Development of a nvoel solid electrolyte using protic ionic liquid-type polymer

• Project/Area Number: 23685051
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Polymer/Textile materials
• Research Institution: Tsuruoka National College of Technology
• Principal Investigator: MORINAGA Takashi 鶴岡工業高等専門学校, その他部局等, その他 (30467435)
• Co-Investigator(Renkei-kenkyūsha): SATO Takaya 鶴岡工業高等専門学校, 物質工学科, 教授 (30399258) ; TSUJII Yoshinobu 鶴岡工業高等専門学校, 物質工学科, 教授 (00217308)
• Project Period (FY): 2011-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥30,030,000 (Direct Cost: ¥23,100,000、Indirect Cost: ¥6,930,000); Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2011: ¥21,710,000 (Direct Cost: ¥16,700,000、Indirect Cost: ¥5,010,000)
• Keywords: 複合材料・物性 / 高分子合成 / 高分子構造・物性 / 燃料電池 / ナノ材料

Research Abstract

We have developed a novel solid electrolyte for polymer electrolyte membrane fuel cells (PEFC) that operates under nonhumidified conditions. A protic type of ionic liquid-carrying methacrylate with comical and thermal stability was newly synthesized, and was polymerized via living radical polymerization producing silica particles grafted with ionic liquid-type polymer brush.
The composite films of the hybrid particle and protic ionic liquid were prepared. The ionic conductivity of the solid electrolyte was extremely high. We demonstrated that such newly designed protic solid electrolyte enabled the PEFC operation without humidification.

Research Products

• [Journal Article] Controlled Polymerization of Protic Ionic Liquid Monomer by ARGET-ATRP and TERP (2014)
  • Author(s): Yasuyuki Nakamura, Kouji Nakanishi, Shigeru Yamago, Yoshinobu Tsujii, Kenichi Takahashi, Takashi Morinaga, Takaya Sato
  • Journal Title: Macromolecular Rapid Communications Volume: Vol. 35 Issue: 6 Pages: 642-648
  • DOI: 10.1002/marc.201300855
  • Peer Reviewed
• [Journal Article] Highly Conductive Plastic Crystals Based on Fluorohydrogenate Anions (2012)
  • Author(s): Ryosuke Taniki, Kazuhiko Matsumoto, Rika Hagiwara, Kan Hachiya, TakashiMorinaga and Takaya Sato
  • Journal Title: J Phys Chem B Volume: 117 Issue: 3 Pages: 955-960
  • DOI: 10.1021/jp311558h
  • Peer Reviewed
• [Journal Article] A thin layer including a carbon material improves the rate capability of an electric double layer capacitor (2011)
  • Author(s): Takaya Sato, Shoko Marukane, Takashi Morinaga, Taichi Uemura, Kunihiro Fukumoto, Satoshi Yamazaki
  • Journal Title: Journal of Power Sources Volume: Vol. 196 Issue: 5 Pages: 2835-2840
  • DOI: 10.1016/j.jpowsour.2010.10.095
  • Peer Reviewed
• [Journal Article] Novel solid-state polymer electrolyte of colloidal crystal decorated with ionic-liquid polymer brush (2011)
  • Author(s): T.Sato, T.Morinaga, S.Marukane, T.Narutomi, T.Igarashi, Y.Kawano, K.Ohno, T.Fukuda, Y.Tsujii
  • Journal Title: Adv.Mater. Volume: 23 Issue: 42 Pages: 4868-4872
  • DOI: 10.1002/adma.201101983
  • Peer Reviewed
• [Presentation] Precise synthesis of ionic liquid-type polymer by living radical polymerization and its application for polymer electrolytes (2014)
  • Author(s): Takashi Morinaga
