Development of Carbon-Carbon Bond Formation Reaction via Formation of Chiral Ion Pair
| Project/Area Number |
23655083
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
BABA Akio 大阪大学, 大学院・工学研究科, 教授 (20144438)
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| Co-Investigator(Renkei-kenkyūsha) |
NISHIMOTO Yoshihiro (30550115)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 有機合成化学 / 有機合成反応 / 触媒反応 / 有機化学 |
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| Research Abstract |
The coupling reaction of alcohol-derivatives with enol acetates was accomplished. This reaction is accelerated by a catalytic amount of indium trihalide to afford various types of α-alkylated ketones and aldehydes. Alkyl ethers, alkyl acetates, and silyl ethers were applicable to this reaction system.
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Report
(3 results)
Research Products
(40 results)
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[Presentation]2011
Author(s)
Onishi, Y.; Nishimoto, Y.; Yasuda, M.; Baba, A.
Organizer
The Seventh International Symposiumon Integrated Synthesis (ISIS-7)
Place of Presentation
Kobe, Japan
Related Report
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