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Synthesis of Crystalline Porous Silica-Organic Hybrids from Anisotropic Structural Units

Research Project

Project/Area Number 22750183
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionThe University of Tokyo

Principal Investigator

SHIMOJIMA Atsushi  東京大学, 大学院・工学系研究科, 准教授 (90424803)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords多孔体 / 無機有機ハイブリッド / シリカ / 構造単位 / ゼオライト
Research Abstract

This research has focused on the synthesis of a new type of inorganic. organic hybrid porous materials through three-dimensional connection of cage-like siloxane units via organic linkers. Depending on the type of organic groups and reaction, various materials such as microporous material having certain crystallinity and micromesoporous material with extremely high surface area have been achieved. These materials have many potential applications, including catalysis and adsorption.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (11 results)

All 2012 2011 2010 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Porous Siloxane-Organic Hybrid with Ultrahigh Surface Area through Simultaneous Polymerization-Destruction of Functionalized Cubic Siloxane Cages2011

    • Author(s)
      Watcharop Chaikittisilp, Masaru Kubo, Takahiko Moteki, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Journal of the American chemical Society

      Volume: 133 Issue: 35 Pages: 13832-13835

    • DOI

      10.1021/ja2046556

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microporous Hybrid Polymer with a Certain Crystallinity Build from Functionalized Cubic Siloxane Cages as a Singular Building Unit2010

    • Author(s)
      Watcharop Chaikittisilp, Ayae Sugawara-Narutaki, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Chem. Mater

      Volume: 22巻 Issue: 17 Pages: 4841-4843

    • DOI

      10.1021/cm1017882

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microporous Hybrid Polymer with a Certain Crystallinity Build from Functionalized Cubic Siloxane Cages as a Singular Building Unit2010

    • Author(s)
      W.Chaikittisilp, A.Sugawara, A.Shimojima, T.Okubo
    • Journal Title

      Chemistry of Materials

      Volume: 22 Pages: 4841-4843

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] カゴ型シロキサンのジオール架橋による多孔体の構築2012

    • Author(s)
      和田友布子,伊與木健太,久保優,大久保達也,下嶋敦
    • Organizer
      日本セラミックス協会2012年会
    • Place of Presentation
      京都大学
    • Year and Date
      2012-03-20
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] フリーデル-クラフツ反応を利用した高表面積有機シリカの合成2011

    • Author(s)
      Watcharop Chaikittisilp,久保優,茂木堯彦,下嶋敦,鳴瀧彩絵,大久保達也
    • Organizer
      第27回ゼオライト研究発表会
    • Place of Presentation
      関西大学
    • Year and Date
      2011-12-02
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ナノ構造単位の連結による有機シリカ多孔体の構築2011

    • Author(s)
      下嶋敦
    • Organizer
      化学系学協会東北大会ナノマテリアルコロキウム
    • Place of Presentation
      東北大学
    • Year and Date
      2011-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノ構造単位の連結による有機シリカ多孔体の構築2011

    • Author(s)
      下嶋敦
    • Organizer
      化学系学協会東北大会ナノマテリアルコロキウム
    • Place of Presentation
      東北大学(招待講演)
    • Year and Date
      2011-09-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Covalent Linking of Siloxane Cages via Rigid Organic Groups : Toward Crystalline Hybrid Porous Materials2011

    • Author(s)
      Atsushi Shimojima, Watcharop Chaikittisilp, Ayae Sugawara-Narutaki, and Tatsuya Okubo
    • Organizer
      European Congress and Exhibition on Advanced Materials and Processes(EUROMAT2011)
    • Place of Presentation
      Montpelier, France
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Covalent Linking of Siloxane Cages via Rigid Organic Groups : Toward Crystalline Hybrid Porous Materials2011

    • Author(s)
      Atsushi Shimojima, Watcharop Chaikittisilp, Ayae Sugawara-Narutaki, Tatsuya Okubo
    • Organizer
      European Congress and Exhibition on Advanced Materials and Processes (EUROMAT2011)
    • Place of Presentation
      Montpelier, France
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] ブロモフェニル基を有するD4Rユニットからのシリカー有機ハイブリッドナノ多孔体の合成2010

    • Author(s)
      下嶋敦, Watcharop Chaikittisilp,菅原彩絵,大久保達也
    • Organizer
      高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.zeolite.t.u-tokyo.ac.jp/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2010-08-23   Modified: 2016-04-21  

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