| Project/Area Number |
23656423
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Structural/Functional materials
|
|---|
| Research Institution | The University of Tokyo |
|---|
Principal Investigator |
ARAKI Koji 東京大学, 生産技術研究所, 教授 (40134639)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
MUTAI Toshiki 東京大学, 生産技術研究所, 助教 (80313112)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2011: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Keywords | 固体発光材料 / 分子内水素結合 / 励起状態プロトン移動 / ESIPT / イミダゾピリジ ン / 高分子フィルム / 発光制御 / 個体発光 / 励起状態 / 有機発光材料 / 発光色制御 / 固相発光 / ＥＳＩＰＴ |
|---|
| Research Abstract |
Intramolecularly hydrogen-bonded state ocfertain kinds oforganic dyes in polymer matricewsas found tobe sensitive ttohe polarity of thpeolymers. Thedyes showed yellow-green and blue dual emissions fromthe species with and without intramolecular hydrogen bond, respectively. Based on these findingesm,ission colorofthe dyes in polymer thin fwialsm successfully tuned from blue to orbayngceontrolling the relative intensities of the dual emsisbsyionchanging thpeolarity ofthe polymer matrices, which offers a novel mechanism to tune emission colsoorlido-fstate organicdyes.
|
