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Development of a new CO sensor for reducing atmosphere

Research Project

Project/Area Number 23550156
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionEhime University

Principal Investigator

YAMAURA Hiroyuki  愛媛大学, 理工学研究科, 講師 (40314968)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsセンサー / 燃料電池 / 触媒・化学プロセス
Research Abstract

CO sensing property was investigated for CuO/SnO2-In2O3 in a reducing atmosphere. CuO-loaded SnO2-In2O3 exhibited high sensitivity to CO in the range of 200-1000 ppm of CO concentration. Such a high sensitivity may come from high dispersion of CuO on SnO2. It was considered that the redox of SnO2 surface, which is accelerated by reduced CuO, was closely related to CO sensitivity of CuO-loaded SnO2. The CO sensing properties of Pt/SnO2, Au/SnO2, Ag/SnO2, Pd/SnO2, Ru/SnO2, and Rh/SnO2 sensors were investigated in wet H2 atmosphere at room temperature. Good response and recovery behaviors of Rh(1wt%)/SnO2 sensor were observed. It is concluded that Rh/SnO2 sensor has a potential candidate as CO monitoring in H2 at room temperature.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (26 results)

All 2013 2012 2011 Other

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (20 results) Remarks (1 results)

  • [Journal Article] Room temperature CO sensing in H_2 atmosphere using noble meatal-loaded tin oxide2013

    • Author(s)
      H. Yamaura, H. Yahiro
    • Journal Title

      Chemical Sensors

      Volume: 29(A) Pages: 52-54

    • URL

      http://chemsens.electrochem.jp

    • Related Report
      2013 Final Research Report
  • [Journal Article] ROOM-TEMPERATURE CO SENSING IN H2 ATMOSPHERE USING NOBLE METAL-LOADED TIN OXIDE2013

    • Author(s)
      Hiroyuki YAMAURA and Hidenori YAHIRO
    • Journal Title

      Chem. Sensors

      Volume: 29(A) Pages: 52-54

    • Related Report
      2012 Research-status Report
  • [Journal Article] CO sensing property of copper oxide-loaded tin dioxide system in a reducing atmosphere2011

    • Author(s)
      H. Yamaura, S. Hirao, Y. Iwasaki, H. Yahiro
    • Journal Title

      Chemical Sensors

      Volume: 27(B) Pages: 19-21

    • NAID

      40019025278

    • URL

      http://chemsens.electrochem.jp

    • Related Report
      2013 Final Research Report
  • [Journal Article] Effect of pretreatment on carbon oxidation activity over copper ion-exchanged zeolite catalysts2011

    • Author(s)
      H. Yamaura, T. Akamatsu, Y. Abe, S. Yamaguchi, H. Yahiro
    • Journal Title

      Research on Chemical Intermidiates

      Volume: 37 Issue: 9 Pages: 1157-1164

    • DOI

      10.1007/s11164-011-0381-0

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] CuO/SnO_2-In_2O_3 sensor for monitoring CO concentration in a reducing atmosphere2011

    • Author(s)
      H. Yamaura, Y. Iwasaki, S. Hirao, H. Yahiro
    • Journal Title

      Sensors and Actuators B

      Volume: 153 Issue: 2 Pages: 465-467

    • DOI

      10.1016/j.snb.2010.10.044

    • Related Report
      2013 Final Research Report 2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Cyanosilylation of benzaldehyde using Zn-Sn oxide catalyst with cubic shape particles2013

    • Author(s)
      H. Yamaura
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco- Materials
    • Place of Presentation
      松山
    • Year and Date
      2013-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation and Catalytic Property of Zn-Sn Oxide with Cubic Shape Particles2013

    • Author(s)
      H. Yamaura
    • Organizer
      APCAT-6
    • Place of Presentation
      台湾(台北)
    • Year and Date
      2013-10-14
    • Related Report
      2013 Final Research Report
  • [Presentation] 高温前処理を行ったCuイオン交換ゼオライト上でのPM燃焼反応の評価2013

    • Author(s)
      山浦弘之
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Year and Date
      2013-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrical conductivity of Ni/SDC electrocatalyst film fabricated by electrophoretic deposition2013

    • Author(s)
      H. Yamaura
    • Organizer
      ISHHC16
    • Place of Presentation
      札幌
    • Year and Date
      2013-08-06
    • Related Report
      2013 Final Research Report
  • [Presentation] 貴金属担持酸化スズの室温付近における水素雰囲気中微量CO検知2013

    • Author(s)
      山浦弘之
    • Organizer
      2012日本化学会西日本大会
    • Place of Presentation
      仙台
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrical conductivity of Ni/SDC electrocatalyst film fabricated by electrophoretic deposition2013

