Synthesis of heat-resistant alloy nanoparticles in aprotic solvent

• Project/Area Number: 23560855
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: ABE Hideki 独立行政法人物質・材料研究機構, 環境再生材料ユニット, 主幹研究員 (60354156)
• Project Period (FY): 2011 – 2013
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2012: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
• Keywords: 超耐熱合金 / 粉末冶金 / ナノ粒子 / 前期遷移金属 / 液相反応 / 常温常圧 / ニッケル / アルミニウム

Research Abstract

We have established a synthetic method for the alloy nanoparticles (NPs, particle size =< 100 nm) which comprise Al or early d-metals and nickel or platinum: Ni-Al NPs, AlPt3 NPs, ZrPt3 NPs, NbPt3 NPs and TaPt3 NPs. These alloy NPs will be breakthrough materials for defects-free, super-heat-resistant products.

Research Products

• [Journal Article] Synthesis and Electrocatalytic Performance of Atomically Ordered Nickel Carbide (Ni3C) Nanoparticles (2014)
  • Author(s): FADILNor Akmal, SARAVANANGovindachetty,GUBBALAVenkata Ramesh,松本太,吉川英樹,上田茂典,田邉豊和,原徹,石原伸輔,有賀克彦,阿部英樹
  • Journal Title: CHEMICAL COMMUNICATIONS Volume: 未定 Issue: 49 Pages: 6451-6453
  • DOI: 10.1039/c4cc01336k
  • Peer Reviewed
• [Journal Article] NbPt3 Intermetallic Nanoparticles: Highly Stable and CO-Tolerant Electrocatalyst for Fuel Oxidation (2014)
  • Author(s): GUBBALAVenkata Ramesh,KODIYATHRajesh,田邉豊和,MANIKANDANMaidhily,藤田武志,松本太,石原伸輔,上田茂典,山下良之,有賀克彦,阿部英樹
  • Journal Title: CHEM ELECTRO CHEM COMMUNICATIONS Volume: 1 Issue: 4 Pages: 728-732
  • DOI: 10.1002/celc.201300240
  • Peer Reviewed
• [Journal Article] Interleaved Mesoporous Copper for the Anode Catalysis in Direct Ammonium Borane Fuel Cells (2014)
  • Author(s): Francis M. Auxilia,田邉豊和,石原伸輔,SARAVANANGovindachetty,GUBBALAVenkata Ramesh,松本太,許亜,有賀克彦,Arivuoli Dakshanamoorthy,阿部英樹
  • Journal Title: JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY Volume: 14 Issue: 6 Pages: 4443-4448
  • DOI: 10.1166/jnn.2014.8278
  • Peer Reviewed
• [Journal Article] Superior CO Catalytic Oxidation on Novel Pt/Clay Nanocomposites (2013)
  • Author(s): Dharmesh Varade, Hideki Abe, Yusuke Yamauchi, Kazutoshi Haraguchi
  • Journal Title: ACS Appl. Mater. Inter. Volume: Vol. 5 Issue: 22 Pages: 11613-11617
  • DOI: 10.1021/am402998q
  • Peer Reviewed
• [Journal Article] Synthesis of Mesoporous Pt–Ru Alloy Particles with Uniform Sizes by Sophisticated Hard-Templating Method (2013)
  • Author(s): PRASANNANKarthika,ATAEEESFAHANIHamed,FRANCISMalar Auxilia,阿部英樹,Natarajan Rajalakshmi, Kaveripatnam S. Dhathathreyan,Dakshinamoorthy Arivuoli,山内悠輔
  • Journal Title: CHEMISTRY-AN ASIAN JOURNAL Volume: 8 Issue: 5 Pages: 902-907
  • DOI: 10.1002/asia.201201107
  • Peer Reviewed
• [Journal Article] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil, G. Saravanan, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, H. Murakami, Noda kazuhiko, H. Abe
  • Journal Title: ADVANCED MATERIALS RESEARCH
  • Peer Reviewed
• [Journal Article] Post-synthesis Dispersion of Metal Nanoparticles by Poly(amidoamine) Dendrimers: Size-selective Inclusion Water Solubilization (2012)
  • Author(s): G. Saravanan
  • Journal Title: Chem. Commun Volume: 48 Issue: 60 Pages: 7441-7443
  • DOI: 10.1039/c2cc31039b
  • Peer Reviewed
• [Journal Article] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil
  • Journal Title: ADVANCED MATERIALS RESEARCH Volume: 557-559 Pages: 442-447
  • Peer Reviewed
• [Journal Article] Influence of pH on dendritic structure of strongly fluorescent persulfate-treated poly(amidoamine) dendrimer (2011)
  • Author(s): G. Saravanan, H. Abe
