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Preparation of Enzyme-inspired Mn Cluster Catalyst Surfaces and Their Selective Oxidation Performances

Research Project

Project/Area Number 23750068
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

MURATSUGU Satoshi  分子科学研究所, 物質分子科学研究領域, 助教 (20545719)

Project Period (FY) 2011 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsクラスター / マンガン / 酸化物表面 / 固定化 / 触媒 / シリカマトリックス / アルケン / 選択酸化 / 選択的エポキシ化
Research Abstract

New SiO_2-matirx stacked Mn cluster catalysts were prepared by the attachment of a Mn tetranuclear cluster on a SiO_2 surface and the successive stacking of SiO_2 matrix overlayers around the supported Mn cluster on the SiO_2 surface. The surface SiO_2-matrix overlayers significantly improved the stability of the supported Mn cluster and high catalytic activity, selectivity, and recyclability were achieved for the selective epoxidation of alkenes.

Report

(3 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Research-status Report
  • Research Products

    (27 results)

All 2013 2012 2011 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (18 results) (of which Invited: 4 results) Book (3 results)

  • [Journal Article] Dispersed Ru Nanoclusters Transformed from A Grafted Trinuclear Ru Complex on SiO2 for Selective Alcohol Oxidation2013

    • Author(s)
      Satoshi Muratsugu, Min Hwee Lim, Takahiro Itoh, Wipavee Thumrongpatanaraks, Mio Kondo, Shigeyuki Masaoka, T. S. Andy Hor, Mizuki Tada
    • Journal Title

      Dalton Transactions

      Volume: 42 Issue: 35 Pages: 12611-12619

    • DOI

      10.1039/c3dt51142a

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecularly Imprinted Ru-Complex Catalyst Systems Integrated on Oxide Surfaces2013

    • Author(s)
      Satoshi Muratsugu, Mizuki Tada
    • Journal Title

      Accounts of Chemical Research

      Volume: 46 Issue: 2 Pages: 300-311

    • DOI

      10.1021/ar300142p

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 位置選択的反応を指向した表面モレキュラーインプリンティングRu錯体触媒の創製2013

    • Author(s)
      邨次 智・唯美津木
    • Journal Title

      ナノ学会会報

      Volume: 11

    • NAID

      40019741157

    • Related Report
      2012 Annual Research Report
  • [Journal Article] Preparation and catalytic performances of a molecularly imprinted Ru-complex catalyst with an NH_2 binding site on a SiO_2 surface2012

    • Author(s)
      Yong Yang, Zhihuan Weng, Satoshi Muratsugu, Nozomu Ishiguro, Shin-ichi Ohkoshi, Mizuki Tada
    • Journal Title

      Chemistry-A European Journal

      Volume: 18 Issue: 4 Pages: 1142-1153

    • DOI

      10.1002/chem.201100529

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sulfoxidation on a SiO2-Supported Ru Complex Using O2/Aldehyde System2012

    • Author(s)
      Niladri Maity, Chularat Wattanakit, Satoshi Muratsugu, Nozomu Ishiguro, Yong Yang, Shin-ichi Ohkoshi, Mizuki Tada
    • Journal Title

      Dalton Transactions

      Volume: 41 Issue: 15 Pages: 4558-4565

    • DOI

      10.1039/c2dt12133f

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface-Assisted Transfer Hydrogenation Catalysis on a gamma-Al2O3-Supported Ir Dimer2012

    • Author(s)
      Satoshi Muratsugu, Zhihuan Weng, Hidetaka Nakai, Kiyoshi Isobe, Yuko Kushida, Takehiko Sasaki, Mizuki Tada
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 14 Issue: 46 Pages: 16023-16031

    • DOI

      10.1039/c2cp43106h

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属錯体の酸化物表面プログラミングによる触媒機能創出2012

    • Author(s)
      邨次 智
    • Organizer
      新学術領域研究 若手合同シンポジウム「配位プログラム」×「融合マテリアル」
    • Place of Presentation
      東京大学 (東京都) (招待講演)
    • Year and Date
      2012-12-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 金属錯体と酸化物表面を駆使した不均一系触媒の創製2012

    • Author(s)
      邨次 智
    • Organizer
      錯体化学若手の会中部支部勉強会
    • Place of Presentation
      名古屋大学 (愛知県) (招待講演)
    • Year and Date
      2012-12-01
    • Related Report
      2012 Final Research Report
  • [Presentation] 表面シリカマトリックスによる固定化Mn クラスター触媒の安定化とアルケン類の選択的エポキシ化反応特性2012

    • Author(s)
      邨次 智・翁 志換・唯美津木
    • Organizer
      第45回酸化反応討論会
    • Place of Presentation
      名古屋市立大学 (愛知県)
    • Year and Date
      2012-11-16
    • Related Report
      2012 Final Research Report
  • [Presentation] 酸化物表面を媒体とした固定化金属錯体触媒の創製2012

    • Author(s)
      邨次 智
    • Organizer
      第43回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋工業大学 (愛知県) (招待講演)
    • Year and Date
      2012-11-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Design and Functionalization of Oxide-supported Transition Metal Complex Catalysts for Heterogeneous Catalysis2012

