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Anomalous Aggregation of Inorganic Anions into Ionic Nanostructures

Research Project

Project/Area Number 23651091
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanostructural science
Research InstitutionOsaka University

Principal Investigator

TAKUMI KONNO  大阪大学, 理学(系)研究科(研究院), 教授 (50201497)

Co-Investigator(Renkei-kenkyūsha) NAKAZAWA Yasuhiro  大阪大学, 大学院・理学研究科, 教授 (60222163)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsイオン結晶 / 自己組織化
Research Abstract

In this study, the creation of ionic nanostructures, in which complex cations are self-assembled through various, multiple non-covalent interactions accompanied by the unusual aggregation of inorganic anions into the interstices surrounded by cationic molecular aggregates, was investigated. This study evidenced that the introduction of multiple non-covalent interactions can lead to the aggregation of complex cations and that the close-packed arrangement of the created cationic aggregates in crystal results in the aggregation of a number of inorganic anions in its interstices.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (21 results)

All 2013 2012 2011 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (6 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand2013

    • Author(s)
      A. Igashira-Kamiyama, A. Fukushima, and T. Konno
    • Journal Title

      Chem. Eur. J

      Volume: 19 Issue: 49 Pages: 16532-16536

    • DOI

      10.1002/chem.201303731

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of <small>L</small>-Cysteinato Rh<sup>III</sup><sub>4</sub>Zn<sup>II</sup><sub>4</sub> Octanuclear to Rh<sup>III</sup><sub>2</sub>Ag<sup>I</sup><sub>3</sub> Pentanuclear Structure by Ag<sup>I</sup> Ions2013

    • Author(s)
      U. Yamashira, P. Lee, N. Kuwamura, N. Yoshinari, and T. Konno
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 86 Issue: 12 Pages: 1450-1452

    • DOI

      10.1246/bcsj.20130200

    • NAID

      130004153169

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A 1:1 intercluster compound consisting of +6 and -6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands2013

    • Author(s)
      Nobuto Yoshinari, Ukyo Yamashita and Takumi Konno
    • Journal Title

      CrystEngComm

      Volume: 15 Issue: 46 Pages: 10016-10019

    • DOI

      10.1039/c3ce41800f

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Heteroleptic Palladium(II) Complexes with Mixed Thiol- and Sulfide-Containing Amino Acids : Self-assembly of Novel Heptanuclear Coordination Oligomers2013

    • Author(s)
      A. Yokoi, N. Yoshinari, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 42 Issue: 8 Pages: 885-887

    • DOI

      10.1246/cl.130318

    • NAID

      10031189284

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Coordination Behavior of a Bipyridine Platinum(II) Complex with Thioglucose2013

    • Author(s)
      T. Tsuji, N. Kuwamura, N. Yoshinari, and T. Konno
    • Journal Title

      Inorg. Chem

      Volume: 52 Issue: 9 Pages: 5350-5358

    • DOI

      10.1021/ic400287g

    • NAID

      120005767248

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] cyclo-Tetrakis(m2-D-penicillaminato-k4N,S:O,S)tetrapalladium(II) 9.75-hydrate2013

    • Author(s)
      Anzu Yokoi, Nobuto Yoshinari and Takumi Konno
    • Journal Title

      Acta Cryst.

      Volume: E69 Issue: 5 Pages: m288-m289

    • DOI

      10.1107/s160053681301088x

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Halide-controlled Construction and Structural Determination of a Series of Thiolato-bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline2012

    • Author(s)
      今野巧、瀧野祐輔
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 3 Pages: 334-336

    • DOI

      10.1246/cl.2012.334

    • NAID

      130004426539

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aggregation of Chiral Hexanuclear Complex-cations into Cationic Metallosupramolecules with Concomitant Aggregation of Inorganic Counter-anions into Anionic Clusters2012

