| Project/Area Number |
23655205
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Waseda University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
SAITO Hitomi 早稲田大学, 理工学術院, 助手 (50609245)
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| Co-Investigator(Renkei-kenkyūsha) |
PIERRE Hubert Mutin Centre national de la recherche scientifique France, Institut Charles Gerhardt, Director
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| Project Period (FY) |
2011 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 層状 / 層間化合物 / ナノシート / 層状ニオブ酸塩 / 有機ホスホン酸 / グラフト反応 / 有機誘導体 / “ヤヌス”型 / インターカレーション / 層状六ニオブ酸 |
|---|
| Research Abstract |
K_4Nb_6O_<17>・3H_2O ion-exchanged with (C_<18>H_<37>)_2N(CH_3)_2+ ions were reacted with phenylphosphonic acid to prepare a A-type derivative possessing modified an interlayer I. Then, C_<12>H_<25>NH_3+ ions were introduced into an unmodified interlayer II and a resulting intermediate was further treated with carboxyalkylphosphonic acids (COOHCnP;n=1-3). The nanosheets in the products were likely to possess two interlayer surfaces modified with different organophosphonate moieties.
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