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Fabrication of Electrolyte Membranes Based on Inorganic Solid Acid Nanocomposite and Aromatic Polymer for Intermediate Temperature Fuel Cells

Research Project

Project/Area Number 23360286
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionToyohashi University of Technology

Principal Investigator

MATSUDA Atsunori  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (70295723)

Co-Investigator(Kenkyū-buntansha) KAWAMURA Go  豊橋技術科学大学, 大学院・工学研究科, 助教 (10548192)
武藤 浩行  豊橋技術科学大学, 工学(系)研究科(研究院), 准教授 (20293756)
小暮 敏博  東京大学, 理学(系)研究科(研究院), 准教授 (50282728)
大幸 裕介  名古屋工業大学, 工学(系)研究科(研究院), 助教 (70514404)
打越 哲郎  独立行政法人物質・材料研究機構, その他部局等, グループリーダー (90354216)
Co-Investigator(Renkei-kenkyūsha) MUTO Hiroyuki  豊橋技術科学大学, 大学院・工学研究科, 准教授 (20293756)
KOGURE Toshihiro  東京大学, 理学研究科, 准教授 (50282728)
DAIKO Yusuke  名古屋工業大学, 大学院・工学研究科, 助教 (70514404)
UCHIKOSHI Tetsuo  独立行政法人物質, 材料研究機構, グループリーダー (90354216)
Project Period (FY) 2011-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywords燃料電池 / 中温 / メカニカルミリング / プロトン / 無機有機 / コンポジット / ポリベンズイミダゾール / 発電特性 / 中温領域 / 無機有機複合体 / 固体酸 / 芳香族高分子 / 固体電解質 / 膜・電極複合体
Research Abstract

In this study, highly proton conductive inorganic nanoparticles were prepared by mechanochemical method, and applied for the development of new composite electrolyte membranes based on aromatic polymer for fuel cells at intermediate temperature under anhydrous conditions.
Various proton conductive nanoparticles composed of hydrogen sulfate and heteropoly acid were synthesized by mechanical milling. Polybenzimidazole composite membranes containing CsHSO4- H4SiW12O40 nanoparticles and ortho-phosphoric acid showed high performance and good durability during contentious operation at 150oC under anhydrous for over 800h.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • Research Products

    (52 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (31 results) (of which Invited: 3 results) Book (1 results) Remarks (12 results)

  • [Journal Article] Electricity producing property and bacterial community structure in microbial fuel cells equipped with membrane electrode assembly2013

    • Author(s)
      Owen Rubaba, Yoko Araki, Shuji Yamamoto, Kei Suzuki, Hisatoshi Sakamoto, Atsunori Matsuda, and Hiroyuki Futamata
    • Journal Title

      J. Bioscience Bioeng

      Volume: 1 Issue: 1 Pages: 1-8

    • DOI

      10.1016/j.jbiosc.2013.01.019

    • NAID

      110009634753

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shape-Controlled Metal Nanoparticles and their Assemblies with Optical Functionalities2013

    • Author(s)
      Go Kawamura, Masayuki Nogami and Atsunori Matsuda
    • Journal Title

      J. Nanomater.

      Volume: 2013, 631350 Issue: 1 Pages: 1-17

    • DOI

      10.1155/2013/631350

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conductive Composite Electrolytes in the KH_2PO_4-H_3PW_<12>O_<40> System for H_2/O_2 Fuel Cell Operation2013

    • Author(s)
      S-Y. Oh, T. Kikuchi, G. Kawamura, H. Muto, and A. Matsuda
    • Journal Title

      Applied Energy

      Volume: 112 Pages: 1108-1114

    • DOI

      10.1016/j.apenergy.2013.03.058

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conductive Composite Electrolytes Consisting of KH_2PO_4-H_3PW_<12>O_<40> and Their Application for Fuel Cell2012

    • Author(s)
      S-Y. Oh, T. Kikuchi, G. Kawamura, H. Muto, and A. Matsuda
    • Journal Title

      International Congress on Applied Energy 2012, Proceedings

      Pages: 1085-1092

    • URL

      http://www.applied-energy.org/history/2012/accept.html

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conductive Composite Electrolytes Consisting of K2PO4 and H3PW12O40 and Their Applicaton for Fuel Cells2012

    • Author(s)
      S-Y. Oh, T. Kikuchi, G. Kawamura, H. Muto, and A. Matsuda
    • Journal Title

