Electrochemically generated trifluoromethyl cation equivalent
| Project/Area Number |
23655085
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
SUGA Seiji 岡山大学, 大学院・自然科学研究科, 教授 (50291430)
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | トリフルオロメチル基 / トリフルオロ酢酸 / 電気化学 / 電解酸化 / マイクロリアクター / 酸化電位 / 電子移動 / カチオン / マイクロ化学 / クラウンエーテル |
|---|
| Research Abstract |
Generation of trifluoromethyl cation equivalents via electrochemical oxidation of trifluoroacetic acid was examined. Although we have not get trifluoromethyl cation equivalents in hand、some important information concerning oxidation of trifluoroacetic acid was obtained. Oxidation potential of trifluoroacetic acid was decreased by ether additives. Electrochemical microflow reactors are potential tools to effectively oxidize trifluoroacetic acid for the trifluoromethylation.
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Report
(3 results)
Research Products
(31 results)
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[Journal Article] Addition of ArSSAr to Alkenes. Implication of a Cationic Chain Mechanism Initiated by Electrogenerated ArS(ArSSAr)+2013
Author(s)
Matsumoto, K.; Sanada, T.; Shimazaki, H.; Shimada, K.; Hagiwara, S.; Fujie, S.; Ashikari, Y.; Suga, S.; Kashimura, S.; Yoshida, J.
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Journal Title
Asian J. Org. Chem.
Volume: 2
Issue: 4
Pages: 325-329
DOI
Related Report
Peer Reviewed
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