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Development of high efficient organic photovoltaics by control of electronic structure and interface structure

Research Project

Project/Area Number 22850012
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionThe Institute of Physical and Chemical Research (2011)
Okayama University (2010)

Principal Investigator

AKAIKE Kouki  独立行政法人理化学研究所, 光電変換研究チーム, 特別研究員 (90581695)

Project Period (FY) 2010 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords有機太陽電池 / ケルビンプローブ法 / 界面電子構造 / 光電流発生 / 新ドナー・アクセプター材料 / ドーピング / 結晶性有機/有機界面
Research Abstract

Correlation between the interfacial electronic structure and device performance of organic photovoltaics is indispensible to provide well-defined guidelines for highly efficient organic photovoltaics(OPVs). In this research, we first elucidated the distribution of the internal potential in planar heterojunction OPVs using Kelvin probe method. Secondly, the electronic structure at donor/acceptor interface could be modified by the control of substrate work function. Based on this finding, it was found that the formation of the interfacial dipole at the donor/acceptor interface strongly influences photocurrent generation

Report

(3 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • Research Products

    (22 results)

All 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (9 results) Book (1 results) Remarks (3 results)

  • [Journal Article] Characteristics of conjugated hydrocarbon based thin film transistor with ionic liquid gate dielectric2011

    • Author(s)
      Y. Kaji, K. Ogawa, R. Eguchi, H. Goto, Y. Sugawara, T. Kambe, K. Akaike, S. Gohda, A. Fujiwara, Y. Kubozono
    • Journal Title

      Org. Electron.

      Volume: 12 Pages: 2076-2076

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Incommensurate Crystalline phase of n-Alkane Monolayers on Graphite(0001)2011

    • Author(s)
      O. Endo, T. Horikoshi, N. Katsumata, K. Otani, T. Fujishima, H. Goto, K. Minami, K. Akaike, and H. Ozaki
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Pages: 5720-5725

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metal-intercalated aromatic hydrocarbons : a new class of carbon-based superconductors2011

    • Author(s)
      Y. Kubozono, H. Mitamura, X. Lee, X. He, Y. Yamanari, Y. Takahashi, Y. Suzuki, Y. Kaji, R. Eguchi, K. Akaike, T. Kambe, H. Okamoto, A. Fujiwara, T. Kato, T. Kosugi and H. Aoki
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 13 Pages: 16476-16476

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of conjugated hydrocarbon based thin film tranistor with ionic liquid gate dielectric2011

    • Author(s)
      Y.Kaji, K.Ogawa, R.Eguchi, H.Goto, Y.Sugawara, T.Kambe, K.Akaike, S.Gohda, A.Fujiwara, Y.Kubozono
    • Journal Title

      Organic Electronics

      Volume: 12 Issue: 12 Pages: 2076-2083

    • DOI

      10.1016/j.orgel.2011.08.016

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-intercalated aromatic hydrocarbons : a new class of carbon-based superconductors2011

    • Author(s)
      Y.Kubozono, H.Mitamura, X.Lee, X.He, Y.Yamanari, Y.Takahashi, Y.Suzuki, Y.Kaji, R.Eguchi, K.Akaike, T.Kambe, H.Okamoto, A.Fujiwara, Takashi Kato, T.Kosugi, H.Aoki
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 13 Issue: 37 Pages: 16476-16493

    • DOI

      10.1039/c1cp20961b

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Incommensurate Crystalline phase of n-Alkane Monolayers on Graphite (0001)2011

    • Author(s)
      O.Endo
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 115 Pages: 5720-5725

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機分子性固体における電界効果キャリア注入と物性制御2011

    • Author(s)
      久保園芳博
    • Journal Title

      表面科学

      Volume: 32 Pages: 27-32

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unoccupied states in copper phthalocyanine/fullerene blended films determined by inverse photoemission spectroscopy2010

    • Author(s)
      K. Akaike, A. Opitz, J. Wagner, W. Brutting, K. Kanai, Y. Ouchi and K. Seki
    • Journal Title

      Org. Electron.

      Volume: 11 Pages: 1853-1853

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unoccupied states in copper phthalocyanine/fullerene blended films determined by inverse photoemission spectroscopy2010

    • Author(s)
      Kouki Akaike
    • Journal Title

      Organic Electronics

      Volume: 11 Pages: 1853-1857

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機太陽電池と界面電子構造の相関2012

    • Author(s)
      赤池幸紀
    • Organizer
      京都大学化学研究所セミナー
    • Place of Presentation
      京都大学化学研究所
    • Year and Date
      2012-05-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Characterizing interfacial electronic structure in organic photovoltaics and device performances of photovoltaics based on new materials2012

    • Author(s)
      赤池幸紀
    • Organizer
      太陽光資源戦略若手勉強会
    • Place of Presentation
      理化学研究所(東京都)(招待講演)
    • Year and Date
      2012-01-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Correlation between Energy Level Alignment and Device Performance in Small-Molecule Based Organic Photovoltaic Cells2011

    • Author(s)
      Kouki Akaike and Yoshihiro Kubozono
    • Organizer
      The 6^<th> Japan-Sweden Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
    • Place of Presentation
      ホテルアローレ(加賀市)
    • Year and Date
      2011-11-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Correlation between Energy Level Alignment and Device Performance in Small-Molecule Based Organic Photovoltaic Cells2011

    • Author(s)
      Kouki Akaike, Yoshihiro Kubozono
    • Organizer
      The 6^<th> Japan-Sweden Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
    • Place of Presentation
      加賀温泉(石川県)
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 界面電子構造研究の有機太陽電池への展開2011

    • Author(s)
      赤池幸紀
    • Organizer
      有機デバイス院生研究会チュートリアル講演
    • Place of Presentation
      九州大学
    • Year and Date
      2011-06-18
    • Related Report
      2011 Final Research Report
  • [Presentation] 界面電子構造研究の有機太陽電池への展開2011

    • Author(s)
      赤池幸紀
    • Organizer
      有機デバイス院生研究会
    • Place of Presentation
      九州大学(福岡県)(チュートリアル講演)
    • Year and Date
      2011-06-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] CuPc/C60混合膜の電子輸送準位の観測2010

    • Author(s)
      赤池幸紀
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 逆光電子分光によるドナー/アクセプター混合膜の空準位の測定2010

    • Author(s)
      赤池幸紀
    • Organizer
      応用物理学会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Dominant Factors in Electronic Structure at Donor/Acceptor Interface : Ground-State Charge Transfer and Change in Polarization Energy2010

    • Author(s)
      Kouki Akaike
    • Organizer
      Gordon Research Conference on Electronic Processes in Organic Materials
    • Place of Presentation
      Mount Holyoke College(U.S)
    • Year and Date
      2010-07-26
    • Related Report
      2010 Annual Research Report
  • [Book] 有機分子性固体における電界効果キャリア注入と物性制御2011

    • Author(s)
      久保園芳博,加地由美子,小川景子,菅原保幸,江口律子,赤池幸紀,神戸高志,藤原明比古
    • Publisher
      表面科学
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://koukisite.web.fc2.com/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://koukisite.web.fc2.com/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://interfa.rlss.okayama-u.ac.jp/

    • Related Report
      2010 Annual Research Report

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Published: 2010-08-27   Modified: 2016-04-21  

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