      Internationa Congress on Applied Energy(ICAE) 2012

      Volume: Proceedings Pages: 1085-1092

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 複合系ナノプロトニクス材料の設計(解説)2011

    • Author(s)
      松田厚範
    • Journal Title

      Electrochemistry

      Volume: 79 Pages: 621-625

    • URL

      https://www.jstage.jst.go.jp/article/electrochemistry/79/8/79_8_620/_article

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Journal Article] Estimation of interfacial proton conductivity by effective media approximation for sheet-like composite electrolyte prepared from poly(2-acrylamido-2-methyl-1-propanesulfonic acid)-deposited core-shell particles2011

    • Author(s)
      H. Sakamoto, Y. Daiko, H. Muto, and A. Matsuda
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 119 Issue: 1395 Pages: 845-849

    • DOI

      10.2109/jcersj2.119.845

    • NAID

      130001310512

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrophilic and Mesoporous SiO_2-TiO_2-SO_3H System for Fuel Cell Membrane Applications2011

    • Author(s)
      L-Y. Hong, S-Y. Oh, A. Matsuda, C-S. Lee, and D-P. Kim
    • Journal Title

      Electrochimica Acta

      Volume: 56 Issue: 9 Pages: 3108-3114

    • DOI

      10.1016/j.electacta.2011.01.075

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Presentation] コンポジット電解質膜の作製と中温無加湿作動燃料電池への応用2014

    • Author(s)
      松田厚範
    • Organizer
      日本セラミックス協会2014年年会サテライトプログラム 「第1回電子・エネルギー材料プロセス研究会」
    • Place of Presentation
      慶応大日吉C
    • Year and Date
      2014-03-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 無機固体酸複合体添加PBI 電解質の無機添加効果と中温燃料電池発電特性2014

    • Author(s)
      矢島将行・武藤浩行・松田厚範
    • Organizer
      2014年電気化学会第81回大会
    • Place of Presentation
      大阪
    • Related Report
      2013 Final Research Report
  • [Presentation] コンポジット電解質膜の作製と中温無加湿作動燃料電池への応用2014

    • Author(s)
      松田厚範
    • Organizer
      日本セラミックス協会2014年年会サテライトプログラム
    • Place of Presentation
      慶応大学日吉
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 無機固体酸複合体添加PBI電解質の無機添加効果と中温燃料電池発電特性2014

    • Author(s)
      矢島将行・武藤浩行・松田厚範
    • Organizer
      2014年電気化学会第81回大会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] PBI 電解質膜への無機固体酸添加効果と中温燃料電池発電特性2013

    • Author(s)
      矢島将行・武藤浩行・松田厚範
    • Organizer
      平成25年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      愛知
    • Year and Date
      2013-12-07
    • Related Report
      2013 Final Research Report
  • [Presentation] プロトン伝導性複合体の創製と次世代燃料電池への応用(特別講演)2013

    • Author(s)
      松田厚範
    • Organizer
      電気電子材料技術セミナーInsulation2013
    • Place of Presentation
      亀戸文化センター
    • Year and Date
      2013-11-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 無機-有機コンポジット電解質膜を用いた中温無加湿燃料電池の構築2013

    • Author(s)
      松田厚範・武藤浩行・河村剛
    • Organizer
      2013年度セラミックス総合研究会
    • Place of Presentation
      浜名湖
    • Related Report
      2013 Final Research Report
  • [Presentation] 無機固体酸複合体を含むPBIコンポジット電解質膜を用いたスタックセルの構築と発電特性2013

    • Author(s)
      栩木啓佑・吉田敏宏・河村剛・武藤浩行・松田厚範
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 無機-有機コンポジット電解質を用いた中温無加湿作動燃料電池2013

    • Author(s)
      松田厚範・田中恵
    • Organizer
      第9回国際水素・燃料電池展, アカデミックフォーラム
    • Place of Presentation
      東京ビックサイト
    • Related Report
      2013 Final Research Report
  • [Presentation] 無機-有機コンポジット電解質膜を用いた中温無加湿燃料電池の構築2013

    • Author(s)
      松田厚範・武藤浩行・河村剛
    • Organizer
      2013年度セラミックス総合研究会
    • Place of Presentation
      浜名湖
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロトン伝導性複合体の創製と次世代燃料電池への応用2013

    • Author(s)
      松田厚範
    • Organizer
      電気電子材料技術セミナーInsulation2013
    • Place of Presentation
      亀戸文化センター
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] PBI電解質膜への無機固体酸添加効果と中温燃料電池発電特性2013

