Development of monitoring system for hazardous material using QCM-stimuli-responsive polymer hydrogel

• Project/Area Number: 23510092
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Toyo University
• Principal Investigator: YOSHIMI Seida 東洋大学, 経済学部, 教授 (60216504)
• Co-Investigator(Kenkyū-buntansha): SUZUKIK Takahiro 東洋大学, 経済学部, 教授 (30192131)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: QCM－A / ハイドロゲル / センシング / 粘弾性 / クライオ測定 / 吸着 / 水和・脱水和 / 水晶振動子 / 粘弾性解析 / マイクロセル / QCM / 発振周波数 / 低温観測 / アフィニティー

Research Abstract

In the present research, development of adsorption based sensing system of hazardous micro-pollutant in water environment using stimuli-responsive hydrogel-quartz crystal microbalance conjugate was performed. The system applied the self-regulating phase behavior/property of the gel as the principal mechanism of the sensing. Basic property of QCM that was conjugated with the cross-linked stimuli-responsive adsorbent hydrogel was examined. The use of network analyzer with big power supply was found to enable the application of the gel with large molecular weight in the sensing with keeping high resolution of QCM. The new method to identify the phase behavior of hydrogel during environmental change with high resolution was also developed by using a technique of inert liquid film sealing of gel The sensing system based on the stimuli-responsive hydrogel-QCM-A conjugate was developed.

