| Project/Area Number |
23656601
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Energy engineering
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
KAMEYAMA Hideo 東京農工大学, 大学院・工学研究院, 教授 (10114448)
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| Project Period (FY) |
2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
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| Keywords | アンモニア合成 / 熱化学サイクル / 反応実験 / アンモニア生成の確認 / 化学平衡 / 触媒探索 / 窒素とヨウ化水素の反応 / ヨウ化アンモニウム |
|---|
| Research Abstract |
The experiment was done in the batch device using the autoclave. We tested it at 180 degrees Celsius this time. The formation rates of NH4I from the nitrogen HI increased every time. A value of 3. 60 and 3. 96 was provided each as NH4+density[ mg/L]. But this vales showed the 0. 31mol% of conversion of N_2 in comparison with the equilibrium level of 15mol%. This results showed that a catalyst was necessary for this reaction. We showed the activity that Ru was the highest activity in Ru, Pt, the Rh. Reaction rate of the degree to double 1. 5～2 in comparison with no catalyst was provided. By the experiment of three kinds of supporting materials, in Al2O3, ZrO2, Ta2O5, SiO2 the supporting material of Al_2O_3 was proved to be the highest reaction rate.
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