    • Author(s)
      矢島将行・武藤浩行・松田厚範
    • Organizer
      平成25年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] 無機-有機コンポジット電解質を用いた中温無加湿作動燃料電池2013

    • Author(s)
      松田厚範・田中恵
    • Organizer
      FC EXPO2013 第9回国際水素・燃料電池展、アカデミック―フォーラム
    • Place of Presentation
      東京ビックサイト
    • Related Report
      2012 Annual Research Report
  • [Presentation] メカノケミカル合成したKHS-WPA複合体を含むSPEEKコンポジット電解質の特性評価とDMFCへの応用2012

    • Author(s)
      栩木啓佑・菊地拓也・吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      平成24年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2012-12-01
    • Related Report
      2013 Final Research Report
  • [Presentation] PBI-無機固体酸複合体コンポジットをイオノマーとして含むカソードの電気化学特性評価2012

    • Author(s)
      吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      浜松
    • Year and Date
      2012-04-01
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] メカノケミカル法による高プロトン伝導性複合体の合成と界面解析による伝導メカニズムの究明2012

    • Author(s)
      松田厚範・呉松烈・森利之
    • Organizer
      第3回ナノ材料科学環境拠点シンポジウム
    • Year and Date
      2012-02-28
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] 無機固体酸複合体を含むPBIコンポジット電解質を用いた中温無加湿燃料電池の連続運転評価2012

    • Author(s)
      吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Design of Highly Proton Conductive Solid Electrolytes Based on Nanopore, Interface and Defect and Their Electrochemical Application2012

    • Author(s)
      A. Matsuda
    • Organizer
      IUMRS-International Conference on Electronic Materials
    • Place of Presentation
      Yokohama
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Proton Conductive Composite Electrolytes Consisting of K_2PO_4 and H_3PW_<12>O_<40> and Their Application for Fuel Cell2012

    • Author(s)
      S-Y. Oh・T. Kikuchi・G. Kawamura・H. Muto・A. Matsuda
    • Organizer
      The 4th International Conference on Applied Energy (ICAE 2012)
    • Place of Presentation
      Suzhou, China
    • Related Report
      2013 Final Research Report
  • [Presentation] メカノケミカル合成したKHS-WPA複合体を含むSPEEKコンポジット電解質の作製と燃料電池への応用2012

    • Author(s)
      栩木啓佑・菊地拓也・吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      日本セラミック協会東海支部 第44回東海若手セラミスト懇話会
    • Place of Presentation
      浜松
    • Related Report
      2013 Final Research Report
  • [Presentation] メカノケミカル合成したKHS-WPA複合体を含むSPEEKコンポジット電解質の作製と燃料電池への応用2012

    • Author(s)
      栩木啓佑・菊地拓也・吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      日本セラミックス協会東海支部第44回 東海若手セラミスト懇話会
    • Place of Presentation
      浜松
    • Related Report
      2012 Annual Research Report
  • [Presentation] Proton Conductive Composite Electrolytes Consisting of KH2PO4 and H3PW12O40 and Their Application for Fuel Cell2012

    • Author(s)
      Song-Yul Oh・菊地拓也・河村剛・武藤浩行・松田厚範
    • Organizer
      The 4th International Conference on Applied Energy (ICAE 2012)
    • Place of Presentation
      Suzhou, China
    • Related Report
      2012 Annual Research Report
  • [Presentation] Design of Highly Proton Conductive Solid Electrolytes Based on Nanopore, Interface and Defect and Their Electrochemical Application (Ivited talk)2012

    • Author(s)
      A. Matsuda
    • Organizer
      IUMRS-International Conference on Electronic Materials (IUMRS-ICEM 2012)
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2012 Annual Research Report
  • [Presentation] メカノケミカル合成したKHS-WPA 複合体を含むSPEEK コンポジット電解質の特性評価とDMFC への応用2012

    • Author(s)
      栩木 啓佑・菊地 拓也・吉田 敏宏・呉 松烈・河村 剛・武藤 浩行・松田 厚範
    • Organizer
      平成24年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] MHAO_4 型固体酸塩とヘテロポリ酸からなる複合体を用いた燃料電池の構築2011

    • Author(s)
      菊地拓也・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      平成23年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名工大
    • Year and Date
      2011-12-03
    • Related Report
      2013 Final Research Report
  • [Presentation] MHAO_4型固体酸塩とヘテロポリ酸からなる複合体を用いた燃料電池の構築2011

