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Elimination of interface defects at SiC/insulator by introducing phosphorus and other atoms toward innovation of power MOSFETs

Research Project

Project/Area Number 23760283
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionUniversity of Tsukuba (2013)
Nara Institute of Science and Technology (2011-2012)

Principal Investigator

YANO Hiroshi  筑波大学, 数理物質系, 准教授 (40335485)

Project Period (FY) 2011 – 2013
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords炭化ケイ素 / MOSFET / 界面準位 / しきい値変動 / リン / 炭化珪素
Research Abstract

In order to realize high-performance SiC power MOSFETs, defects at the SiC/insulator interface should be reduced greatly. In this study, effects of phosphorus introduction into the interface on the reduction of interface defects and improvement in MOSFET performance were investigated. In addition combination effects of phosphorus with hydrogen or nitrogen were also investigated. The channel mobility was improved by combination of phosphorus and hydrogen. The flatband and threshold voltage shifts were successfully minimized by both methods of combination of phosphorus and nitrogen and localization of phosphorus near the interface. The model of trap distribution in the SiC MOS structure was built from the threshold voltage instability experiments using various bias conditions and temperatures.

Report

(4 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • 2011 Research-status Report
  • Research Products

    (43 results)

All 2014 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (31 results) (of which Invited: 8 results) Book (4 results)

  • [Journal Article] Reduction of SiC-MOS Interface Traps and Improved MOSFET Performance by Phosphorus Incorporation into Gate Oxides2014

    • Author(s)
      矢野裕司,畑山智亮,冬木隆
    • Journal Title

      Hyomen Kagaku

      Volume: 35 Issue: 2 Pages: 90-95

    • DOI

      10.1380/jsssj.35.90

    • NAID

      130004785041

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Improved Stability of 4H-SiC MOS Device Properties by Combination of NO and POCl3 annealing2013

    • Author(s)
      H. Yano, T. Araoka, T. Hatayama, and T. Fuyuki
    • Journal Title

      Mater. Sci. Forum

      Volume: 740-742 Pages: 727-732

    • DOI

      10.4028/www.scientific.net/msf.740-742.727

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of POCl3- and NO-annealed 4H-SiC MOSFETs by Charge Pumping Technique2013

    • Author(s)
      A. Osawa, H. Yano, T. Hatayama, and T. Fuyuki
    • Journal Title

      Mater. Sci. Forum

      Volume: 740-742 Pages: 541-544

    • DOI

      10.4028/www.scientific.net/msf.740-742.541

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Interface Localization of Phosphorus on Electrical Properties and Reliability of 4H-SiC MOS Devices2013

    • Author(s)
      T. Akagi, H. Yano, T. Hatayama, and T. Fuyuki
    • Journal Title

      Mater. Sci. Forum

      Volume: 740-742 Pages: 695-698

    • DOI

      10.4028/www.scientific.net/msf.740-742.695

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] POCl3 Annealing as a New Method for Improving 4H-SiC MOS Device Performance2012

    • Author(s)
      H. Yano, T. Hatayama, and T. Fuyuki
    • Journal Title

      ECS Trans.

      Volume: 50 Issue: 3 Pages: 257-265

    • DOI

      10.1149/05003.0257ecst

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of 4H-SiC MOSFETs with Phosphorus-Doped Gate Oxide2012

    • Author(s)
      D. Okamoto, H. Yano, T. Hatayama, and T. Fuyuki
    • Journal Title

      Mater. Sci. Forum

      Volume: 未定

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of POCl3 annealing on Reliability of Thermal Oxides Grown on 4H-SiC2012

    • Author(s)
      R. Morishita, H. Yano, D. Okamoto, T. Hatayama, and T. Fuyuki
    • Journal Title

      Mater. Sci. Forum

      Volume: 未定

    • Related Report
      2011 Research-status Report
    • Peer Reviewed
  • [Journal Article] SiO2/p型4H-SiC界面特性におけるPOCl3アニールの効果2011

    • Author(s)
      高上稔充, 矢野裕司, 畑山智亮, 冬木隆
    • Journal Title

      信学技報

      Volume: 111 Pages: 11-15

    • Related Report
      2011 Research-status Report
  • [Presentation] Comparative Study of Threshold Voltage Instability in 4H-SiC MOSFETs with POCl_3- and NO- Annealed Gate Oxides2013

    • Author(s)
      H. Yano, A. Osawa, T. Hatayama, and T. Fuyuki
    • Organizer
      The International Conference on Silicon Carbide and Related Materials 2013 (ICSCRM2013)
    • Place of Presentation
      Miyazaki (Japan)
    • Year and Date
      2013-10-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Comparative Study of Threshold Voltage Instability in 4H-SiC MOSFETs with POCl3- and NO- Annealed Gate Oxides2013

    • Author(s)
      H. Yano, A. Osawa, T. Hatayama, and T. Fuyuki
    • Organizer
      The International Conference on Silicon Carbide and Related Materials 2013 (ICSCRM2013)
    • Place of Presentation
      シーガイア・コンベンションセンター(宮崎県宮崎市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] チャージポンピング法によるSiC-MOS界面特性の評価2013

