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Characterization of cellulose/silica nanohybrid films prepared by sol-gel processes of cellulose-silane solutions

Research Project

Project/Area Number 23580237
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Wood science
Research InstitutionForestry and Forest Products Research Institute

Principal Investigator

TOGAWA Eiji  独立行政法人森林総合研究所, バイオマス化学研究領域, 主任研究員 (60343810)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2013: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsセルロース / 有機-無機ハイブリッド / 高分子構造・物性 / バイオマス / 有機・無機ハイブリッド / ゾル-ゲル法 / 高次構造
Research Abstract

Cellulose/LiCl/N,N-dimethylacetamide solution and the regenerated cellulose hydro gel prepared from the cellulose solution have been treated by sol-gel processes with alkoxysilanes in order to create cellulose/silica hybrid films to enhance their mechanical properties and thermal stability. The structure and properties of the hybrid films were investigated by X-ray diffraction, SEM, tensile testing, and thermogravimetry. The results revealed that most of the silanes used in this study yielded hybrid films composed of cellulose and silica formed by hydrolysis and condensation reaction of silanes. The tensile strength and thermal stability of the hybrid films were improved over those of the pure regenerated cellulose film. Therefore, this method would show the potential application of developing cellulose-inorganic hybrid materials with high performance.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (11 results)

All 2014 2013 2012 Other

All Presentation (10 results) Book (1 results)

  • [Presentation] アルコキシシランのゾル-ゲル反応を利用して調製したセルロース/シリカハイブリッドフィルムの特性解析2014

    • Author(s)
      戸川英二、菱川裕香子
    • Organizer
      日本木材学会大会
    • Place of Presentation
      愛媛県民文化会館(松山市)
    • Year and Date
      2014-03-13
    • Related Report
      2013 Final Research Report
  • [Presentation] アルコキシシランのゾル-ゲル反応を利用して調製したセルロース/シリカハイブリッドフィルムの特性解析2014

    • Author(s)
      戸川英二、菱川裕香子
    • Organizer
      日本木材学会大会
    • Place of Presentation
      愛媛県民文化会館(愛媛県松山市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Nanoscopic morphology changes of microfibrillated cellulose by endoglucanase2014

    • Author(s)
      Jaehyuk Jang, Noriko Hayashi, Eiji Togawa, Satoshi Kubo, Seunghwan Lee, Namhun Kim
    • Organizer
      The 8th International Conference on Green Composite
    • Place of Presentation
      Seol National University(大韓民国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 再生セルロースゲルとアルコキシシランのゾル-ゲル反応を用いたセルロース/シリカハイブリッドフィルムの調製2013

    • Author(s)
      戸川英二、林徳子
    • Organizer
      日本木材学会大会
    • Place of Presentation
      岩手大学(盛岡市)
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Facile dissolution of cellulose into LiCl / N,N-dimethylacetamide solvent2012

    • Author(s)
      Eiji Togawa、Shigenori Kuga
    • Organizer
      3rd International Cellulose Conference
    • Place of Presentation
      Chateraise Gateaux Kingdom(札幌市)
    • Year and Date
      2012-10-11
    • Related Report
      2013 Final Research Report
  • [Presentation] セルロース/LiCl/ジメチルアセトアミド溶液の簡便調製法とフィルムの作製2012

    • Author(s)
      戸川英二、菱川裕香子、田中良平
    • Organizer
      繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2012-06-07
    • Related Report
      2013 Final Research Report
  • [Presentation] ゾル-ゲル法を用いて調製したセルロース/シリカハイブリッドフィルム2012

    • Author(s)
      戸川英二、林徳子
    • Organizer
      日本木材学会大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2012-03-15
    • Related Report
      2013 Final Research Report
  • [Presentation] ゾル-ゲル法を用いて調製したセルロース/シリカハイブリッドフィルム2012

    • Author(s)
      戸川英二、林徳子
    • Organizer
      第62回日本木材学会大会
    • Place of Presentation
      北海道大学(札幌)
    • Related Report
      2011 Research-status Report
  • [Presentation] Facile dissolution of cellulose into LiCl/N,N-dimethylacetamide solvent

    • Author(s)
      Eiji Togawa, Shigenori Kuga
    • Organizer
      3rd International Cellulose Conference
    • Place of Presentation
      Chateraise Gateaux Kingdom (Sapporo)
    • Related Report
      2012 Research-status Report
  • [Presentation] 再生セルロースゲルとアルコキシシランのゾル-ゲル反応を用いたセルロース/シリカハイブリッドフィルムの調製

    • Author(s)
      戸川英二、林徳子
    • Organizer
      第63回日本木材学会大会
    • Place of Presentation
      岩手大学(盛岡)
    • Related Report
      2012 Research-status Report
  • [Book] セルロースのおもしろ科学とびっくり活用. セルロース学会編2012

    • Author(s)
      戸川英二(分担執筆)
    • Total Pages
      223
    • Publisher
      講談社
    • Related Report
      2013 Final Research Report

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Published: 2011-08-05   Modified: 2019-07-29  

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