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Synthesis and Photophysical properties of the novel planar arylborane compounds

Research Project

Project/Area Number 23750141
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionNagasaki University (2014)
Hokkaido University (2011-2013)

Principal Investigator

SAKUDA Eri  長崎大学, 工学研究科, 准教授 (80554378)

Project Period (FY) 2011-04-28 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords光化学 / 典型元素
Outline of Final Research Achievements

In this study, we synthesized and measured the photophysical properties of triarylborane compounds by controlling the substituent and size of the steric hindrance of the aryl group. As a result, by changing the combination of cored aryl moieties and the electron-donating groups as substituent of the aryl boron compounds, to achieve a control of the emission colors in a wide wavelength. Furthermore, by introducing a arylborane group and an amino group to azobenzene. As a result, we were synthesized and evaluated the photophysical and photofunctional properties of the novel azobenzene compounds having both amino and arylborane group.

Report

(5 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013 2012 2011

All Journal Article (10 results) (of which Peer Reviewed: 9 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Invited: 2 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 2 results)

  • [Journal Article] Synthesis of yellow and red fluorescent 1,3a,6a-triazapentalenes and the theoretical investigation of their optical properties2015

    • Author(s)
      Kosuke Namba, Ayumi Osawa, Akira Nakayama, Akane Mera, Fumi Tano, Yoshiro Chuman, Eri Sakuda, Tetsuya Taketsugu, Kazuyasu Sakaguchi, Noboru Kitamura, Keiji Tanino
    • Journal Title

      Chemical Science

      Volume: 6 Issue: 2 Pages: 1083-1093

    • DOI

      10.1039/c4sc02780a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dual Emissions from Ruthenium(II) Complexes Having 4-Arylethynyl-1,10- phenanthroline at Low Temperature2015

    • Author(s)
      E. Sakuda, C. Matsumoto, Y. Ando, A. Ito, K. Mochida, A. Nakagawa, N. Kitamura
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 7 Pages: 3245-3252

    • DOI

      10.1021/ic502843x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthetic Control of Spectroscopic and Photophysical Properties of Triarylborane Derivatives Having Peripheral Electron-Donating Groups2014

    • Author(s)
      Akitaka Ito, Kazuyoshi Kawanishi, Eri Sakuda and Noboru Kitamura
    • Journal Title

      Chem.-Eur. J.

      Volume: 20 Issue: 14 Pages: 3940-3953

    • DOI

      10.1002/chem.201304207

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Constraint-induced structural deformation of planarized triphenylboranes in the excited state2014

    • Author(s)
      Kushida, T. ; Camacho, C. ; Shuto, A. ; Irle, S. ; Muramatsu, M. ; Katayama, T. ; Ito, S. ; Nagasawa, Y. ; Miyasaka, H. ; Sakuda, E. ; Kitamura, N. ; Zhou, Z. ; Wakamiya, A. ; Yamaguchi, S.
    • Journal Title

      Chemical Science

      Volume: 5 Issue: 4 Pages: 1296-1304

    • DOI

      10.1039/c3sc52751d

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoluminescence Switching with Changes in the Coordination Number and Coordinating Volatile Organic Compounds in Tetracyanidonitridorhenium(V) and -technetium(V) Complexes2012

    • Author(s)
      H. Ikeda, T. Yoshimura, A. Ito, E. Sakuda, N. Kitamura, T. Takayama, T. Sekine and A. Shinohara
    • Journal Title

      Inorg. Chem.

      Volume: 51 Issue: 22 Pages: 12065-12074

    • DOI

      10.1021/ic202243d

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] One-Pot Synthesis of Highly Fluorescent 2,5-Disubstituted-1,3a,6a-triazapentalene2012

    • Author(s)
      K. Namba, A. Mera, A. Osawa, E. Sakuda, N. Kitamura and K. Tanino
    • Journal Title

      Org. Lett.

      Volume: 14 Issue: 21 Pages: 5554-5557

    • DOI

      10.1021/ol302668y

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photophysical and Photoredox Characteristics of a Novel Tricarbonyl Rhenium(I) Complex Having an Arylborane-appended Aromatic Diimine Ligand2012

    • Author(s)
      A. Ito, Y. Kang, S. Saito, E. Sakuda and N. Kitamura
    • Journal Title

      Inorg. Chem.

