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Development of Innovative Hybrid Nanoparticles Saving the Energy of Liquid Crystal Devices

Research Project

Project/Area Number 24510158
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionTokyo University of Science, Yamaguchi

Principal Investigator

SHIRAISHI Yukihide  山口東京理科大学, 工学部, 教授 (60289303)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords超分子化学 / 包接化合物 / ナノ粒子 / ナノワイヤー / シクロデキストリン / ククルビツリル / 液晶 / 液晶ディスプレイ / 架橋シクロデキストリン / 金 / ジルコニア / 複合ナノ粒子 / 高速応答液晶 / 液晶表示素子 / 応答時間 / ポリ(シクロデキストリン) / チタン酸バリウム / 垂直配向液晶 / 国際情報交換
Outline of Final Research Achievements

The modification of the physical properties of liquid crystals by doping nanoparticles have received much attention from the view point of the enhancement of the performance of LCDs. Reflecting these trends several research groups reported on heterogeneous liquid crystal suspensions using; fullerene, noble metal nanoparticles, and semiconductor nanoparticles.
Poly(γ-cyclodextrin) (P γCyD)-protected ZrO2 nanoparticles were prepared by using a microwave reactor equipped with ultrasonic nozzle mixing a tetraethylene glycol solution of zirconium ethoxide in the presence of poly(γ -cyclodextrin). The response time of this twisted nematic liquid crystal devices (TN-LCDs)in the presence of P γ CyD-ZrO2 nanoparticles was faster than that in the absence. The threshold voltage of TN-LCDs by doping P γ CyD-ZrO2 nanoparticles decreased. The decrease of threshold voltage can reduce power consumption, which may meet the demands of future power-saving LCDs.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (48 results)

All 2015 2014 2013 2012 Other

All Journal Article (13 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 4 results) Presentation (24 results) (of which Invited: 1 results) Book (2 results) Remarks (7 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Effect of Particle Size on Electro-Optic Properties of Liquid Crystal Devices Doped with γ-Cyclodextrin Stabilized Barium Titanate Nanoparticles2015

    • Author(s)
      Y. Shiraishi, H. Sawai R. Tsujihata, S. Kobayashi and N. Toshima
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 611 Issue: 1 Pages: 1-9

    • DOI

      10.1080/15421406.2015.1028000

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electro-Optic Properties of Liquid Crystal Devices Doped with Cucurbituril-protected Zirconia Nanowires2014

    • Author(s)
      Y. Shiraishi, T. Uehara H. Sawai, H. Kakiuchi, S. Kobayashi and N. Toshima
    • Journal Title

      Colloids and Surf. A

      Volume: 460 Pages: 90-94

    • DOI

      10.1016/j.colsurfa.2014.03.060

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ナノ粒子を用いた省エネ高性能液晶2014

    • Author(s)
      白石幸英
    • Journal Title

      ケミカルエンジニアリング

      Volume: 59 Pages: 37-42

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Preparation and Application of Poly(beta-cyclodextrin)-Protected Zirconia Nanoparticles by Ultrasonic/Microwave Method2014

    • Author(s)
      白石幸英, 田中誠, 澤井寛哉, 大木妙子, 戸嶋直樹
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 71 Issue: 10 Pages: 467-470

    • DOI

      10.1295/koron.71.467

    • NAID

      130004700456

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electro-Optical Properties of LCD Doped with Nanoparticles and with Optical Compensators: Ways for Fast Response2014

    • Author(s)
      S. Kobayashi, M. Akimoto, K. Takatoh, Y. Shiraishi, H. Sawai, N. Toshima, K. Takeuchi, K. Kotani, M. Kaneoya, K. Takeishi, H. Takatsu
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 594 Issue: 1 Pages: 21-30

    • DOI

      10.1080/15421406.2014.917462

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zirconia Nanocolloids Having A Nanospace of Poly(cyclodextrin): Preparation and Application to Liquid Crystal Devices2014

    • Author(s)
      H. Sawai, Y. Shiraishi, T. Miyama, S. Kobayashi, and N. Toshima
    • Journal Title

      J. Nanoscience Nanotechnology

      Volume: 14 Issue: 3 Pages: 2217-2224

    • DOI

      10.1166/jnn.2014.8486

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Optical properties of NTN-FSC-LCD and ECB cells with the doping of nanoparticles2013

