素分離
Research Abstract

Separation of CO_2 gas from gas mixtures has been a significant challenge in terms of environmental and resource issues. While zeolites show considerably higher selectivities, they still suffer from high recovery cost for their regeneration. In this study, high selectivity and low-energy regeneration for adsorption of CO_2 gas were achieved concurrently in a two-dimensional Cu(II) porous coordination polymer containing inorganic fluorinated PF_6^-. anions that act as moderate and selective interaction sites for CO_2 molecules.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (32 results)

All 2012 2011 2010

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (22 results) Book (2 results)

  • [Journal Article] Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer2011

    • Author(s)
      S. Noro, K. Fukuhara, K. Kubo, T. Nakamura
    • Journal Title

      Cryst. Growth & Des

      Volume: 11巻 Pages: 2379-2385

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diverse structures and adsorption properties of quasi-Werner-type copper(II) complexes with flexible and polar axial bonds2011

    • Author(s)
      S. Noro, T. Ohba, K. Fukuhara, Y. Takahashi, T. Akutagawa, T. Nakamura
    • Journal Title

      Dalton Trans

      Volume: 40巻 Pages: 2268-2274

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diverse structures and adsorption properties of quasi-Werner-type copper (II) complexes with flexible and polar axial bonds2011

    • Author(s)
      S.Noro, T.Ohba, K.Fukuhara, Y.Takahashi, T.Akutagawa, T.Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 2268-2274

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer2011

    • Author(s)
      S.Noro, K.Fukuhara, K.Kubo, T.Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 11 Issue: 6 Pages: 2379-2385

    • DOI

      10.1021/cg2001392

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational synthesis and characterization of porous Cu(II) coordination polymers2010

    • Author(s)
      S. Noro
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 12巻 Pages: 2519-2531

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Orthogonality of Jahn-Teller axes in a dinuclear Cu(II) complex bridged by one F^-anion2010

    • Author(s)
      S. Noro, T. Akutagawa, T. Nakamura
    • Journal Title

      Chem. Commun

      Volume: 46巻 Pages: 4619-4621

    • NAID

      120005906982

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Orthogonality of Jahn-Teller axes in a dinuclear Cu(II) complex bridged by one F-anion2010

    • Author(s)
      S.Noro, T.Akutagawa, T.Nakamura
    • Journal Title

      Chemical Communications

      Volume: 46 Pages: 4619-4621

    • NAID

      120005906982

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational synthesis and characterization of porous Cu(II) coordination polymers2010

    • Author(s)
      S.Noro
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 12 Pages: 2519-2531

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] ウェルナー型銅金属錯体による「フェイク分子」の創出2012

    • Author(s)
      野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 1, 3-bis(4-pyridyl) propane配位子が架橋した多孔性銅錯体におけるCO_2ガス吸着状態の評価2012

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 1,3-bis(4-pyridyl)propane配位子が架橋した多孔性銅錯体におけるCO2ガス吸着状態の評価2012

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(横浜)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 軽金属イオンを含んだ高分子型金属錯体の合成と構造2012

    • Author(s)
      水谷純也、野呂真一郎、久保和也、中村貴義
    • Organizer
      化学系学協会北海道支部2012年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2012-02-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Gas Adsorption Properties of Copper Coordination Polymers Containing Two Kinds of Inorganic Anion Molecules2011

    • Author(s)
      K. Fukuhara, S. Noro, K. Kubo, T. Nakamura
    • Organizer
      The Third Asian Conference on Coordination Chemistry
    • Place of Presentation
      Indian Habitat Center(India)
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] アルカリ土類金属イオンを含んだ多孔性軽金属錯体の合成とその性質2011

    • Author(s)
      水谷純也、高橋由紀子、野呂真一郎、久保和也、中村貴義
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 分極した無機アニオン分子混合による1次元銅金属錯体の吸着挙動制御2011

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2011-09-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 選択的CO2吸着特性を示す1次元銅金属錯体における混合アニオン効果2011

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山)
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 無機アニオン混合による多孔性金属錯体の相互作用ポテンシャル精密制御の試み2011

