Development of materials which respond to the external stimuli by using the synchrotron radiation technique
Project/Area Number |
23550083
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Teikyo University (2013-2014) Toho University (2011-2012) |
Principal Investigator |
OHGO Yoshiki 帝京大学, 大学院医学研究科, 教授 (40287496)
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Project Period (FY) |
2011-04-28 – 2015-03-31
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Project Status |
Completed (Fiscal Year 2014)
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Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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Keywords | 鉄(III) / ヘムタンパク質 / 電子密度分布解析 / ポルフィリン / スピン密度 / 電子配置 / 電子状態 / 磁性 / 鉄(III) / へムタンパク質 |
Outline of Final Research Achievements |
Syntheses of the novel functional materials, which respond to the external stimuli, have been carried out. We have developed novel method to apply external stimuli to the materials in spectroscopic experiment. The combined study of single crystal, powder, and synchrotron structure analysis clarified the detailed electronic structure of the novel functional materials. The obtained perception suggested interesting possibility in catalytic cycle of the enzymes.
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Report
(5 results)
Research Products
(29 results)
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[Journal Article] (12,17-Diethoxycarbonyl-11,18- dimethyl-2,3:6,7-dibutano- corrphycenato)copper(II)-12,17- diethoxycarbonyl-11,18-dimethyl- 2:3,6:7-dibutanocorrphycene (3/97)2011
Author(s)
Y. Ohgo, Y. Yokoyama, D. Hashizume, S. Neya, M. Nakamura
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Journal Title
Acta Crystallogr., E
Volume: 67
Related Report
Peer Reviewed
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[Presentation] Structural Characterization and Physicochemical Properties in the Biomimetic Spin-Crossover Materials
Author(s)
Y. Ohgo, K. Takahashi, M. Takahashi, Y. Namatame, H. Konaka, H. Mori, S. Neya, S. Hayami, D. Hashizume, and M. Nakamura
Organizer
7th INTERNATIONAL SYMPOSIUM ON HIGH-TECH POLYMER MATERIALS (HTPM-VII)
Place of Presentation
Xi'an, China
Related Report
Invited
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