Synthesis and Photophysical properties of the novel planar arylborane compounds
| Project/Area Number |
23750141
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials chemistry
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| Research Institution | Nagasaki University (2014)
Hokkaido University (2011-2013) |
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Principal Investigator |
SAKUDA Eri 長崎大学, 工学研究科, 准教授 (80554378)
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| Project Period (FY) |
2011-04-28 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 光化学 / 典型元素 |
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| Outline of Final Research Achievements |
In this study, we synthesized and measured the photophysical properties of triarylborane compounds by controlling the substituent and size of the steric hindrance of the aryl group. As a result, by changing the combination of cored aryl moieties and the electron-donating groups as substituent of the aryl boron compounds, to achieve a control of the emission colors in a wide wavelength. Furthermore, by introducing a arylborane group and an amino group to azobenzene. As a result, we were synthesized and evaluated the photophysical and photofunctional properties of the novel azobenzene compounds having both amino and arylborane group.
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Report
(5 results)
Research Products
(23 results)
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[Journal Article] Synthesis of yellow and red fluorescent 1,3a,6a-triazapentalenes and the theoretical investigation of their optical properties2015
Author(s)
Kosuke Namba, Ayumi Osawa, Akira Nakayama, Akane Mera, Fumi Tano, Yoshiro Chuman, Eri Sakuda, Tetsuya Taketsugu, Kazuyasu Sakaguchi, Noboru Kitamura, Keiji Tanino
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Journal Title
Chemical Science
Volume: 6
Issue: 2
Pages: 1083-1093
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Constraint-induced structural deformation of planarized triphenylboranes in the excited state2014
Author(s)
Kushida, T. ; Camacho, C. ; Shuto, A. ; Irle, S. ; Muramatsu, M. ; Katayama, T. ; Ito, S. ; Nagasawa, Y. ; Miyasaka, H. ; Sakuda, E. ; Kitamura, N. ; Zhou, Z. ; Wakamiya, A. ; Yamaguchi, S.
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Journal Title
Chemical Science
Volume: 5
Issue: 4
Pages: 1296-1304
DOI
Related Report
Peer Reviewed
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