    • Author(s)
      野呂真一郎、福原克郎、久保和也、中村貴義
    • Organizer
      第63回コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2011-09-08
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 異なるアニオンが混在した固溶体型銅金属錯体の作製とガス吸着挙動2011

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会北海道支部2011年夏季研究発表会
    • Place of Presentation
      室蘭工業大学(室蘭)
    • Year and Date
      2011-07-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 1次元金属錯体の固溶体合成とガス・蒸気吸着特性2011

    • Author(s)
      福原克郎、野呂真一郎、久保和也、中村貴義
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 構造制御された有機-無機複合体の合成と機能化2011

    • Author(s)
      野呂真一郎
    • Organizer
      日本化学会北海道支部2011年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)(招待講演)
    • Year and Date
      2011-02-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 異種アニオンを含む一次元金属錯体の固溶体の合成とガス吸着特性2011

    • Author(s)
      福原克郎、野呂真一郎、中村貴義
    • Organizer
      日本化学会北海道支部2011年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2011-02-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] 1,3-ビス(4-ピリジル)プロパン配位子から形成される高分子型銅金属錯体の合成とガス吸着特性2010

    • Author(s)
      福原克郎、野呂真一郎、中村貴義
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター(大阪)
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Selective Uptake of Guest Molecules in Cu(II) Coordination Polymer2010

    • Author(s)
      S. Noro, K. Fukuhara, T. Nakamura
    • Organizer
      第60回記念錯体化学OSAKA国際会議
    • Place of Presentation
      大阪国際交流センター(大阪)
    • Year and Date
      2010-09-27
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Flexible Cu(II) Coordination Polymers Capable of Selective Adsorption Properties2010

    • Author(s)
      S. Noro, T. Nakamura
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science(NCSS2010)
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2010-09-22
    • Related Report
      2011 Final Research Report
  • [Presentation] Flexible Cu(II) Coordination Polymers Capable of Selective Adsorption Properties2010

    • Author(s)
      S.Noro, T.Nakamura
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science (NCSS2010)
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2010-09-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Host-Guest Chemistry of One-Dimensional Cu(II) Coordination Polymer2010

    • Author(s)
      S. Noro, T. Akutagawa, T. Nakamura
    • Organizer
      39th International Conference on Coordination Chemistry
    • Place of Presentation
      Valencia Conference Centre(South Australia)
    • Year and Date
      2010-07-29
    • Related Report
      2011 Final Research Report
  • [Presentation] Host-Guest Chemistry of One-Dimensional Cu(II) Coordination Polymer2010

    • Author(s)
      S.Noro, T.Akutagawa, T.Nakamura
    • Organizer
      39th International Conference on Coordination Chemistry
    • Place of Presentation
      Valencia Conference Centre (South Australia)
    • Year and Date
      2010-07-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 1,3-ビス(4-ピリジル)プロパン配位子から構築される高分子状金属錯体の結晶構造と吸着特性2010

    • Author(s)
      福原克郎、野呂真一郎、中村貴義
    • Organizer
      日本化学会北海道支部2010夏季研究発表会
    • Place of Presentation
      函館高専(函館)
    • Year and Date
      2010-07-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅錯体の弱配位結合を利用したゲスト分子認識2010

    • Author(s)
      野呂真一郎
    • Organizer
      GCOEシンポジウム:共同現象を誘発する錯体化学の新パラダイム
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2010-05-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 銅錯体の弱配位結合を利用したゲスト分子認識2010

    • Author(s)
      野呂真一郎
    • Organizer
      GCOEシンポジウム:共同現象を誘発する錯体化学の新パラダイム
    • Place of Presentation
      北海道大学(札幌)(招待講演)
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Book] The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials2010

    • Author(s)
      S. Noro, S. Kitagawa
    • Publisher
      Wiley & Sons, Inc.
    • Related Report
      2011 Final Research Report
  • [Book] The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials2010

    • Author(s)
      S.Noro, S.Kitagawa(共著)
    • Publisher
      Wiley & Sons, Inc.
    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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