    • Author(s)
      S. Kobayashi, Y. Shiraishi, H. Sawai, N. Toshima, H. Takatsu and K. Kotani
    • Journal Title

      Proceedings of SPIE

      Volume: 8642

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Construction and electro-optic properties of liquid-crystal display doped by rhodium nanoparticles2012

    • Author(s)
      Y. Shiraishi, H. Nakamura, N. Okamura, N. Nishida, S. Kobayashi and N. Toshima
    • Journal Title

      J. Nanoscience Nanotechnology

      Volume: 12 Pages: 396-402

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Green digital signage using nanoparticle embedded narrow-gap field sequential TN-LCDs2012

    • Author(s)
      S. Kobayashi, Y. Shiraishi, H. Sawai, N. Toshima, M. Okita, K. Takeuchi, H. Takatsu,
    • Journal Title

      Proceedings of SPIE

      Volume: 8279

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] NTN-FSC-LCD を用いたグリーンディジタルサイネージ2012

    • Author(s)
      小林駿介, 白石幸英, 澤井寛哉, 戸嶋直樹, 見山友裕, 高津晴義, 竹内清文
    • Journal Title

      月刊ディスプレイ

      Volume: 18 Pages: 58-60

    • Related Report
      2012 Research-status Report
  • [Journal Article] Fast Electro-Optic Switching of Twisted Nematic LCD Doped with Cyclodextrin Capped Silica Nanoparticles2012

    • Author(s)
      Y. Shiraishi, K. Sugihara, N. Okamura, H. Sawai, S. Kobayashi and N. Toshima
    • Journal Title

      Macromolecular Symposia

      Volume: 317-318 Pages: 28-33

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation and Electro-optic Properties of Liquid Crystal Devices Doped with Cucurbituril-Protected Gold Nanowires2012

    • Author(s)
      H. Sawai, T. Matsuura, H. Kakiuchi, T. Ohgi, Y. Shiraishi, and N. Toshima
    • Journal Title

      Chem. Lett

      Volume: 41 Pages: 1160-1162

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improvement of the Performance of Liquid Crystal Displays by Doping with Nanoparticles2012

    • Author(s)
      Y. Shiraishi, S. Kobayashi and N. Toshima
    • Journal Title

      Israel Journal of Chemistry

      Volume: 52 Pages: 908-916

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] シクロデキストリンポリマーで保護した貴金属/ジルコニア複合ナノ粒子分散系液晶の電気光学特性2015

    • Author(s)
      白石幸英,神崎天心,浅野比,戸嶋直樹
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fast Response LCDs by Doping Nanoparticles and Optical Compensation2014

    • Author(s)
      S. Kobayashi, Y. Shiraishi and H. Takatsu
    • Organizer
      The 21st International Display Workshops
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2014-12-03 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] フラーレン/シクロデキストリン保護貴金属ナノ粒子複合体の創製と液晶表示素子の電気光学特性2014

    • Author(s)
      白石幸英, 原田祐加里, 澤井寬哉, 小林駿介, 戸嶋直樹
    • Organizer
      第31 回シクロデキストリンシンポジウム
    • Place of Presentation
      島根市
    • Year and Date
      2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis and Function of Fullerene/Calix[6]arene-Protected Rhodium Hybrid Nanoparticles2014

    • Author(s)
      H. Sawai, T. Sasaki H. Kakiuchi, and Y. Shiraishi
    • Organizer
      5th European Chemistry Congresses (EuCheM)
    • Place of Presentation
      Istanbul, Turkey
    • Year and Date
      2014-09-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] Improvement of Performance of Liquid Crystal Displays Doped with Cyclodextrin Stabilized Barium Titanate Nanoparticles2014

    • Author(s)
      Y. Shiraishi, H. Sawai, R. Tsujihata, S. Kobayashi, and N. Toshima, Improvement of Performance of Liquid Crystal Displays Doped with Cyclodextrin Stabilized Barium Titanate Nanoparticles
    • Organizer
      25th International Liquid Crystal Conference (ILCC 2014)
    • Place of Presentation
      Dublin, Ireland
    • Year and Date
      2014-06-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポリ(γ-シクロデキストリン)保護SrTiO3ナノ粒子の創製と垂直配向型液晶への応用2014