    • Author(s)
      Hiroyuki Yamaura, Muku Nakasato, Hidenori Yahiro
    • Organizer
      ISHHC16
    • Place of Presentation
      Hokkaido University (北海道札幌市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 立方体状に形態制御されたSn-Zn複合酸化物の 調製および触媒活性2013

    • Author(s)
      山浦弘之、岩崎正孝、森原健太、山口修平、八尋秀典
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学 (秋田県秋田市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation and Catalytic Property of Zn-Sn Oxide with Cubic Shape Particles2013

    • Author(s)
      Hiroyuki Yamaura, Masataka Iwasaki, Kenta Morihara, Syuhei Yamaguchi, Hidenori Yahiro
    • Organizer
      APCAT-6
    • Place of Presentation
      aipei International Convention Center (台湾、台北市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cyanosilylation of benzaldehyde using Zn-Sn oxide catalyst with cubic shape particles2013

    • Author(s)
      Hiroyuki Yamaura, Kenta Morihara, Syuhei Yamaguchi, Hidenori Yahiro
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials
    • Place of Presentation
      愛媛大学 (愛媛県松山市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 共沈法によるSn-Zn系複合酸化物の調製および評価2012

    • Author(s)
      山浦弘之
    • Organizer
      2012日本化学会西日本大会
    • Place of Presentation
      佐賀
    • Year and Date
      2012-11-11
    • Related Report
      2013 Final Research Report
  • [Presentation] Study on Perovskite-type Oxide Cathodes for Proton Conducting Solid Oxide Fuel Cells2012

    • Author(s)
      H. Yamaura
    • Organizer
      Interantional Symposium on Rare Earths in 2012
    • Place of Presentation
      沖縄
    • Year and Date
      2012-11-08
    • Related Report
      2013 Final Research Report
  • [Presentation] 高温前処理を行ったCuイオン交換ゼオライト上でのPM燃焼反応の評価2011

    • Author(s)
      山浦弘之
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見
    • Year and Date
      2011-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Investigation on reduction behavior of CuO-loaded SnO_2 by simultaneous measurements of TPR and electric resistance2011

    • Author(s)
      H. Yamaura
    • Organizer
      XV.ISHHC
    • Place of Presentation
      ドイツ(ベルリン)
    • Year and Date
      2011-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 銅担持酸化スズ系材料の還元雰囲気でのCO検知挙動2011

    • Author(s)
      山浦弘之
    • Organizer
      第52回化学センサ研究発表会
    • Place of Presentation
      新潟
    • Year and Date
      2011-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] 銅担持酸化スズ系材料の還元雰囲気でのCO検知挙動2011

    • Author(s)
      山浦弘之、平尾晋介、岩崎裕史、八尋秀典
    • Organizer
      第52回化学センサ研究発表会
    • Place of Presentation
      朱雀メッセ(新潟:県)
    • Related Report
      2011 Research-status Report
  • [Presentation] Investigation on reduction behavior of CuO-loaded SnO2 by simultaneous measurements of TPR and electric resistance2011

    • Author(s)
      H. Yamaura, S. Hirao, H. Yahiro
    • Organizer
      XV.ISHHC
    • Place of Presentation
      ベルリン自由大学(ドイツ)
    • Related Report
      2011 Research-status Report
  • [Presentation] 高温前処理を行ったCuイオン交換ゼオライト上でのPM燃焼反応の評価2011

    • Author(s)
      山浦弘之、赤松竜典、山口修平、八尋秀典
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Study on Perovskite-type Oxide Cathodes for Proton Conducting Solid Oxide Fuel Cells

    • Author(s)
      H. Yamaura, M. Asamoto, S. Yamaguchi, and H. Yahiro
    • Organizer
      International Symposium on Rare Earths 2012 in Okinawa for the 30th Anniversary of The Rare Earth Society of Japan
    • Place of Presentation
      Okinawa Harborview Crowne Plaza(沖縄県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 共沈法によるSn-Zn系複合酸化物の調製および評価

    • Author(s)
      岩崎正孝、中田仁志、山浦弘之、八尋秀典
    • Organizer
      2012日本化学会西日本大会
    • Place of Presentation
      佐賀大学(佐賀県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 貴金属担持酸化スズの室温付近における水素雰囲気中微量CO検知

    • Author(s)
      山浦弘之、八尋秀典
    • Organizer
      第54回化学 センサ研究発表会
    • Place of Presentation
      東北大学(宮城県)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/~achem/solid/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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