    • Author(s)
      今野巧、李來恩
    • Journal Title

      Cryst Eng Comm

      Volume: 14 Issue: 6 Pages: 1936-1938

    • DOI

      10.1039/c2ce06539h

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thiolato-Bridged Au^I_2Cu^I_2 and Cu^I_4 Metallorings Derived from Benzothiazoline : Can Gold(I) Plus Copper(I) Make Silver(I)?2012

    • Author(s)
      Y. Takino, N. Yoshinari, T. Kawamoto, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 41 Issue: 8 Pages: 834-836

    • DOI

      10.1246/cl.2012.834

    • NAID

      130004426653

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Optically Resolved Crystal of Thiomalate: (S)-1-Phenylethylammonium (R)-Thiomalate2012

    • Author(s)
      Keisuke Igawa
    • Journal Title

      Acta Crystallogra., Sect.C

      Volume: 68 Issue: 9 Pages: o332-o334

    • DOI

      10.1107/s0108270112032933

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Remarkable Enantioselectivity of an L-Cysteinato Co^<III>_3 Complex-anion Toward a Racemic 2-Aminoethanethiolato Co^<III>_2Ag^I_3 Complex-cation2011

    • Author(s)
      H. Q. Yuan, A. Igashira-Kamiyama, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 3 Pages: 285-287

    • DOI

      10.1246/cl.2011.285

    • NAID

      10027815706

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Remarkable Metal-Crossing between Thiolato-Bridged Tetragold(I) and Tetrasilver(I) Metallorings2011

    • Author(s)
      今野巧、瀧野祐輔
    • Journal Title

      Chemistry an Asian Journal

      Volume: 6 Issue: 11 Pages: 2931-2935

    • DOI

      10.1002/asia.201100668

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-assembly of D-Penicillaminato M6M'8 (M = NiII, PdII, PtII; M' = CuI, AgI) Clusters and Their Organization into Extended LaIIIM6M'8 Supramolecular Structures2011

    • Author(s)
      N. Yoshinari, and T. Konno
    • Journal Title

      Dalton Trans

      Volume: 40 Issue: 45 Pages: 12191-12200

    • DOI

      10.1039/c1dt10778j

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rational Creation of Chiral Multinuclear and Metallosupramolecular Compounds from Thiol-containing Amino Acids2011

    • Author(s)
      A. Igashira-Kamiyama, and T. Konno
    • Journal Title

      Dalton Trans

      Volume: 40 Issue: 28 Pages: 7249-7263

    • DOI

      10.1039/c0dt01660h

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Presentation] Metallosupramolecular Architectures Controlled by Metal-Center Chirality of L-Cysteinato Cobalt(III) Octahedrons2013

    • Author(s)
      T. Konno, T, Aridomi, N. Yoshinari, and A. Igashira-Kamiyama
    • Organizer
      25th International Symposium on Chirality
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2013-07-07
    • Related Report
      2013 Final Research Report
  • [Presentation] Self-organization of D-Penicillaminato Metal Clusters into Metallosupramolecular Architectures2012

    • Author(s)
      T. Konno, and N. Yoshinari
    • Organizer
      2012 Collaborative Conference on Crystal Growth
    • Place of Presentation
      Orland, USA
    • Year and Date
      2012-12-13
    • Related Report
      2013 Final Research Report
  • [Presentation] Creation of Supramolecular Architectures Based on Chiral Gold(I) Metalloligands2012

    • Author(s)
      T. Konno
    • Organizer
      40 International Conference on Coordination Chemistry
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      2012-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Self-organization of D-penicillaminato Metal Clusters into Metallosupramolecular Architectures2012

    • Author(s)
      Takumi konno
    • Organizer
      Collaborative Conference on Crystal Growth
    • Place of Presentation
      Orland
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 含硫アミノ酸をもつ金(I)錯体の配位化学2011

    • Author(s)
      今野巧
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Can We Create a Variety of Chiral Hererometallic Compounds from a Single Kind of Amino Acid?2011

    • Author(s)
      今野巧
    • Organizer
      The 11th Global COE International Symposium(招待講演)
    • Place of Presentation
      Osaka
    • Related Report
      2011 Research-status Report
  • [Remarks]

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/konno/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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