  • Organizer: Energy Technology Research Workshop, Session 2 : Solar Thermal Energy
  • Place of Presentation: Steigenberger Alpenhotel, Gstaad-Saanen, Switzerland
  • Year and Date: 2014-03-10
  • Invited
• [Presentation] イオン液体型濃厚ポリマーブラシ付与シリカ微粒子を用いた燃料電池用電解質の開発 (2013)
  • Author(s): 森永隆志、本間彩夏、丸金祥子、佐藤貴哉、森利之、大野工司、辻井敬亘
  • Organizer: 第23回日本MRS年次大会
  • Place of Presentation: 横浜情報文化センター (A-I10-007)
  • Year and Date: 2013-12-10
  • Invited
• [Presentation] Controlled Synthesis of Protic Ionic Liquid-type Polymer by ARGET-ATRP (2013)
  • Author(s): Shun Tanno, Saika Honma, Takashi Morinaga and Takaya Sato
  • Organizer: The 3rd international Symposium on Technology for Sustainability (ISTS2013)
  • Place of Presentation: THEi Hall Hong Kong Institute of Vocational Education, Tsing Yi, Hong Kong (Session 20-P2 : Applied Science III, ID29)
  • Year and Date: 2013-11-20
• [Presentation] リビングラジカル重合によるイオン液体型ポリマーの構造設計と電池材料への応用 (2013)
  • Author(s): 森永隆志、本間彩夏、丸金祥子、佐藤貴哉、大野工司、辻井敬亘
  • Organizer: 第62回高分子討論会
  • Place of Presentation: (3C09)
  • Year and Date: 2013-09-13
• [Presentation] Development of a Protic Polymer Electrolyte for Fuel Cell using Ionic Liquid-type Polymer (2013)
  • Author(s): Takashi Morinaga, Saika Honma, Takaya Sato, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: IUPAC 44th World chemistry Congress, Material Science
  • Place of Presentation: Istanbul Lutfi Kırdar Congress and Exhibition Center, Istanbul Turkish (P-0399)
  • Year and Date: 2013-08-12
• [Presentation] Development of a Novel Polymer Electrolyte for Fuel Cell using Silica Particles Grafted with Concentrated Ionic-Liquid Polymer Brush (2012)
  • Author(s): Takashi Morinaga, Saika Honma, Takaya Sato, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: IUMRS-International Conference on Electronic Materials
  • Place of Presentation: Pacifico Yokohama, Yokohama, Japan (A2-O27-016, IUMRS-ICEM 2012)
  • Year and Date: 2012-09-27
• [Presentation] 機能性イオン液体によるPEFC用電解質膜の新規設計 (2012)
  • Author(s): 森永隆志、本間彩夏、佐藤貴哉、大野工司、辻井敬亘
  • Organizer: 平成24年度第43回繊維学会夏季セミナー
  • Year and Date: 2012-08-09
• [Presentation] Development of Novel Polymer Electrolyte using Concentrated Polymer Brush and Ionic-Liquids (2012)
  • Author(s): Takashi Morinaga
  • Organizer: The 4th GREEN Symposium
  • Place of Presentation: NIMS, Namiki Site
  • Year and Date: 2012-06-26
• [Presentation] Fabrication of protoic solid-state polymer electrolyte of colloidal crystal decorated with ionic liquid polymer brush (2012)
  • Author(s): Takashi Morinaga, Saika Honma, Takaya Sato, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: International Association of colloid and interface scientists, Conference
  • Place of Presentation: Sendai International Center, Sendai, Japan (S5P16-17, IACIS2012)
  • Year and Date: 2012-05-16
• [Presentation] Fabrication of Protic Solid-State Polymer Electrolyte using Silica Particles Grafted with Ionic Liquid Polymer Brush (2012)
  • Author(s): Takashi Morinaga, Saika Honma, Takaya Sato, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: 1st International Conference on Emerging Advanced Nanomaterials