Research Products

• [Journal Article] QCM-A を用いたゲルの特性評価 (2014)
  • Author(s): 清田
  • Journal Title: ゲルテクノロジーハンドブック (NTS) Volume: (発刊予定(校正中))
  • Peer Reviewed
• [Journal Article] 感温型高分子ゲルによる温度スイング吸着分離システム (2014)
  • Author(s): 清田、中野義夫
  • Journal Title: ゲルテクノロジーハンドブック (NTS) Volume: (発刊予定(校正中))
  • Peer Reviewed
• [Journal Article] Viscoelastic behavior of O/W emulsion in its freezing-thawing processes characterized by QCM-A (2014)
  • Author(s): Y. Seida
  • Journal Title: Trans. Mat. Res. Soc. Jpn Volume: (submitted)
  • Peer Reviewed
• [Journal Article] QCM によるハイドロゲルの粘弾性特性観察, ゲルの安定化と機能性付与・次世代への応用開発 (2013)
  • Author(s): 清田
  • Journal Title: ゲルの測定・評価・解析 (技術情報協会, 東京) Volume: 第3章, 第3節 Pages: 238-242
• [Journal Article] Viscoelastic behavior of thermo - responsive hydrogel during temperature swing process- measurement of viscosity free mass effect via QCM-A - (2013)
  • Author(s): Y.Seida
  • Journal Title: Tans. Mat. Res. Soc. Jpn Volume: 38(4) Pages: 651-654
  • NAID: 130005004272
  • Peer Reviewed
• [Journal Article] Adsorption property of clay - polymer conjugates for rare earth elements (2013)
  • Author(s): Y.Seida
  • Journal Title: 東洋大学紀要・自然科学篇 Volume: 57 Pages: 83-93
  • NAID: 120005307737
• [Journal Article] 層状無機化合物の層間有機分子配向と乳化特性 -エマルションの構造安定性に及ぼす層間電荷密度の影響- (2013)
  • Author(s): 清田
  • Journal Title: 東洋大学紀要・自然科学篇 Volume: 57 Pages: 73-81
  • NAID: 120005307736
• [Journal Article] Adsorption property of clay-polymer conjugates for rare earth elements (2013)
  • Author(s): 清田佳美
  • Journal Title: 東洋大学紀要自然科学篇 Volume: 57 Pages: 83-93
  • NAID: 120005307737
• [Journal Article] Viscoelastic behavior of thermo-responsive hydrogel during temperature swing process - measurement of viscosity free mass effect via QCM-A - (2013)
  • Author(s): Yoshimi Seida
  • Journal Title: Tans. Mat. Res. Soc. Jpn. Volume: 38(4) Pages: 651-654
  • NAID: 130005004272
  • Peer Reviewed
• [Journal Article] 層状無機化合物の層間有機分子配向と乳化特性 -エマルションの構造安定性に及ぼす層間電荷密度の影響- (2013)
  • Author(s): 清田佳美
  • Journal Title: 東洋大学紀要自然科学篇 Volume: 57 Pages: 73-81
  • NAID: 120005307736
• [Journal Article] QCMを用いたハイドロゲルの局所粘弾性観察 (2013)
  • Author(s): 清田佳美
  • Journal Title: ゲルの安定化と機能性付与・次世代への応用開発 Volume: 該当無し Pages: 238-242
• [Journal Article] Demonstration of Molecular Sensing Using QCM Device Coated with Stimuli-sensitive Hydrogel (2013)
  • Author(s): Y. Seida, Y. Nakano, Y.Nakano
  • Journal Title: MRS Proceedings, Symposium S, Biomimetic, Bio-inspired and Self-Assembled Materials for Engineered Surface and Applications Volume: 1498 Pages: 1-6
  • DOI: 10.1557/opl.2012.1560
  • Peer Reviewed
• [Journal Article] Demonstration of Molecular Sensing Using QCM Device Coated with Stimulisensitive Hydrogel (2012)
  • Author(s): Y. Seida, Y. Nakano, Y. Nakano
  • Journal Title: Material Research Society Online Procs. Library (Cambridge University Press) Pages: 1-6
  • Peer Reviewed
• [Journal Article] 層状複水酸化物の界面活性剤吸着特性および乳化ゲル体の構造安定性 (2012)
  • Author(s): 清田
  • Journal Title: 東洋大学紀要・自然科学篇 Volume: 56 Pages: 43-52
  • NAID: 120005302917
• [Journal Article] Actuation dynamics of polymer hydrogel in electric field (2012)
  • Author(s): 清田
  • Journal Title: 東洋大学紀要・自然科学篇 Volume: 56 Pages: 43-52
  • NAID: 120005302918
• [Journal Article] Actuation Dynamics of Polymer Hydrogel in Electric Field (2012)
  • Author(s): Y.Seida
  • Journal Title: Journal of Toyo University Natural Science Volume: 56 Pages: 43-52
  • NAID: 120005302918
• [Journal Article] 層状複水酸化物の界面活性剤吸着特性および乳化ゲル体の構造安定性 (2012)
  • Author(s): 清田佳美
  • Journal Title: 東洋大学紀要 自然科学編 Volume: 56号 Pages: 43-52
  • NAID: 120005302917
• [Journal Article] Actuation Dynamics of Polymer Hydrogel in Electric Field (2012)
  • Author(s): Y.Seida
  • Journal Title: 東洋大学紀要 自然科学編 Volume: 56号 Pages: 53-64
  • NAID: 120005302918
• [Journal Article] 廃棄物処分のバリア材性能評価における吸着技術の応用 (2011)
  • Author(s): 清田
  • Journal Title: 分離技術 Volume: 41(2) Pages: 35-40
• [Journal Article] Preparation of adsorbent for phosphate recovery from aqueous solutions based on condensed tannin gel (2011)
  • Author(s): T. Ogata, S. Morisada, Y. Oinuma, Y. Seida, Y. Nakano
  • Journal Title: J. Hazardous Materials Volume: 192(2) Pages: 698-703
  • Peer Reviewed
• [Presentation] Viscoelastic Characterization of Soft Material Using QCM-A (2014)
  • Author(s): Y. Seida, T. Suzuki
  • Organizer: The 15^<th> IUMRS- International Conference in Asia (IUMRSICA 2014)
  • Place of Presentation: Fukuoka Univ (scheduled)
  • Year and Date: 2014-08-26
• [Presentation] 高分子ゲル複合 QCM センサの開発 (2014)
  • Author(s): 北村、清田、徳山
  • Organizer: 分離技術会2014年会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2014-05-30
• [Presentation] 完全混合槽吸着装置を用いた樹脂吸着剤粒子内拡散係数の決定法 (2014)
