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Preparation and applications of bismuth-layer-structured ferroelectric nanoplates grown epitaxially on Nb:TiO2 substrates

Research Project

Project/Area Number 23560874
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/treatments
Research InstitutionUniversity of Hyogo

Principal Investigator

KOBUNE MASAFUMI  兵庫県立大学, 工学(系)研究科(研究院), 教授 (90240960)

Co-Investigator(Renkei-kenkyūsha) FUJISAWA Hironori  兵庫県立大学, 大学院工学研究科, 准教授 (30285340)
Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords薄膜プロセス / 非平衡プロセス / 界面制御 / 微細加工 / 強誘電体 / ナノプレート / ナノ材料
Research Abstract

a- and b-axis-oriented Bi3.25Nd0.75Ti3O12 (BNT-0.75) and Bi3.25Nd0.75-xEuxTi3O12 (BNEuT, x = 0-0.75) films of 3.0 um thickness were fabricated on conductive Nb:TiO2(101) substrates containing 0-0.79 mass% Nb by high-temperature sputtering. The optimal sputtering conditions (excess Bi2O3, deposition temperature, gas pressure and effective power density) to fabricate the ferroelectric nanoplates were investigated. By evaluating the physical properties of the resultant bismuth layer-structured ferroelectric nanoplates, it was demonstrated that the developed nanoplates had the potential as microelement materials for ferro- and piezoelectric, and multiferroic applications.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (34 results)

All 2014 2013 2012 2011 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (22 results) Remarks (1 results)

  • [Journal Article] Lattice Distortion and Piezoelectric Properties in (Bi_<3.25>Nd_<0.75->xEu_x)Ti_3O_<12> Nanoplates with a- and b-Axis Orientations2014

    • Author(s)
      M. Kobune, T. Kugimiya, Y. Kaneko, Ueshima, T. Kikuchi, N. Fukumuro, H. Matsuda, K. Fukushima, H. Fujisawa, S. Nakashima, and M. Shimizu
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53, 02BC07 Pages: 5-5

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Lattice Distortions and Piezoelectric Properties in (Bi3.25Nd0.75-xEux)Ti3O12 Nanoplates with a- and b-Axis Orientations2014

    • Author(s)
      M. Kobune, T. Kugimiya, Y. Kaneko, S. Ueshima, T. Kikuchi, N. Fukumuro, H. Matsuda, K. Fukushima, H. Fujisawa, S. Nakashima, and M. Shimizu
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Inorganic-Organic Composites containing Ferroelectric Nanoplates and Evaluation of their Piezoelectric Response Characterisitics2013

    • Author(s)
      R. Kishimoto, M. Kobune, H. Nishioka, T. Kikuchi, H. Kishi, H. Fujisawa, S. Nakashima, M. Shimizu, and S. Kimura
    • Journal Title

      J. Korean Phys. Soc.

      Volume: 62 Pages: 999-1003

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Eu^<3+> Doping on Characteristics of (Bi_<3.25>Nd_<0.75>)Ti_3O_<12> Nanoplates2013

    • Author(s)
      M. Kobune, Y. Kaneko, R. Kishimoto, Kugimiya, S. Ueshima, H. Nishioka, T. Kikuchi, H. Fujisawa, S. Nakashima, M. Shimizu, N. Fukumuro, and H. Matsuda
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52, 09KA10 Pages: 5-5

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Inorganic-Organic Composites Containing Ferroelectric Nanoplates and Evaluation of Their Piezoelectric Response Characteristics2013

    • Author(s)
      R. Kishimoto, M. Kobune, H. Nishioka, T. Kikuchi, H. Kishi, H. Fujisawa, S. Nakashima, M. Shimizu, and S. Kimura
    • Journal Title

      J. Korean Phys. Soc.

      Volume: 62 Pages: 999-1003

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Eu3+ Doping on Characteristics of (Bi3.25Nd0.75)Ti3O12 Nanoplates2013

    • Author(s)
      M. Kobune, Y. Kaneko, R. Kishimoto, T. Kugimiya, S. Ueshima, H. Nishioka, H. Fujisawa, S. Nakashima, M. Shimizu, N. Fukumuro, and H. Matsuda
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52

    • NAID

      210000142826

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferro- and Piezoelectric Properites of (Bi_<3.25>Nd_<0.75>)Ti_3O_<12> Nanoplates Epitaxially Grown on Nb : TiO_2(101) Substrates by Sputtering2011