  • Place of Presentation: Royal On the Park Hotel, Brisbane, Australia (ICEAN-2012, 6E-IL-2)
  • Invited
• [Presentation] Fabrication of protoic solid-state polymer electrolyte of colloidal crystal decorated with ionic liquid polymer brush (2012)
  • Author(s): Takashi Morinaga
  • Organizer: International Association of colloid and interface scientists, Conference (IACIS2012)
  • Place of Presentation: Sendai International Center
• [Presentation] プロトン伝導性イオン液体ポリマーを用いた有機/無機複合固体電解質の創製 (2011)
  • Author(s): 高橋研一, 佐藤俊, 森永隆志, 佐藤貴哉, 大野工司, 辻井敬亘
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-30
• [Presentation] プロトン伝導性イオン液体を用いた固体高分子形燃料用固体電解質膜の創製とその発電特性 (2011)
  • Author(s): 佐藤俊, 森永隆志, 大野工司, 佐藤貴哉, 辻井敬亘
  • Organizer: 平成23年度繊維学会年次大会
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2011-06-11
• [Presentation] Precise synthesis of ionic liquid-type polymer by living radical polymerization and its application for polymer electrolytes
  • Author(s): Takashi Morinaga
  • Organizer: Energy Technology Research Workshop
  • Place of Presentation: Steigenberger Alpenhotel, Gstaad-Saanen, Switzerland
  • Invited
• [Presentation] 多角度光散乱測定法を用いたイオン液体ポリマーの構造解析
  • Author(s): 長谷川 正太，森永 隆志，佐藤 貴哉
  • Organizer: 第19回高専シンポジウム
  • Place of Presentation: 久留米工業高等専門学校
• [Presentation] イオン液体型濃厚ポリマーブラシ付与シリカ微粒子を用いた燃料電池用電解質の開発
  • Author(s): 森永 隆志，本間 彩夏，丸金 祥子，佐藤 貴哉，森 利之，大野 工司，辻井 敬亘
  • Organizer: 第23回日本MRS年次大会
  • Place of Presentation: 横浜情報文化センター
  • Invited
• [Presentation] Synthesis of Protic Ionic Liquid-type Polymer by ARGET-ATRP
  • Author(s): Shun Tanno, Saika Honma, Takashi Morinaga and Takaya Sato
  • Organizer: The 3rd international Symposium on Technology for Sustainability (ISTS2013)
  • Place of Presentation: THEi Hall Hong Kong Institute of Vocational Education, Tsing Yi, Hong Kong
• [Presentation] リビングラジカル重合によるイオン液体型ポリマーの構造設計と電池材料への応用
  • Author(s): 森永 隆志，本間 彩夏，丸金 祥子，佐藤 貴哉，大野 工司，辻井 敬亘
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学角間キャンパス
• [Presentation] 高度に構造制御されたプロトン性アンモニウム塩型イオン液体ポリマーのリビングラジカル重合を用いた合成
  • Author(s): 中村 泰之，仲西 幸二，山子 茂，辻井 敬亘，森永 隆志，佐藤 貴哉
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢大学角間キャンパス
• [Presentation] Novel solid polymer electrolyte for nonflammable lithium ion battery
  • Author(s): Takaya Sato, Takashi Morinaga, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: 246th ACS National Meeting & Exposition
  • Place of Presentation: Hyatt Regency Indianapolis, Room: Regency A, Indianapolis, United States
• [Presentation] Development of a Protic Polymer Electrolyte for Fuel Cell using Ionic Liquid-type Polymer
  • Author(s): Takashi Morinaga, Saika Honma, Takaya Sato, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: IUPAC 44th World chemistry Congress
  • Place of Presentation: Istanbul Lutfi Kirdar Congress and Exhibition Center, Istanbul Turkish
• [Presentation] Novel Solid Polymer Electrolyte for Nonflammable Lithium Ion Battery
  • Author(s): Takaya Sato, Takashi Morinaga, Toshio Kamijo, Kohji Ohno, Yoshinobu Tsujii
  • Organizer: IUPAC 44th World chemistry Congress
  • Place of Presentation: Istanbul Lutfi Kirdar Congress and Exhibition Center, Istanbul Turkish