    • Author(s)
      古方慶太, 澤井寛哉, 大木妙子, 白石幸英
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      目黒区
    • Year and Date
      2014-05-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] シクロデキストリン誘導体を用いた液晶バイオセンサーの開発2014

    • Author(s)
      北村直樹, 澤井寛哉, 岡村るり子, 白石幸英
    • Organizer
      第12回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      目黒区
    • Year and Date
      2014-05-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] ククルビツリル保護銀ナノワイヤーの合成と液晶表示への応用2014

    • Author(s)
      白石幸英,澤井寛哉,江口敏正,小林駿介, 戸嶋直樹
    • Organizer
      日本写真学会年次大会
    • Place of Presentation
      千葉市
    • Year and Date
      2014-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 包接化合物保護ナノ粒子を用いた省エネ高性能液晶表示素子の開発2014

    • Author(s)
      白石幸英
    • Organizer
      日本写真学会年次大会
    • Place of Presentation
      千葉市
    • Year and Date
      2014-05-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 架橋シクロデキストリン保護金/ジルコニアナノ粒子を分散した液晶表示素子の電気光学特性2014

    • Author(s)
      渡邊千代美, 澤井寬哉, 岡村るり子, 大木妙子, 白石幸英
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Electro-Optic Properties of Liquid Crystal Devices Doped with Cucurbituril-protected Zirconia Nanowires2013

    • Author(s)
      Y. Shiraishi, T. Uehara H. Sawai, H. Kakiuchi, and N. Toshima
    • Organizer
      27th Conference of European Colloid and Interface Society (ECIS 2013)
    • Place of Presentation
      Sofia, Bulgaria
    • Related Report
      2013 Research-status Report
  • [Presentation] Fast Switching of Twisted Nematic Liquid Crystal Displays Doped with Poly (cyclodextrin) Protected Zirconia Nanoparticles2013

    • Author(s)
      Y. Shiraishi, H. Sawai, S. Kobayashi, and N. Toshima
    • Organizer
      7th Asian Cyclodextrin Conference (7th ACC)
    • Place of Presentation
      Bangkok, Thai
    • Related Report
      2013 Research-status Report
  • [Presentation] クラウンエーテル保護ロジウムナノ粒子を添加した液晶表示素子の電気光学特性2013

    • Author(s)
      桑野雄太, 澤井寛哉, 大木妙子, 垣内秀志, 白石幸英
    • Organizer
      第10回ホストゲスト化学シンポジウム
    • Place of Presentation
      和歌山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 包接化合物保護ナノ粒子を添加した液晶ディスプレイの電気光学特性2013

    • Author(s)
      白石幸英,澤井寛哉,水野雄貴,小林駿介, 戸嶋直樹
    • Organizer
      2013年度 日本写真学会年次大会
    • Place of Presentation
      千葉大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリ(γ-シクロデキストリン)保護ナノ粒子の調製と垂直配向型液晶への応用2013

    • Author(s)
      白石幸英, 水野雄貴, 澤井寬哉, 大木妙子, 小林駿介, 戸嶋直樹
    • Organizer
      第30 回シクロデキストリンシンポジウム
    • Place of Presentation
      くまもと県民交流館
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノ粒子添加液晶ディスプレイの応答時間と動作電圧の低減およびFSC-LCDの試作2013

    • Author(s)
      小林駿介, 白石幸英, 戸嶋直樹
    • Organizer
      2013年電子情報通信学会ソサイエティ大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] フィールドシークェンシャルカラー液晶表示素子におけるポリ(γ-シクロデキストリン)保護金ナノ粒子の粒径効果2013

    • Author(s)
      澤井寬哉, 河野杏華, 垣内秀志, 大木妙子, 白石幸英, 戸嶋直樹
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation and electro-optic properties of liquid crystal devices doped with cucurbituril-protected gold nanowires

    • Author(s)
      Y. Shiraishi, T. Matsuura, H. Sawai, H. Kakiuchi, T. Ohgi, and N. Toshima
    • Organizer
      International Association of Colloid and Interface Scientists Conference
    • Place of Presentation
      仙台国際センター
    • Related Report
      2012 Research-status Report
  • [Presentation] Electro-Optic Properties of LCD Fabricated by Doped with Poly(Cyclodextrin) Stabilized Zirconia Nanoparticles

