Imidazolium salt supported catalyst under microwave irradiation

• Project/Area Number: 22850016
• Research Category: Grant-in-Aid for Research Activity Start-up
• Allocation Type: Single-year Grants
• Research Field: Functional materials chemistry
• Research Institution: Tokai University
• Principal Investigator: KOGUCHI Shinichi 東海大学, 理学部, 講師 (90580499)
• Project Period (FY): 2010 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000); Fiscal Year 2011: ¥1,495,000 (Direct Cost: ¥1,150,000、Indirect Cost: ¥345,000); Fiscal Year 2010: ¥1,625,000 (Direct Cost: ¥1,250,000、Indirect Cost: ¥375,000)
• Keywords: イオン液体 / マイクロ波 / イミダゾリウム塩

Research Abstract

Catalytic amination is an important and environmentally benign organic reaction. The amination catalysts, alylboronic acid is the best-known amination catalysts for this reaction. An imidazolium salt-supported alylboronic acid were designed, offering several advantages in comparison with other homogeneous and heterogeneous catalysts, including easier product isolation and purification and improved reusability.