  • Journal Title: J. Photochemistry and Photobiology A. Volume: 224 Pages: 102-109
  • Peer Reviewed
• [Journal Article] Effective Use of Platinum Group Metals (2011)
  • Author(s): Y. Yamabe-Mitarai, B. Zebinl, H. Murakami, H. Abe and T. Matsumoto
  • Journal Title: J. Japan Inst. Metals Volume: 75 Pages: 10-20
  • NAID: 10027672628
  • Peer Reviewed
• [Presentation] Ordered Early-d-metal Alloy Nanoparticles : Stable, CO-tolerant and High-performance Catalysts for Environmental/energy Applications (2014)
  • Author(s): H. Abe
  • Organizer: AAMSD-2014
  • Place of Presentation: Nagpur, INDIA
  • Year and Date: 2014-01-17
• [Presentation] Ordered Early-d-metal Alloy Nanoparticles: Stable, CO-tolerant and High-performance Catalysts for Environmental/energy Applications (2014)
  • Author(s): 阿部英樹
  • Organizer: AAMSD-2014
  • Place of Presentation: Hotel Tuli Imperial,Nagpur,India
  • Invited
• [Presentation] 有機-金属ハイブリッド燃料電池触媒 (2013)
  • Author(s): 阿部英樹
  • Organizer: ポリマーフロンティア21
  • Place of Presentation: 東京都(13-4)
  • Year and Date: 2013-10-18
• [Presentation] Intermetallic Pt_3Ti Nanoparticles : CO-poisoning Tolerant Electrocatalyst for the Polymer-membrane Electrolyte Fuel Cells (2013)
  • Author(s): Saravanan Govindachetty, V. Gubbala, R. Kodiyath, T. Tanabe, Matsumoto Futoshi, S. Ueda, S. Ishihara, K. Ariga, H. Abe
  • Organizer: India-Japan Symposium on Frontiers in Science & Technology
  • Place of Presentation: 東京都
  • Year and Date: 2013-10-11
• [Presentation] High Quantum Yield Blue Emission from Biocompatible Alloy-implanted Poly(amidoamine) Dendrimer (2013)
  • Author(s): SARAVANANGovindachetty,石岡邦江,李香蘭,箕輪貴司,小堀康博,阿部英樹
  • Organizer: IUMRS-ICAM2013 International Conference on Advanced Materials
  • Place of Presentation: Qingdao International Convention Center,青島、中国
• [Presentation] Interstitial Carbon Activates Transition Metals for Energy-conversion Catalysis (2012)
  • Author(s): N. Fadil, G. Saravanan, F. Matsumoto, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, S. Ishihara, H. Murakami, K. Noda, K. Ariga, H. Abe
  • Organizer: Indian-Japan Symposium on Frontier in Science and Technology
  • Place of Presentation: 東京都
  • Year and Date: 2012-09-20
• [Presentation] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil, G. Saravanan, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, H. Murakami, Kazuhiko NODA, H. Abe
  • Organizer: The 2012 Int. Con. on Chemical Engineering and Advanced Material
  • Place of Presentation: Guangzhou, CHINA
  • Year and Date: 2012-07-13
• [Presentation] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil
  • Organizer: The 2012 Int. Con. on Chemical Engineering and Advanced Material
  • Place of Presentation: Nanyang King’s Gate Hotel（中国・広州）
• [Presentation] Interstitial Carbon Activates Transition Metals for Energy-conversion Catalysis (2012)
  • Author(s): N. Fadil
  • Organizer: Indian-Japan Symposium on Frontier in Science and Technology
  • Place of Presentation: インド大使館（東京）
• [Presentation] 触媒材料の価電子状態を手掛かりとした排ガス清浄化活性の理解と予測 (2011)
  • Author(s): 阿部英樹, SARAVANAN Govindachetty, 吉川英樹, 許亜, 原徹, 山下良之, 上田茂典, 小林啓介
  • Organizer: 日本金属学会第4回触媒材料研究会
  • Place of Presentation: 宮城県
  • Year and Date: 2011-09-01
• [Presentation] 触媒材料の価電子状態を手掛かりとした排ガス清浄化活性の理解と予測 (2011)
  • Author(s): 阿部英樹, Saravanan Govindachetty, 許亜, 吉川英樹, 原徹, 山下良之, 上田茂典, 小林啓介,
  • Organizer: 日本金属学会 第4回触媒材料研究会(招待講演)
  • Place of Presentation: 東北大学
• [Presentation] Solubilization of post-synthesized nanoparticle catalysts by macromolecules (2011)