    • Author(s)
      Y. Shiraishi, H. Sawai, S. Kobayashi, and N. Toshima
    • Organizer
      26th International Carbohydrate Symposium (ICS2012)
    • Place of Presentation
      Madrid, Spain
    • Related Report
      2012 Research-status Report
  • [Presentation] 超音波/マイクロ波法によるポリ(β-シクロデキストリン)保護ジルコニアナノ粒子の創製と応用

    • Author(s)
      白石幸英, 田中誠, 澤井寛哉, 戸嶋直樹
    • Organizer
      第61 回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Research-status Report
  • [Presentation] ククルビツリルを保護剤とした銀ナノワイヤーの合成と液晶表示素子への応用

    • Author(s)
      白石幸英, 江口敏正, 垣内秀志, 澤井寛哉, 戸嶋直樹
    • Organizer
      第61 回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Related Report
      2012 Research-status Report
  • [Presentation] シクロデキストリン誘導体保護ナノ粒子を添加した液晶表示素子の電気光学特性

    • Author(s)
      天野祥一, 澤井寬哉, 大木妙子, 垣内秀志, 白石幸英
    • Organizer
      第29 回シクロデキストリンシンポジウム
    • Place of Presentation
      星薬科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] ポリシクロデキストリン保護ジルコニアナノ粒子の調製と実用化液晶への応用

    • Author(s)
      澤井寬哉, 田中誠, 白石幸英, 小林駿介, 戸嶋直樹
    • Organizer
      2012年日本化学会西日本大会
    • Place of Presentation
      佐賀大学
    • Related Report
      2012 Research-status Report
  • [Presentation] フラーレン/カリックス[n]アレーン保護ロジウムナノ粒子複合体添加液晶の構築とその電気光学特性

    • Author(s)
      澤井寬哉, 佐々木将, 垣内秀志, 大木妙子, 白石幸英
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Book] 金属ナノ・マイクロ粒子の最新技術と応用2014

    • Author(s)
      白石幸英
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Research-status Report
  • [Book] Electrical Phenomena at Interfaces and Biointerfaces: Fundamentals and Applications in Nano-, Bio-, and Environmental Sciences2012

    • Author(s)
      Y. Shiraishi, N. Nishida, and N. Toshima
    • Publisher
      WILEY
    • Related Report
      2012 Research-status Report
  • [Remarks] Yukihide Shiraishi -Google Scholar Citations

    • URL

      https://scholar.google.com/citations?hl=en&user=olz8a2IAAAAJ&view_op=list_works&pagesize=100

    • Related Report
      2014 Annual Research Report
  • [Remarks] Yukihide Shiraishi Lab.

    • URL

      http://www.rs.tus.ac.jp/shiraishi/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 東京理科大学 研究者情報データーベース

    • URL

      https://www.tus.ac.jp/ridai/doc/ji/RIJIA01.php

    • Related Report
      2014 Annual Research Report
  • [Remarks] 東京理科大学 研究者情報データーベース

    • URL

      http://www.tus.ac.jp/ridai/

    • Related Report
      2013 Research-status Report
  • [Remarks] Yukihide Shiraishi Lab.

    • URL

      http://www.rs.tus.ac.jp/shiraishi/

    • Related Report
      2013 Research-status Report
  • [Remarks] 東京理科大学 研究者情報データーベース

    • URL

      http://www.tus.ac.jp/ridai/

    • Related Report
      2012 Research-status Report
  • [Remarks] Yukihide Shiraishi Lab.

    • URL

      http://www.ed.yama.tus.ac.jp/~siraisi/

    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] 液晶表示素子の出力光の均一化方法及び液晶表示素子2014

    • Inventor(s)
      小林駿介, 白石幸英, 穐本光弘, 戸嶋直樹, など
    • Industrial Property Rights Holder
      DIC(株), 学校法人東京理科大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-223427
    • Filing Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 液晶組成物2013

    • Inventor(s)
      戸嶋直樹, 白石幸英, 小林駿介, 小谷邦彦
    • Industrial Property Rights Holder
      学校法人東京理科大学,DIC(株)
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-07-18
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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