    • Author(s)
      菊地拓也・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      平成23年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2011-12-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] Influence of Additives in Catalytic Layer of Cathode on the Performance of PEFC Using PBI-Inorganic Solid Acid Composite Electrolyte2011

    • Author(s)
      T. Yoshida・S-Y. Oh・G. Kawamura・H. Muto・A. Matsuda
    • Organizer
      21st Academic Symposium of The Materials Research Society of Japan (MRS-J) 2011
    • Place of Presentation
      Yokohama
    • Related Report
      2013 Final Research Report
  • [Presentation] 触媒層に無機固体酸複合体を含むPBIコンポジットイオノマーの電気化学特性評価2011

    • Author(s)
      吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      第52回電池討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Final Research Report
  • [Presentation] Characterization of Mechanochemically Synthesized MHSO_4-H_4SiW_<12>O_<40> Composites (M=K, Rb, NH_4, Cs)2011

    • Author(s)
      S-Y. Oh・K. Kawai・G. Kawamura・H. Muto・A. Matsuda
    • Organizer
      2011 International forum on Functional Materials (IFFM 2011)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Presentation] 触媒層に無機固体酸複合体を含むPBIコンポジットイオノマーの電気化学特性評価2011

    • Author(s)
      吉田敏宏・呉松烈・河村剛・武藤浩行・松田厚範
    • Organizer
      第52回電池討論会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Influence of Additives in Catalytic Layer of Cathode on the Performance of PEFC Using PBI-Inorganic Solid Acid Composite Electrolyte2011

    • Author(s)
      Toshihiro Yoshida, Song-Yul.Oh, Go Kawamura, Hiroyuki. Muto, Atsunori Matsuda
    • Organizer
      21^<st> Academic Symposium of The Materials Research Society ofrapan (MRS-J) 2011
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2011 Annual Research Report
  • [Book] イオン伝導体の材料技術と測定方法2011

    • Author(s)
      松田厚範, 他29名
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2013 Final Research Report 2011 Annual Research Report
  • [Remarks] Fuel Cell Works (eNews in the US) Toyohashi University of Technology Researchers Develop a High-Performance Electrolyte Film for Fuel Cells 松田厚範(2012.12.19)(新聞掲載記事)

    • URL

      http://fuelcellsworks.com/news/2012/12/19/toyohashi-university-of-technology-researchers-develop-a-high-performance-electrolyte-film-for-fuel-cells/

    • Related Report
      2013 Final Research Report
  • [Remarks] 日刊工業新聞 2012年11月1日「高性能電解質膜を開発 リン酸添加量1/3に 燃料電池 無加湿で出力最高水準」豊橋技術科学大学 松田厚範教授らの研究グループ(2012.11.1)(新聞掲載記事)

    • Related Report
      2013 Final Research Report
  • [Remarks] 豊橋技術科学外学第30回オープンキャンパス「次世代に利用される機能性材料の開発」 松田厚範他(2013.8.31)(アウトリーチ活動)

    • Related Report
      2013 Final Research Report
  • [Remarks] 豊田高等専門学校専攻科 先端技術紹介「次世代燃料電池」 松田厚範,(2013.4.25)(アウトリーチ活動)

    • Related Report
      2013 Final Research Report
  • [Remarks] 豊橋技術科学外学第29回オープンキャンパス「次世代に利用される機能性材料の開発」松田厚範他(2012.8.25)(アウトリーチ活動)

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://ion.ee.tut.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 国立大学法人 豊橋技術科学大学 松田・武藤・河村研究室

    • URL

      http://ion.ee.tut.ac.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 松田研究テーマ3:次世代燃料用新規電解質膜の開発

    • URL

      http://www.tut.ac.jp/teach/main.php?mode=detail&article=214

    • Related Report
      2013 Annual Research Report
  • [Remarks] 豊橋技術科学大学 電気電子情報工学系 松田・武藤・河村研究室

    • URL

      http://ion.ee.tut.ac.jp/

    • Related Report
      2012 Annual Research Report
  • [Remarks] 豊橋技術科学大学 教員紹介 松田厚範

    • URL

      http://www.tut.ac.jp/teach/main.php?mode=detail&article=214

    • Related Report
      2012 Annual Research Report
  • [Remarks] 個人

    • URL

      http://material.tutms.tut.ac.jp/STAFF/MATSUDA/index.html.ja

    • Related Report
      2011 Annual Research Report
  • [Remarks] 研究室

    • URL

      http://www3.to/sakai-matsuda

    • Related Report
      2011 Annual Research Report

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Published: 2011-04-06   Modified: 2019-07-29  

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