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Formation of carbon-rich molecules by fast ion impact

Research Project

Project/Area Number 23656591
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nuclear engineering
Research InstitutionTokyo Metropolitan University

Principal Investigator

SHIROMARU Haruo  首都大学東京, 大学院・理工学研究科, 教授 (70196632)

Co-Investigator(Kenkyū-buntansha) MAJIMA Takuya  京都大学, 工学系研究院, 助教 (50515038)
WAKABAYASHI Tomonari  近畿大学, 理工学部, 准教授 (30273428)
Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2012: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2011: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsポリイン / フラーレン / 高速イオン衝突 / 炭素クラスター / 有機溶媒 / 高エネルギーイオン照射 / 高エネルギーイオンビーム / 高密度励起 / non-IPRフラーレン
Research Abstract

To study ion impact induced reactions yielding carbon-rich molecules so called polyynes and fullerenes, n-hexane and n-octane solvent near the melting point were set in rough vacuum conditions and irradiated by a 2 MeV ion beam of H+, or H_2^+. The solid carbon materials and the hydrocarbon vapor were also used as a target. The irradiated samples were analyzed by UV spectroscopy and high performance liquid chromatography. Ion-induced reactions of C_70 solution, polyyne solution and the solid C_60 were also performed.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (12 results)

All 2012 2011 Other

All Journal Article (4 results) (of which Peer Reviewed: 1 results) Presentation (6 results) Remarks (2 results)

  • [Journal Article] Formation of carbon-rich molecules by fast ion impact2012

    • Author(s)
      H. Sugimoto, A. Togashi, Y. Wada, M. Tomioka, T. Kodama, T. Wakabayashi, T. Majima, H. Shiromaru
    • Journal Title

      Annual Report of Quantum Science and Engineering Center

      Volume: 15

    • Related Report
      2012 Final Research Report
  • [Journal Article] Spectroscopic characterization of a series of polyyne-iodine molecular complexes H(C≡C)_nH(I_6) of n = 5-92012

    • Author(s)
      Y. Wada, Y. Morisawa, T. Wakabayashi
    • Journal Title

      Chem.Phys. Lett.

      Volume: 541 Pages: 54-59

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of carbon-rich molecules by fast ion impact2011

    • Author(s)
      Y. Sato, T. Sato, Y. Wada, T. Wakabayashi, B. Wales, Y. Iriki, T. Majima, H. Shiromaru
    • Journal Title

      Annual Report of Quantum Science and Engineering Center

      Volume: 13 Pages: 127-130

    • Related Report
      2012 Final Research Report
  • [Journal Article] Formation of carbon-rich molecules by fast ion impact2011

    • Author(s)
      Y. Sato, T. Sato, Y. Wada, T. Kodama, T. Wakabayashi, T. Majima, H. Shiromaru
    • Journal Title

      Annual Report of Quantum Science and Engineering Center

      Volume: 14 Pages: 107-109

    • Related Report
      2012 Final Research Report
  • [Presentation] 希ガス中グラファイトレーザーアブレーションによるポリインの生成2012

    • Author(s)
      杉本寛征,兒玉健,城丸春夫,和田資子、若林知成,阿知波洋次
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Related Report
      2012 Final Research Report
  • [Presentation] グラファイトレーザーアブレーションで生成した安定炭素クラスターの同定2012

    • Author(s)
      杉本寛征,兒玉健,城丸春夫,和田資子,若林知成,阿知波洋次
    • Organizer
      原子衝突学会第37 回年会
    • Place of Presentation
      電気通信大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 希ガス中グラファイトレーザーアブレーションによるポリインの生成2012

    • Author(s)
      杉本寛征,兒玉健,城丸春夫,和田資子、若林知成,阿知波洋次
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] Laser ablation of graphite in solution with low density hydrogen-containing molecules2012

    • Author(s)
      Yuki Sato, Takeshi Kodama, Haruo Shiromaru, Yohji Achiba
    • Organizer
      第42回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2011 Research-status Report
  • [Presentation] 炭素クラスターを骨格とする分子の生成を目指した高速イオン照射実験2011

    • Author(s)
      佐藤祐旭,佐藤智子,和田資子,若林知成,Wales Benjamin,入来仁隆,間嶋拓也,兒玉 健,城丸春夫
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌市
    • Related Report
      2012 Final Research Report
  • [Presentation] 炭素クラスターを骨格とする分子の生成を目指した高速イオン照射実験2011

    • Author(s)
      佐藤 祐旭,佐藤 智子,和田 資子,若林 知成,Wales Benjamin,入来 仁隆,間嶋 拓也,兒玉 健1,城丸 春夫
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Related Report
      2011 Research-status Report
  • [Remarks] ホームページ

    • URL

      http://www.comp.tmu.ac.jp/physchem3/main/mainmenu1.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.comp.tmu.ac.jp/shiromaruharuo/shiro.html

    • Related Report
      2011 Research-status Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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