    • Author(s)
      M. Kobune, A. Tamura, K. Imagawa, R. Kishimoto, H. Nishioka, S. Nakashima, H. Fujisawa, M. Shimizu, H. Yamaguchi, and K. Honda
    • Journal Title

      2011 Inter. Sym. on Appli. of Ferroelectrics and 2011 Inter. Sym. on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials

      Volume: 6014115

    • Related Report
      2013 Final Research Report
  • [Journal Article] Effect of Substrate Materials on Physical Properties of Nd-substituted Bi_4Ti_3O_<12> Thin Films with a^- and b-axis Orientations Deposited on IrO_2/Al_2O_3 and Nb:TiO_2 Substrates2011

    • Author(s)
      M. Kobune, H. Oshima, A. Tamura, K. Imagawa, Y. Daiko, A. Mineshige, T. Yazawa, H. Morioka, K. Saito, H. Yamaguchi, and K. Honda
    • Journal Title

      J. Korean Phys. Soc.

      Volume: 59 Pages: 2519-2523

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Characteristics of Epitaxially a- and b-Axis–Oriented (Bi_<3.25>Nd_<0.75>)Ti_3O_<12> Films Fabricated on Conductive Nb : TiO_2 Substrates by High-Temperature Sputtering2011

    • Author(s)
      A. Tamura, M. Kobune, K. Imagawa, Y. Daiko, A. Mineshige, T. Yazawa, H.Nishioka, H. Fujisawa, M. Shimizu, H. Yamaguchi, and K. Honda
    • Journal Title

      J. Korean Phys. Soc.

      Volume: 59 Pages: 2528-2531

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Substrate Materials on the Physical Properties of Nd-Substituted Bi4Ti3O12 Thin Films with a- and b-axis Orientations Deposited on IrO2/Al2O3 and Nb:TiO2 Substrates2011

    • Author(s)
      M. Kobune, H. Oshima, A. Tamura, K. Imagawa, Y. Daiko, A. Mineshige and T. Yazawa
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 59 Pages: 2519-2523

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Characteristics of Epitaxially a- and b-Axis-Oriented (Bi3.25Nd0.75)Ti3O12 Films Fabricated on Conductive Nb:TiO2 Substrates by High-temperature Sputtering2011

    • Author(s)
      A. Tamura, M. Kobune, K. Imagawa, H. Oshima, Y. Daiko, A. Mineshige, T. Yazawa, H. Nishioka, H. Fujisawa and M. Shimizu
    • Journal Title

      Journal of the Korean Physical Society

      Volume: 59 Pages: 2528-2531

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Sr_2Bi_4Ti_5O_<18>ナノプレート構造体の創製と特性評価2014

    • Author(s)
      上島慧史, 小舟正文, 金子勇作, 釘宮拓也, 栗山知侑, 西岡洋, 菊池丈幸, 藤澤浩訓, 中嶋誠二, 清水勝, 福室直樹, 松田均
    • Organizer
      第31回強誘電体応用会議
    • Place of Presentation
      コープイン京都、京都市
    • Year and Date
      2014-05-28
    • Related Report
      2013 Final Research Report
  • [Presentation] スパッタ法による層状構造強誘電体のナノプレート化とその長距離格子整合性2013

    • Author(s)
      上島慧史, 小舟正文, 金子勇作, 釘宮拓也, 西岡洋, 菊池丈幸, 福室直樹, 松田均
    • Organizer
      第8回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      龍谷大学瀬田学舎、大津市
    • Year and Date
      2013-07-26
    • Related Report
      2013 Final Research Report
  • [Presentation] (Bi_<3.25>Nd_<0.75>)Ti_3O_<12>ナノプレートの諸特性に及ぼすEu^<3+>添加効果2013

    • Author(s)
      金子勇作, 小舟正文, 岸本亮, 釘宮拓也, 上島慧史, 西岡洋, 菊池丈幸, 藤澤浩訓, 中嶋誠二, 清水勝
    • Organizer
      第30回強誘電体応用会議
    • Place of Presentation
      コープイン京都、京都市
    • Year and Date
      2013-05-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Lattice Distortions and Piezoelectric Properties in Epitaxial (Bi3.25Nd0.75-xEux)Ti3O12 Nanoplates2013