  • Author(s): 阿部英樹, Saravanan Govindachetty, 吉川英樹, 原徹, 山下良之, 上田茂典, 小林啓介
  • Organizer: 日本金属学会 第4回触媒材料研究会
  • Place of Presentation: 東北大学
• [Presentation] 排ガス清浄化触媒の現状と課題、および白金族元素の需要動向 (2011)
  • Author(s): 阿部英樹, Saravanan Govindachetty, Ya Xu, 吉川英樹, 山下良之, 上田茂典, 小林啓介, 関戸信彰, 御手洗容子, 有賀克彦
  • Organizer: サイエンス＆テクノロジーセミナー(招待講演)
  • Place of Presentation: 東京
• [Presentation] 熱凝集耐性排ガス触媒の開発とレアメタル削減技術 (2011)
  • Author(s): 阿部英樹, Saravanan Govindachetty, Ya Xu, 吉川英樹, 山下良之, 上田茂典, 小林啓介, 関戸信彰, 御手洗容子, 有賀克彦
  • Organizer: NTSセミナー(招待講演)
  • Place of Presentation: 東京
• [Presentation] Intermetallic Pt3Ti Nanoparticles: CO-poisoning Tolerant Electrocatalyst for the Polymer-membrane Electrolyte Fuel Cells
  • Author(s): Saravanan Govindachetty,GUBBALAVenkata Ramesh,KODIYATHRajesh,田邉豊和,松本太,上田茂典,石原伸輔,有賀克彦,阿部英樹
  • Organizer: India-Japan Symposium on Frontiers in Science
  • Place of Presentation: インド大使館,東京都
  • Invited
• [Presentation] Highly Active and Stable Intermetallic Pt3Ta Nanostructure for the Methanol and Ethanol Fuel Cells and Exhaust NO Gas Purification
  • Author(s): KODIYATHRajesh,GUBBALAVenkata Ramesh,田邉豊和,MANIKANDANMaidhily,阿部英樹
  • Organizer: India-Japan Symposium on Frontiers in Science & Technology
  • Place of Presentation: インド大使館,東京都
• [Presentation] 有機－金属ハイブリッド燃料電池触媒
  • Author(s): 阿部英樹
  • Organizer: 13-4 ポリマーフロンティア21
  • Place of Presentation: 東工大蔵前会館,東京都
  • Invited
• [Patent(Industrial Property Rights)] 白金合金ナノ粒子、その製造方法、 白金合金ナノ粒子含有電極及び燃料電池 (2013)
  • Inventor(s): 阿部英樹, グバラベンカタラメシュ, 田邊豊和, コディヤ ス ラジェッシュ, マニカンダン マイディリ, 有賀克彦, 石原伸輔
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Filing Date: 2013-11-28
  • Overseas
• [Patent(Industrial Property Rights)] 多孔質ニッケル合金化合物、その製造方法及び触媒 (2013)
  • Inventor(s): 阿部英樹,田邉豊和,藤田武志,陳明偉
  • Industrial Property Rights Holder: 物質・材料研究機構,東北大学
  • Industrial Property Rights Type: 特許
  • Filing Date: 2013-10-29
• [Patent(Industrial Property Rights)] 白金合金ナノ粒子、その製造方法、白金合金ナノ粒子含有電極及び燃料電池 (2013)
  • Inventor(s): 阿部英樹,Gubbala.R,田邉豊和,Kodiyath.R
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Filing Date: 2013-11-28
• [Patent(Industrial Property Rights)] 小径Ni_3Cナノ粒子及びその製 造方法、小径Ni_3Cナノ粒子含有電極触媒及びその製造方法 (2012)
  • Inventor(s): 阿部英樹, ノール アクマル フ ァディル, 村上秀之, 吉川英樹, 山下良之, 上田茂典, 田邊豊和, グバラベンカタラメッシュ, サラバナンゴビンダッチャリ, 有賀克彦, 石原伸輔
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Filing Date: 2012-11-22
  • Overseas
• [Patent(Industrial Property Rights)] 非水溶媒中の無電解めっき方法 (2012)
  • Inventor(s): 阿部英樹, 村上秀之, ファデルノルアクマル, サラバナンゴバンダチェティ, 田邊豊和, グバラベンガタラメシュ
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Filing Date: 2012-05-21
  • Overseas
• [Patent(Industrial Property Rights)] 非水溶媒中の無電解めっき方法 (2012)
  • Inventor(s): 阿部英樹/村上秀之/ファデルノルアクマルほか
  • Industrial Property Rights Holder: 独立行政法人 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-115600
  • Filing Date: 2012-05-21
• [Patent(Industrial Property Rights)] 小径Ｎｉ３Ｃナノ粒子及びその製造方法、小径Ｎｉ３Ｃナノ粒子含有電極触媒及びその製造方法 (2012)
  • Inventor(s): 阿部英樹/ノールアクマルファディル/村上秀之/吉川英樹ほか
  • Industrial Property Rights Holder: 独立行政法人 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-256243
  • Filing Date: 2012-11-22
• [Patent(Industrial Property Rights)] 耐酸化性NiAlナノ粒子及びその製造方法、耐酸化性NiAlナノ粒子含有ボンドコート層 (2012)
  • Inventor(s): 阿部英樹/ノールアクマルファディル/村上秀之/吉川英樹ほか
  • Industrial Property Rights Holder: 独立行政法人 物質・材料研究機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-287587
  • Filing Date: 2012-12-28
• [Patent(Industrial Property Rights)] 排ガス浄化触媒およびその製造方法 (2011)
  • Inventor(s): 独立行政法人物質・材料研究機構; トヨタ自動車株式会社
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構; トヨタ自動車株式会社
  • Filing Date: 2011