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Molecular weight effects on structural formation of polymers under shear flow

Research Project

Project/Area Number 22750197
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionYamagata University

Principal Investigator

MATSUBA Go  山形大学, 大学院・理工学研究科, 准教授 (10378854)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords高分子材料物性 / ナノ構造 / 繊維材料 / 高分子物性 / ポリエチレン / 結晶化 / 量子ビーム / 高分子結晶 / 繊維構造 / 散乱法
Research Abstract

In order to clarify the shish-kebab formation process, we carried out the quantum beam analysis and FT-IR measurements. Especially, the effects of molecular weight on the shish-kebabs and conformational changes were focused on. By neutron and synchrotron radiation x-ray scattering measurements, we observed the oriented structure of low molecular weight component with about 1 micron. From FT-IR measurements, we succeeded the conformation of precursors, which has crystalline conformations.

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (23 results)

All 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (12 results) Remarks (4 results)

  • [Journal Article] Shear-induced crystallization and rheological behavior of syndiotactic polystyrene2012

    • Author(s)
      Zhao Y, Matsuba G, Ito H
    • Journal Title

      J. Mater. Res

      Volume: vol27 Pages: 1372-1378

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] In situ observations of the mesophase formation of isotactic polypropylene-A fast time-resolved2012

    • Author(s)
      Nishida K, Okada K, Asakawa H, Matsuba G, Ito K, Kanaya T, Kaji K
    • Journal Title

      X-ray diffraction Polymer J

      Volume: vol44 Pages: 95-101

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Relaxation of shish-kebab precursor in isotactic polystyrene after short-term shear flow2011

    • Author(s)
      Zhao Y, Matsuba G, Nishida K, Fujiwara T, Inoue R, Polec I, Deng C, Kanaya T
    • Journal Title

      J. Polym. Sci. Part B : Polym. Phys

      Volume: vol49(3) Pages: 214-221

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Melt memory effects on recrystallization of polyamide 6 revealed by depolarized light scattering and small-angle X-ray scattering2011

    • Author(s)
      Kawabata J, Matsuba G, Nishida K, Inoue R, Kanaya T
    • Journal Title

      J.Appl.Polym.Sci.

      Volume: 122 Issue: 3 Pages: 1913-1920

    • DOI

      10.1002/app.34294

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 中性子小角散乱法による高分子の構造解析2011

    • Author(s)
      松葉豪
    • Journal Title

      マテリアルライフ学会誌

      Volume: 23 Pages: 98-103

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Relaxation of shish-kebab precursor in isotactic polystyrene after short-term shear flow2011

    • Author(s)
      Zhao Y, Matsuba G, Nishida K, Fujiwara T, Inoue R, Polec I, Deng C, Kanaya T
    • Journal Title

      J.Polym.Sci.Part B : Polym.Phys.

      Volume: 49 Issue: 3 Pages: 214-221

    • DOI

      10.1002/polb.22176

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relaxation of Shish-Kebab Precursor in Isotactic Polystyrene after Short-Term Shear Flow2011

    • Author(s)
      Zhao YF, Matsuba G, Nishida K, et al
    • Journal Title

      Journal of Polymer Science Part B : Polymer Physics

      Volume: 49 Pages: 214-221

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fiber structure analysis in a wide spatial scale with a quantum beam2011

    • Author(s)
      Matsuba Go
    • Organizer
      ATC-11
    • Place of Presentation
      Daegu, Korea
    • Year and Date
      2011-11-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] Effects of various molecular weights components on shish-kebab structure with small angle x-ray and neutron scattering measurements2011

    • Author(s)
      Matsuba G, Tomita N, Hanano S, Nishida K, Kanaya T
    • Organizer
      第242回アメリカ化学会
    • Place of Presentation
      米国デンバー市
    • Year and Date
      2011-08-31
    • Related Report
      2011 Final Research Report
  • [Presentation] Effects of various molecular weights components on shish-kebab structure with small angle x-ray and neutron scattering measurements2011

    • Author(s)
      Matsuba Go
    • Organizer
      242nd ACS National Meeting
    • Place of Presentation
      Denver, CO, USA
    • Year and Date
      2011-08-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] The precise analysis for shish-kebab formation processes and melting2011

    • Author(s)
      Matsuba Go
    • Organizer
      International Discussion Meeting on Polymer Crystallization
    • Place of Presentation
      Beijing, China
    • Year and Date
      2011-08-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高分子の結晶化メカニズムと精密構造解析2011

    • Author(s)
      松葉豪
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪市)
    • Year and Date
      2011-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子の結晶化メカニズムと精密構造解析2011

    • Author(s)
      松葉豪
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      大阪市(招待講演)
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] シシケバブ構造の量子ビームを用いた精密構造解析2011

    • Author(s)
      松葉豪
    • Organizer
      高分子学会東北支部若手セミナー
    • Place of Presentation
      山形県上山市(招待)
    • Year and Date
      2011-03-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] シシケバブ構造における構造形成機構の広い空間スケールでの観察2011

    • Author(s)
      松葉豪、富田直人、西田幸次、金谷利治
    • Organizer
      JRR-3改造20周年記念シンポジウム
    • Place of Presentation
      日本科学未来館(東京)
    • Year and Date
      2011-02-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 広い空間スケールにおけるシシケバブ構造解析2011

    • Author(s)
      松葉豪、富田直人、西田幸次、金谷利治
    • Organizer
      小角・反射率・高分解能装置研究会
    • Place of Presentation
      東京大物性研
    • Year and Date
      2011-02-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] 広い空間構造解析を用いたシシケバブ構造の低分子量成分の役割の解明2010

    • Author(s)
      富田直人、松葉豪、西田幸次、金谷利治
    • Organizer
      平成22年度 中性子科学会
    • Place of Presentation
      東北大片平キャンパス
    • Year and Date
      2010-12-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 高分子の延伸過程における構造形成過程2010

    • Author(s)
      松葉豪
    • Organizer
      平成22年度.化学系学協会東北地区大会
    • Place of Presentation
      岩手大学工学部(依頼講演)
    • Year and Date
      2010-09-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Detailed Analysis for Shish-kebab Structure during Drawing Process of Polyethylene2010

    • Author(s)
      Matsuba G, Ito C, Nishida K, Kanaya T
    • Organizer
      IUPAC Macro 2010
    • Place of Presentation
      英国グラスゴー市
    • Year and Date
      2010-07-14
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://polyweb.yz.yamagata-u.ac.jp/~matsuba/index.html

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://polyweb.yz.yamagata-u.ac.jp/~matsuba/index.html

    • Related Report
      2011 Annual Research Report
  • [Remarks] 研究室

    • URL

      http://polyweb.yz.yamagata-u.ac.jp/~matsuba/index.html

    • Related Report
      2010 Annual Research Report
  • [Remarks] 大学

    • URL

      http://yudb.kj.yamagata-u.ac.jp/OUTSIDE?ISTActId=SCHKOB0010RIni001&userId-100000265&lang_kbn=o

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-23   Modified: 2016-04-21  

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