    • Author(s)
      矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連半導体研究 第22回講演会
    • Place of Presentation
      埼玉会館(埼玉県さいたま市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 4H-SiC Si面上における表面ラフネスがMOSFETの電気特性に及ぼす影響2013

    • Author(s)
      串阪哲也, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連半導体研究 第22回講演会
    • Place of Presentation
      埼玉会館(埼玉県さいたま市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 界面にリンおよび窒素を導入した4H-SiC MOSFETの高温下におけるしきい値電圧不安定性の考察2013

    • Author(s)
      金藤夏子, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連半導体研究 第22回講演会
    • Place of Presentation
      埼玉会館(埼玉県さいたま市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] SiC-MOSデバイスの界面欠陥低減技術2013

    • Author(s)
      矢野裕司
    • Organizer
      SEMI FORUM JAPAN 2013
    • Place of Presentation
      グランキューブ大阪(大阪府大阪市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] POCl_3 Annealing as a New Method for Improving 4H-SiC MOS Device Performance2012

    • Author(s)
      H. Yano, T. Hatayama, and T. Fuyuki
    • Organizer
      PRiME 2012 (Pacific Rim Meeting on Electrochemical and Solid-State Science)
    • Place of Presentation
      Honolulu (HI, USA)
    • Year and Date
      2012-10-10
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Improved Stability of 4H-SiC MOS Device Properties by Combination of NO and POCl_3 Annealing2012

    • Author(s)
      H. Yano, T. Araoka, T. Hatayama, and T. Fuyuki
    • Organizer
      The 9th European Conference on Silicon Carbide and Related Materials (ECSCRM2012)
    • Place of Presentation
      Saint-Petersburg (Russia)
    • Year and Date
      2012-09-05
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] NO/POCl3複合アニール処理したSiC MOSデバイスの電子注入耐性2012

    • Author(s)
      荒岡幹, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      2012年春季 第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Related Report
      2011 Research-status Report
  • [Presentation] Development of 4H-SiC MOSFETs with Phosphorus-Doped Gate Oxide2011

    • Author(s)
      D. Okamoto, H. Yano, T. Hatayama, and T. Fuyuki
    • Organizer
      2011 International Conference on Silicon Carbide and Related Materials (ICSCRM2011)(招待講演)
    • Place of Presentation
      Cleveland (OH, USA)
    • Related Report
      2011 Research-status Report
  • [Presentation] Effect of POCl3 annealing on Reliability of Thermal Oxides Grown on 4H-SiC2011

    • Author(s)
      R. Morishita, H. Yano, D. Okamoto, T. Hatayama, and T. Fuyuki
    • Organizer
      2011 International Conference on Silicon Carbide and Related Materials (ICSCRM2011)
    • Place of Presentation
      Cleveland (OH, USA)
    • Related Report
      2011 Research-status Report
  • [Presentation] SiO2/p型4H-SiC界面特性におけるPOCl3アニールの効果2011

    • Author(s)
      高上稔充, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      電子情報通信学会 シリコン材料・デバイス研究会
    • Place of Presentation
      奈良先端科学技術大学院大学
    • Related Report
      2011 Research-status Report
  • [Presentation] SiCデバイスプロセスの高度化に向けた新規表面・界面改質技術の開発2011

    • Author(s)
      冬木隆, 矢野裕司, 畑山智亮
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第20回講演会(招待講演)
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2011 Research-status Report
  • [Presentation] POCl3アニールした4H-SiC MOS構造の高電界ストレスによる電気特性への影響2011

    • Author(s)
      森下隆至, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第20回講演会
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2011 Research-status Report
  • [Presentation] 4H-SiC MOS界面特性におけるNOとPOCl3アニールの組み合わせ効果2011

    • Author(s)
      荒岡幹, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第20回講演会
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2011 Research-status Report
  • [Presentation] SiO2/p型4H-SiC界面特性におけるPOCl3アニールの効果2011

    • Author(s)
      高上稔充, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第20回講演会
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2011 Research-status Report
  • [Presentation] Improved Inversion Channel Mobility in 4H-SiC MOSFETs on Si Face Utilizing Phosphorus-Doped Gate Oxide2011

    • Author(s)
      D. Okamoto, H. Yano, K. Hirata, T. Hatayama, and T. Fuyuki
    • Organizer
      IEEE EDS Kansai Chapter 第11回関西コロキアム電子デバイスワークショップ(招待講演)
    • Place of Presentation
      大阪大学 中之島センター
    • Related Report
      2011 Research-status Report
  • [Presentation] 定電流ストレス印加によるPOCl3アニール4H-SiC熱酸化膜の劣化特性2011

    • Author(s)
      森下隆至,矢野裕司,岡本大,畑山智亮,冬木隆
    • Organizer
      平成23年秋季 第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学 小白川キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 4H-SiC MOS界面特性におけるNOとPOCl3アニールの組み合わせ効果2011

