Separation of Stereoisomers by Membrane-Embedded Metal Complexes
| Project/Area Number |
23550166
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kansai University |
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Principal Investigator |
YAJIMA Tatsuo 関西大学, 化学生命工学部, 准教授 (40434823)
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| Co-Investigator(Kenkyū-buntansha) |
SHIRAIWA Tadashi 関西大学, 化学生命工学部, 教授 (10067746)
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| Project Period (FY) |
2011 – 2013
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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| Keywords | 分子認識 / 立体異性体 / 金属錯体 / 光学分割 / アミノ酸 / 立体異性体の分離 / 立体異性体の選別 |
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| Research Abstract |
We have studied metal complexes to use for obtaining valuable amino acids from mixtures of stereoisomers, which are prepared by economical synthetic methods. It was revealed that a copper complex containing a tridentate derivative of L-proline analog can bind more strongly to amino acids having a specific configuration than those having the other configuration.
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Report
(4 results)
Research Products
(37 results)