    • Author(s)
      T. Kugimiya, M. Kobune, R. Kishimoto, Y. Kaneko, S. Ueshima, H. Nishioka, T. Kikuchi, S. Nakashima, H. Fujisawa, and M. Shimizu
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO)
    • Place of Presentation
      Kanazawa, Ishikawa, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structural, and Ferro- and Piezoelectric Characteristics in Epitaxial Eu-Substituted (Bi3.25Nd0.75)Ti3O12 Nanoplates2013

    • Author(s)
      M. Kobune, Y. Kaneko, T. Kugimiya, S. Ueshima, H. Nishioka, T. Kikuchi, S. Nakashima, H. Fujisawa, M. Shimizu, N. Fukumuro, and H. Matsuda
    • Organizer
      The 13th International Meeting on Ferroelectricity (IMF-13)
    • Place of Presentation
      Krakow, Poland
    • Related Report
      2013 Annual Research Report
  • [Presentation] (Bi3.25Nd0.75)Ti3O12ナノプレートの諸特性に及ぼすEu3+添加効果2013

    • Author(s)
      金子勇作、小舟正文、岸本亮、釘宮拓也、上島慧史、西岡洋、菊池丈幸、藤澤浩訓、中嶋誠二、清水勝
    • Organizer
      第30回強誘電体応用会議
    • Place of Presentation
      コープイン京都、日本
    • Related Report
      2013 Annual Research Report
  • [Presentation] スパッタ法による層状構造強誘電体のナノプレート化とその長距離格子整合性2013

    • Author(s)
      上島慧史、小舟正文、釘宮拓也、金子勇作、西岡洋、菊池丈幸、福室直樹、松田均
    • Organizer
      日本セラミックス協会第8回関西支部学術講演会
    • Place of Presentation
      龍谷大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] (Bi3.25Nd0.75-xEux)Ti3O12ナノプレートの電気特性に及ぼすEu3+置換効果2013

    • Author(s)
      釘宮拓也, 小舟正文, 岸本亮, 金子勇作, 上島慧史, 西岡洋, 菊池丈幸
    • Organizer
      日本セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学, 日本
    • Related Report
      2012 Research-status Report
  • [Presentation] Eu3+で置換した(Bi3.25Nd0.75)Ti3O12ナノプレートの作製とその構造特性2013

    • Author(s)
      金子勇作, 小舟正文, 岸本亮, 西岡洋, 菊池丈幸, 釘宮拓也, 上島慧史
    • Organizer
      日本セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学, 日本
    • Related Report
      2012 Research-status Report
  • [Presentation] 強誘電性Bi_<3.25>Nd_<0.75>Ti_3O_<12>ナノプレートの諸特性に及ぼすEu^<3+>添加効果2012

    • Author(s)
      金子勇作, 小舟正文, 岸本亮, 釘宮拓也, 上島慧史, 西岡洋, 菊池丈幸
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学東山キャンパス、名古屋市
    • Year and Date
      2012-09-19
    • Related Report
      2013 Final Research Report
  • [Presentation] Fabrication and Characterization of Inorganic-Organic Composites Using Ferroelectric Nanoplates2012

    • Author(s)
      R. Kishimoto, M. Kobune, H. Nishioka, T. Kikuchi, H. Kishi, H. Fujisawa, S. Nakashima, M. Shimizu, and S. Kimura
    • Organizer
      KJC-FE09 Conference in
    • Place of Presentation
      University of Ulsan, Ulsan, Korea
    • Year and Date
      2012-08-07
    • Related Report
      2013 Final Research Report
  • [Presentation] (Bi,Nd,Eu)_4Ti_3O_<12>ナノプレートの構造及び電気特性2012

    • Author(s)
      岸本亮, 小舟正文, 樽磨直希, 西岡洋, 菊池丈幸, 中嶋誠二, 藤澤浩訓, 清水勝
    • Organizer
      第29回強誘電体応用会議
    • Place of Presentation
      コープイン京都、京都市
    • Year and Date
      2012-05-23
    • Related Report
      2013 Final Research Report
  • [Presentation] (Bi,Nd,Eu)4Ti3O12ナノプレートの構造及び電気特性2012

    • Author(s)
      岸本亮, 小舟正文, 樽磨直希, 西岡洋, 菊池丈幸, 中嶋誠二, 藤澤浩訓, 清水勝
    • Organizer
      第29回強誘電体応用会議
    • Place of Presentation
      コープイン京都, 日本
    • Related Report
      2012 Research-status Report
  • [Presentation] 強誘電性Bi3.25Nd0.75Ti3O12ナノプレートの諸特性に及ぼすEu3+添加効果2012