    • Author(s)
      荒岡 幹,矢野裕司,畑山智亮,冬木隆
    • Organizer
      平成23年秋季 第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学 小白川キャンパス
    • Related Report
      2011 Research-status Report
  • [Presentation] 界面にリンおよび窒素を導入した4H-SiC MOSFETのしきい値電圧不安定性の考察

    • Author(s)
      金藤夏子, 矢野裕司, 大澤愛, 畑山智亮, 冬木隆
    • Organizer
      電子情報通信学会 シリコン材料・デバイス研究会
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 界面に窒素およびリンを導入した4H-SiC MOSFETのしきい値電圧不安定性の考察

    • Author(s)
      金藤夏子, 矢野裕司, 大澤愛, 畑山智亮, 冬木隆
    • Organizer
      応用物理学会関西支部第2回講演会
    • Place of Presentation
      奈良先端科学技術大学院大学(奈良県生駒市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] POCl3アニールによるSiC-MOSデバイスの高性能化

    • Author(s)
      矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      電子情報通信学会 シリコン材料・デバイス研究会, 応用物理学会 シリコンテクノロジー分科会(共催)
    • Place of Presentation
      機械振興会館(東京都港区)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] POCl3 Annealing as a New Method for Improving 4H-SiC MOS Device Performance

    • Author(s)
      H. Yano, T. Hatayama, and T. Fuyuki
    • Organizer
      PRiME 2012 (Pacific Rim Meeting on Electrochemical and Solid-State Science)
    • Place of Presentation
      Honolulu (HI, USA)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Improved Stability of 4H-SiC MOS Device Properties by Combination of NO and POCl3 Annealing

    • Author(s)
      H. Yano, T. Araoka, T. Hatayama, and T. Fuyuki
    • Organizer
      The 9th European Conference on Silicon Carbide and Related Materials (ECSCRM2012)
    • Place of Presentation
      Saint-Petersburg (Russia)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Effect of Interfacial Localization of Phosphorus on Electrical Properties and Reliability of 4H-SiC MOS Devices

    • Author(s)
      T. Akagi, H. Yano, T. Hatayama, and T. Fuyuki
    • Organizer
      The 9th European Conference on Silicon Carbide and Related Materials (ECSCRM2012)
    • Place of Presentation
      Saint-Petersburg (Russia)
    • Related Report
      2012 Research-status Report
  • [Presentation] Characterization of POCl3-Annealed 4H-SiC MOSFETs by Charge-Pumping Technique

    • Author(s)
      A. Osawa, H. Yano, T. Hatayama, and T. Fuyuki
    • Organizer
      The 9th European Conference on Silicon Carbide and Related Materials (ECSCRM2012)
    • Place of Presentation
      Saint-Petersburg (Russia)
    • Related Report
      2012 Research-status Report
  • [Presentation] SiO2/SiC界面へのリン導入による高品質界面の形成

    • Author(s)
      矢野裕司
    • Organizer
      ゲートスタック研究会 -材料・プロセス・評価の物理- 第18回研究会
    • Place of Presentation
      ニューウェルシティー湯河原
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] リンを界面に局在化させた4H-SiC MOSデバイスの電気特性と信頼性

    • Author(s)
      赤木剛, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第21回講演会
    • Place of Presentation
      大阪市中央公会堂
    • Related Report
      2012 Research-status Report
  • [Presentation] チャージポンピング法を用いた4H-SiC MOSFETにおける界面準位密度分布の評価

    • Author(s)
      大澤愛, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会 第21回講演会
    • Place of Presentation
      大阪市中央公会堂
    • Related Report
      2012 Research-status Report
  • [Presentation] リンの局在化が4H-SiC MOSデバイスの電気特性に与える影響

    • Author(s)
      赤木剛, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      平成24年秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] POCl3アニール処理をした4H-SiC MOSFETのチャージポンピング測定

    • Author(s)
      大澤愛, 矢野裕司, 畑山智亮, 冬木隆
    • Organizer
      平成24年秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Related Report
      2012 Research-status Report
  • [Book] ポストシリコン半導体-ナノ成膜ダイナミクスと基板・界面効果-(分担:第2編、第1章、第4節SiCデバイスプロセスにおける新規表面・界面改質技術)2013

    • Author(s)
      矢野裕司
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Final Research Report
  • [Book] ポストシリコン半導体 -ナノ成膜ダイナミクスと基板・界面効果-2013

    • Author(s)
      矢野裕司 (他 全57名)
    • Total Pages
      510
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2013 Annual Research Report
  • [Book] 「SiCパワーデバイスの開発と最新動向-普及に向けたデバイスプロセスと実装技術-」岩室憲幸監修(分担:第2章-第4節MOS界面欠陥の低減技術と高品質化)2012

    • Author(s)
      矢野裕司
    • Publisher
      S&T出版
    • Related Report
      2013 Final Research Report
  • [Book] SiCパワーデバイスの開発と最新動向 -普及に向けたデバイスプロセスと実装技術-2012

    • Author(s)
      矢野裕司 (岩室憲幸 監修)
    • Publisher
      S&T出版
    • Related Report
      2012 Research-status Report

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Published: 2011-08-05   Modified: 2019-07-29  

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