      Volume: 51 Issue: 14 Pages: 7722-7732

    • DOI

      10.1021/ic3007469

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Dynamic Emission Quenching of a Novel Ruthenium(II) Complex by Carbon Dioxide in Solution2012

    • Author(s)
      E. Sakuda, M. Tanaka, A. Ito and N. Kitamura
    • Journal Title

      RSC Advances

      Volume: 2 Issue: 4 Pages: 1296-1298

    • DOI

      10.1039/c2ra00268j

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct Observation of a {Re(6)m(3)-S)(8)} Core-to-Ligand Charge-Transfer Excited State in an Octahedral Hexarhenium Complex2011

    • Author(s)
      T. Yoshimura, S. Ishizaka, T. Kashiwa, A. Ito, E. Sakuda, A. Shinohara and N. Kitamura
    • Journal Title

      Inorg. Chem

      Volume: 50 Issue: 20 Pages: 9918-9920

    • DOI

      10.1021/ic2010858

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] 新たな骨格を用いた蛍光プローブの開発2011

    • Author(s)
      作田 絵里
    • Journal Title

      ぶんせき

      Volume: 無 Pages: 728-728

    • Related Report
      2011 Research-status Report
  • [Presentation] アリールホウ素化合物の光物性と光反応2015

    • Author(s)
      作田 絵里
    • Organizer
      九州錯体化学懇談会第247回例会
    • Place of Presentation
      熊本大学 黒髪キャンパス (熊本県熊本市)
    • Year and Date
      2015-02-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 新規ジピロメテン系配位子を有するルテニウム(II)錯体の合成と光化学物性2015

    • Author(s)
      菅野 瑛一, 作田 絵里, 喜多村 曻
    • Organizer
      化学系学協会北海道支部2015年冬季研究発表会
    • Place of Presentation
      北海道大学 フロンティア応用科学研究棟 (北海道札幌市)
    • Year and Date
      2015-01-27 – 2015-01-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] アリールホウ素化合物を利用した新規二酸化炭素光還元反応の構築に向けて2013

    • Author(s)
      作田絵里
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学 (松山市)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] アリールホウ素を置換基として有する遷移金属錯体の光化学物性とその利用2013

    • Author(s)
      作田絵里
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学 (中頭郡西原町)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ヘテロ原子置換基を有する新規アゾベンゼン誘導体の合成、光化学物性および光機能性2013

    • Author(s)
      高橋弘人、作田絵里、伊藤亮孝、喜多村 曻
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀)
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis, Photophysical and Photofunctional Properties of Novel Azobenzene Derivatives Having Hetero-atom Substituents2012

    • Author(s)
      Hiroto Takahashi, Eri Sakuda, Akitaka Ito and Noboru Kitamura
    • Organizer
      7th Asian and Oceanian Photochemistry Conference
    • Place of Presentation
      銀杏会館(大阪)
    • Related Report
      2012 Research-status Report
  • [Presentation] 電子供与基を有する新規トリアリールホウ素化合物の光化学物性2011

    • Author(s)
      川西 一嘉、伊藤 亮孝、作田 絵里、喜多村 曻
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎市河畔コンベンションエリア(宮崎市)
    • Related Report
      2011 Research-status Report
  • [Presentation] 電子供与基を有するトリアリールホウ素化合物の発光特性制御2011

    • Author(s)
      川西 一嘉、伊藤 亮孝、作田 絵里、喜多村 曻
    • Organizer
      第22回基礎有機化学討論会
    • Place of Presentation
      つくば国際会議場(つくば市)
    • Related Report
      2011 Research-status Report
  • [Presentation] Synthetic Control of Spectroscopic and Photophysical Properties of Triarylborane Compounds Having Electron-donating Groups2011

    • Author(s)
      Kazuyoshi Kawanishi, Akitaka Ito, Eri Sakuda and Noboru Kitamura
    • Organizer
      The 7th Nanjing University& Hokkaido University Joint Symposium & 2011 NJU & SUDA & HKU & NIMS/MANA Joint Symposium
    • Place of Presentation
      蘇州大学(中国)
    • Related Report
      2011 Research-status Report
  • [Presentation] アリールホウ素化合物およびそれらを置換基として有する遷移金属錯体の光化学物性と光機能性2011

    • Author(s)
      作田 絵里
    • Organizer
      材料フォーラム「光分子工学」(招待講演)
    • Place of Presentation
      産業技術研究所(つくば市)
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] ボラン化合物と共役高分子化合物とを含む組成物及び素子2011

    • Inventor(s)
      喜多村曻, 伊藤亮孝, 作田絵里, 川西一嘉, 石井佑典
    • Industrial Property Rights Holder
      喜多村曻, 伊藤亮孝, 作田絵里, 川西一嘉, 石井佑典
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report
  • [Patent(Industrial Property Rights)] 金属錯体及び該金属錯体を用いた素子2011

    • Inventor(s)
      喜多村曻, 作田絵里, 伊藤亮孝, 廣川健夫, 関根千津
    • Industrial Property Rights Holder
      喜多村曻, 作田絵里, 伊藤亮孝, 廣川健夫, 関根千津
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 金属錯体及び該金属錯体を用いた素子2011

    • Inventor(s)
      喜多村曻, 作田絵里, 伊藤亮孝, 廣川健夫, 関根千津
    • Industrial Property Rights Holder
      喜多村曻, 作田絵里, 伊藤亮孝, 廣川健夫, 関根千津
    • Filing Date
      2011
    • Related Report
      2011 Research-status Report
    • Overseas

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Published: 2011-08-05   Modified: 2019-07-29  

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