    • Author(s)
      Satoshi Muratsugu
    • Organizer
      2nd International Conference on Molecular and Functional Catalysis (ICMFC-2)
    • Place of Presentation
      Biopolis (SINGAPORE) (招待講演)
    • Year and Date
      2012-07-31
    • Related Report
      2012 Final Research Report
  • [Presentation] 表面マトリックスで保護された酸化物表面固定化Mn クラスターの調製とそのエポキシ化反応特性2012

    • Author(s)
      邨次 智・翁 志換・唯 美津木
    • Organizer
      第92回日本化学会年会
    • Place of Presentation
      慶應義塾大学 (神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2012 Final Research Report
  • [Presentation] 表面マトリックスで保護された酸化物表面固定化Mnクラスターの調製とそのエポキシ化反応特性2012

    • Author(s)
      邨次 智・翁 志換・唯 美津木
    • Organizer
      第92回日本化学会年会
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 表面を媒体とした新しいMn クラスター選択酸化触媒の創出2011

    • Author(s)
      邨次 智・翁 志換・唯 美津木
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学 (岡山県)
    • Year and Date
      2011-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 表面を媒体とした新しいMnクラスター選択酸化触媒の創出2011

    • Author(s)
      邨次 智・翁 志換・唯 美津木
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(岡山県)
    • Related Report
      2011 Research-status Report
  • [Presentation] 金属錯体の酸化物表面プログラミングによる触媒機能創出

    • Author(s)
      邨次 智
    • Organizer
      新学術領域研究 若手合同シンポジウム 「配位プログラム」×「融合マテリアル」
    • Place of Presentation
      東京大学(東京都)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 金属錯体と酸化物表面を駆使した不均一系触媒の創製

    • Author(s)
      邨次 智
    • Organizer
      錯体化学若手の会中部支部勉強会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 表面シリカマトリックスによる固定化Mnクラスター触媒の安定化とアルケン類の選択的エポキシ化反応特性

    • Author(s)
      邨次 智・翁 志換・唯美津木
    • Organizer
      第45回酸化反応討論会
    • Place of Presentation
      名古屋市立大学(愛知県)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 酸化物表面を媒体とした固定化金属錯体触媒の創製

    • Author(s)
      邨次 智
    • Organizer
      第43回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Design of a Molecularly Imprinted Ru Complex Catalyst with a Molecular Binding Site on a SiO2 Surface

    • Author(s)
      Satoshi Muratsugu, Yong Yang, Zhihuan Weng, Nozomu Ishiguro, Mizuki Tada
    • Organizer
      7th International Conference on Molecular Imprinting (MIP2012)
    • Place of Presentation
      AgroParisTech, Paris (FRANCE)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation of Surface Molecularly Imprinted Ru Complex Catalysts for Asymmetric Transfer Hydrogenation Catalysis in Water

    • Author(s)
      Satoshi Muratsugu, Zhihuan Weng, Nozomu Ishiguro, Mizuki Tada
    • Organizer
      7th International Conference on Molecular Imprinting (MIP2012)
    • Place of Presentation
      AgroParisTech, Paris (FRANCE)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Design and Functionalization of Oxide-supported Transition Metal Complex Catalysts for Heterogeneous Catalysis

    • Author(s)
      Satoshi Muratsugu
    • Organizer
      2nd International Conference on Molecular and Functional Catalysis (ICMFC-2)
    • Place of Presentation
      Biopolis (SINGAPORE)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Structure and Surface-Assisted Transfer Hydrogenation of gamma-Al2O3-Supported Ir dimer

    • Author(s)
      Satoshi Muratsugu, Zhihuan Weng, Hidetaka Nakai, Kiyoshi Isobe, Takehiko Sasaki, Mizuki Tada
    • Organizer
      15th International Congress on Catalysis (15th ICC 2012)
    • Place of Presentation
      International Congress Center Munich, Munich (GERMANY)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Preparation and Surface-Mediated Transfer Hydrogenation of Ir Dimer Catalyst Supported on gamma-Al2O3 Surface

    • Author(s)
      Satoshi Muratsugu, Zhihuan Weng, Hidetaka Nakai, Kiyoshi Isobe, Takehiko Sasaki, Mizuki Tada
    • Organizer
      International Association of Colloid and Interface Scientists (IACIS 2012)
    • Place of Presentation
      Sendai International Center, Sendai, Miyagi (JAPAN)
    • Related Report
      2012 Annual Research Report
  • [Book] "Site-Isolated Heterogeneous Catalysts" in "Handbook of Heterogeneous Catalysts"2013

    • Author(s)
      Mizuki Tada, Satoshi Muratsugu
    • Publisher
      Wiley-VCH
    • Related Report
      2012 Annual Research Report
  • [Book] "MIPs as Catalysts and Artificial Enzymes" in "Imprinted Polymers: A Handbook for Academia and Industry"2013

    • Author(s)
      Satoshi Muratsugu, Mizuki Tada
    • Publisher
      iSmithers
    • Related Report
      2012 Annual Research Report
  • [Book] MIPs as Catalysts and Artificial Enzymes in "Imprinted Polymers : A Handbook for Academia and Industry"

    • Author(s)
      S. Muratsugu, M. Tada
    • Publisher
      iSmithers (in press)
    • Related Report
      2012 Final Research Report

URL: 

Published: 2011-08-05   Modified: 2019-07-29  

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