  • Author(s): 川北、清田、中山、古谷
  • Organizer: 分離技術会2014年会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2014-05-30
• [Presentation] 解析解の利用による濃度減衰曲線を用いた粒子内拡散係数の簡便な決定法 (2014)
  • Author(s): 高曽根、清田、中山、古谷
  • Organizer: 化学工学会第79年会
  • Place of Presentation: 岐阜大学
  • Year and Date: 2014-03-20
• [Presentation] Viscoelastic characterization of soft material using QCM‒A (2014)
  • Author(s): Y.Seida
  • Organizer: IUMRS-ICA2014
  • Place of Presentation: Fukuoka
• [Presentation] クライオ QCM によるゲル体の粘弾性測定 (2013)
  • Author(s): 清田、若本
  • Organizer: 化学工学会第45回秋季大会
  • Place of Presentation: 岡山大学
  • Year and Date: 2013-09-17
• [Presentation] QCM Observation of Soft Material under Cryo-condition (2013)
  • Author(s): Y. Seida
  • Organizer: 第23回日本 MRS 年次大会
  • Place of Presentation: 横浜市開港記念会館、横浜
• [Presentation] クライオQCMによるゲル体の粘弾性測定 (2013)
  • Author(s): 清田佳美,若本悟
  • Organizer: 化学工学会第45回秋季大会
  • Place of Presentation: 岡山大学
• [Presentation] QCM Observation of Soft Material under Cryo-condition (2013)
  • Author(s): 清田佳美
  • Organizer: 第23回日本MRS年次大会
  • Place of Presentation: 横浜市開港記念会館
• [Presentation] Viscoelastic behavior of hydrogel observed by quartz crystal microbalance with impedance analysis (2012)
  • Author(s): Y. Seida
  • Organizer: 10th Japan-Korea Symposium on Materials & Interfaces, International Symposium on Frontiers in Chemical Engineering-
  • Place of Presentation: Kyoto
  • Year and Date: 2012-11-08
  • Invited
• [Presentation] Evaluation of Mass Effect Free from Viscosity Influence of Loading Viscoelastic Media in Quartz Crystal Microbalance Measurement (2012)
  • Author(s): Y. Seida, T. Suzuki
  • Organizer: 22nd Academic Symposium of MRSJapan 2012 Advanced Ecomaterials Research for Emerging Ecoinnovations
  • Place of Presentation: Yokohama
  • Year and Date: 2012-09-25
• [Presentation] QCM を用いたハイドロゲルの局所粘弾性挙動観察における一考察 (2012)
  • Author(s): 清田、鈴木
  • Organizer: 化学工学会第44回秋季大会
  • Place of Presentation: 東北大学(仙台)
  • Year and Date: 2012-09-21
• [Presentation] ハイドロゲルの水和挙動の QCM 観察 (2012)
  • Author(s): 清田
  • Organizer: 分離技術会年会2012
  • Place of Presentation: 関西大学
  • Year and Date: 2012-06-01
• [Presentation] Demonstration of molecular sensing using QCM device coated with stimuliresponsive hydrogel (2012)
  • Author(s): Y. Seida, Y. Nakano, Y. Nakano
  • Organizer: Mater. Res. Soc. Fall Meeting 2012
  • Place of Presentation: Boston, USA
• [Presentation] QCM Observation of viscoeleastic behavior of collapsed Poly(NIPAm) Gel in Response to Protein Adsorption (2012)
  • Author(s): Y. Sedia, Y. Nakano, Y. Nakano
  • Organizer: Polymer Networks Group
  • Place of Presentation: Jackson hole, WY, USA
• [Presentation] QCM Observation of Viscoeleastic Behavior of Collasped Poly(NIPAm) Gel in Response to Protein Adsorption (2012)
  • Author(s): Y.Seida, Y.Nakano, Y.Nakano
  • Organizer: Polymer Networks Group
  • Place of Presentation: Jackson Hole, WY（USA)
• [Presentation] QCMを用いたハイドロゲルの局所粘弾性挙動観察における一考察 (2012)
  • Author(s): 清田佳美
  • Organizer: 化学工学会第44回秋季大会
  • Place of Presentation: 仙台（東北大学）
• [Presentation] Evaluation of Mass Effect Free from Viscosity Influence of Loading Viscoelastic Media in Quartz Crystal Microbalance Measurement (2012)
  • Author(s): Y.Seida
  • Organizer: 22nd Academic Symposium of MRS Japan 2012
  • Place of Presentation: Yokohama
• [Presentation] Viscoelastic behavior of hydrogel observed by quartz crystal microbalance with impedance analysis (2012)
  • Author(s): Y.Seida
  • Organizer: 10th Japan-Korea Symposium on Materials & Interfaces, International Symposium on Frontiers in Chemical Engineering
  • Place of Presentation: Kyoto
  • Invited
• [Presentation] 8） Demonstration of molecular sensing using QCM device coated with stimuli-sensitive hydorgel (2012)
  • Author(s): Y. Seida, Y. Nakano, Y.Nakano
  • Organizer: Materials Research Society Fall Meeting 2012
  • Place of Presentation: Boston
• [Presentation] Local viscoelastic behavior of hydrogel in its collapse phase ; the dependence of viscoelastic behavior of hydrogel on the intrinsic resonation frequency of QCM (2011)
  • Author(s): Y. Seida
  • Organizer: The 21st MRS-Japan Academic Symposium
  • Place of Presentation: The Materials Research Society of Japan、Yokohama
• [Presentation] Local Viscoelastic Behavior of Hydrogel in Its Collapse Phase - The Influence of Intrinsic Oscillation Frequency of Probe QCM on The Observed Viscoelasticity- (2011)
  • Author(s): Y. Seida & T.Suzuki
  • Organizer: MRS-Japan
  • Place of Presentation: The 21st MRS-Japan Academic Symposium（神奈川県横浜市）
• [Presentation] QCMによるハイドロゲルの水和構造観察
  • Author(s): 清田佳美
  • Organizer: 分離技術会2012年会
  • Place of Presentation: 大阪（関西大学）