    • Author(s)
      金子勇作, 小舟正文, 岸本亮, 釘宮拓也, 上島慧史, 西岡洋, 菊池丈幸
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学, 日本
    • Related Report
      2012 Research-status Report
  • [Presentation] Fabrication and Characterization of Inorganic-Organic Composites Using Ferroelectric Nanoplates2012

    • Author(s)
      R. Kishimoto, M. Kobune, H. Nishioka, T. Kikuchi, H. Kishi, H. Fujisawa, S. Nakashima, M. Shimizu, and S. Kimura
    • Organizer
      The 9th Korea-Japan Conference on Ferroelectrics (KJC-FE09)
    • Place of Presentation
      Ulsan, Korea
    • Related Report
      2012 Research-status Report
  • [Presentation] Nb : TiO_2基板上にエピタキシャル成長した強誘電性チタン酸ビスマスネオジウムナノプレートの構造及び電気特性2011

    • Author(s)
      小舟正文, 岸本亮, 西岡洋, 中嶋誠二, 藤澤浩訓, 清水勝, 山口秀史, 本田耕一郎
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学札幌キャンパス、札幌市
    • Year and Date
      2011-09-07
    • Related Report
      2013 Final Research Report
  • [Presentation] rfマグネトロンスパッタリング法を用いて作製した(Bi_<4->xPr_x)Ti_3O_<12>膜の電気及び構造特性2011

    • Author(s)
      岸本亮, 小舟正文, 西岡洋
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学札幌キャンパス、札幌市
    • Year and Date
      2011-09-07
    • Related Report
      2013 Final Research Report
  • [Presentation] 高温スパッタ法による(Bi_<4->xPr_x)Ti_3O_<12>膜の作製とその電気特性2011

    • Author(s)
      岸本亮, 小舟正文, 今川一輝, 田村昭裕, 西岡洋
    • Organizer
      第6回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      イーグレひめじ、姫路市
    • Year and Date
      2011-07-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Ferro- and Piezoelectric Properites of (Bi_<3.25>Nd_<0.75>)Ti_3O_<12> Nanoplates Epitaxially Grown on Nb : TiO_2(101) Substrates by Sputtering2011

    • Author(s)
      M. Kobune, A. Tamura, K. Imagawa, R. Kishimoto, H. Nishioka, H. Fujisawa, M. Shimizu, H. Yamaguchi, and K. Honda
    • Organizer
      ISAF-PFM- 2011 Conference in Vancouver
    • Place of Presentation
      Westin Bayshore Hotel, Vancouver, Canada
    • Year and Date
      2011-07-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Ferro- and Piezoelectric Properties of (Bi3.25Nd0.75)Ti3O12 Nanoplates Epitaxially Grown on Nb:TiO2(101) Substrate by Sputtering2011

    • Author(s)
      M. Kobune, A. Tamura, K. Imagawa, R. Kishimoto, H. Nishioka, H. Fujisawa, M. Shimizu, H. Yamaguchi, and K. Honda
    • Organizer
      The 20th IEEE International Symposium on Applications of Ferroelectrics and International Symposium on Piezoresponse Force Microscopy & Nanoscale Phenomena in Polar Materials (ISAF-PFM-2011)
    • Place of Presentation
      Vancouver, Canada
    • Related Report
      2011 Research-status Report
  • [Presentation] Ferro- and Piezoelectric Properties of (Bi3.25Nd0.75)Ti3O12 Nanoplates Epitaxially Grown on Nb:TiO2(101) Substrates by Sputtering2011

    • Author(s)
      M. Kobune
    • Organizer
      The 19th International Joint Seminar between the Dong-A University & the University of Hyogo(招待講演)
    • Place of Presentation
      釜山、韓国
    • Related Report
      2011 Research-status Report
  • [Presentation] Nb:TiO2基板上にエピタキシャル成長した強誘電性チタン酸ビスマスネオジウムナノプレートの構造及び電気特性2011

    • Author(s)
      小舟正文, 岸本亮, 西岡洋, 中嶋誠二, 藤澤浩訓, 清水勝, 山口秀史, 本田耕一郎
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      北海道大学、日本
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.eng.u-hyogo.ac.jp/msc/msc6/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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