• [Presentation] プロトン伝導性イオン液体を用いた新規固体高分子形燃料電池の開発
  • Author(s): 本間 彩夏
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] 機能性イオン液体によるPEFC用電解質膜の新規設計
  • Author(s): 森永 隆志
  • Organizer: 平成24年度第43回繊維学会夏季セミナー
  • Place of Presentation: 奈良県新公会堂
• [Presentation] Novel Solid Polymer Electrolyte for High Voltage Energy Storage Devices
  • Author(s): Takaya Sato
  • Organizer: Vth International Conference on Molecular Materials.(MOLMAT 2012)
  • Place of Presentation: AXA Auditorium, Barcelona
• [Presentation] Development of a Novel Polymer Electrolyte for Fuel Cell using Silica Particles Grafted with Concentrated Ionic-Liquid Polymer Brush
  • Author(s): Takashi Morinaga
  • Organizer: IUMRS-International Conference on Electronic Materials (IUMRS-ICEM 2012)
  • Place of Presentation: Pacifico Yokohama
• [Presentation] Fabrication of Protic Solid-State Polymer Electrolyte using Silica Particles Grafted with Ionic Liquid Polymer Brush
  • Author(s): Takashi Morinaga
  • Organizer: 1st International Conference on Emerging Advanced Nanomaterials (ICEAN-2012)
  • Place of Presentation: Royal On the Park Hotel, Brisbane, Australia
  • Invited
• [Book] "Preparation, physicochemical properties and battery applications of a novel poly(ionic liquid)", Chapter27 in Ionic Liquids–New Aspects for the Future, edited by : Dr. Jun-ichi Kadokawa (2013)
  • Author(s): Takaya Sato, Takashi Morinaga, Takeo Ishizuka
  • Publisher: InTech-Open Access Publisher, Rijeka, Croatia, (ISBN 980-953-51-0937-2)
• [Book] Preparation, physicochemical properties and battery applications of a novel poly(ionic liquid) (2013)
  • Author(s): Takaya Sato
  • Total Pages: 23
  • Publisher: InTech-Open Access Publisher
• [Book] "Ionic Liquids for the Electric Double Layer Capacitor Applications", Chapter 6 in Applications of Ionic Liquids in Science and Technology, edited by : Prof. Scott Handy (2011)
  • Author(s): Takaya Sato, Shoko Marukane, Takashi Morinaga
  • Publisher: InTech-Open Access Publisher, Rijeka, Croatia, (ISBN 979-953-307-202-8)
• [Remarks]
  • URL: http://ts.tsuruoka-nct.ac.jp/
• [Remarks] 鶴岡工業高等専門学校 佐藤貴哉研究室 ホームページ
  • URL: http://ts.tsuruoka-nct.ac.jp/
• [Remarks] 鶴岡工業高等専門学校 佐藤貴哉研究室 ホームページ
  • URL: http://ts.tsuruoka-nct.ac.jp/
• [Remarks]
  • URL: http://pr.tsuruoka-nct.ac.jp/~takayasa/
• [Patent(Industrial Property Rights)] ケイ素化合物およびその製造方法、並 びにその利用 (2012)
  • Inventor(s): 菱川 靖浩、小島 正章、森 永 隆志、佐藤 貴哉
  • Industrial Property Rights Holder: 東洋ゴム工業株式会社/独立行政法 人国立高等専門学校機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-084289
  • Filing Date: 2012-04-02
  • Overseas
• [Patent(Industrial Property Rights)] ゴムまたはプラスチック補強材および その製造方法、並びにゴム組成物及びプラス チック組成物 (2012)
  • Inventor(s): 菱川 靖浩、小島 正章、森 永 隆志、佐藤 貴哉
  • Industrial Property Rights Holder: 東洋ゴム工業株式会社/独立行政法 人国立高等専門学校機構
  • Industrial Property Rights Type: 特許
  • Industrial Property Number: 2012-084290
  • Filing Date: 2012-04-02
  • Overseas
• [Patent(Industrial Property Rights)] ケイ素化合物およびその製造方法、並びにその利用 (2012)
  • Inventor(s): 菱川 靖浩，小島 正章，森永 隆志，佐藤 貴哉
  • Industrial Property Rights Holder: 菱川 靖浩，小島 正章，森永 隆志，佐藤 貴哉
  • Industrial Property Rights Type: 特許
  • Filing Date: 2012-04-02