Development of nanospace materials based on layered metal multifunctional phosphonate structures

• Project/Area Number: 24550230
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Tokyo University of Agriculture and Technology
• Principal Investigator: KAZUYUKI Maeda 東京農工大学, 工学(系)研究科(研究院), 准教授 (60343159)
• Co-Investigator(Renkei-kenkyūsha): KONDO Atsushi 東京農工大学, 大学院工学研究院, 助教 (60533619)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: 多孔体 / 無機有機ハイブリッド / 金属ホスホネート / ナノシート / MOF / ハイブリッド多孔体 / 層状・層間化合物

Outline of Final Research Achievements

The aim of the research was to develop nanospace materials based on layer structures derived from layered metal multifunctional phosphonates by using strategies established in inorganic layered materials. Monolayer nanosheets obtained via intercalation of surfactants in a layered zinc phosphonate and the subsequent exfoliation were successfully immobilized on substrates. It was also confirmed that the local structure of the original layered compound was retained throughout the nanosheet formation. Microporous pillared layered materials with specific layer structures and pillars such as organic cations and pillaring ligands were prepared, the crystal structures and adsorption properties of which were revealed.

Research Products

• [Journal Article] Ordered Microporous Layered Lanthanide 1,3,5-Benzenetriphosphonates Pillared with Cationic Organic Molecules (2015)
  • Author(s): Takahiro Araki, Atsushi Kondo, Kazuyuki Maeda
  • Journal Title: Chemistry, A European Journal Volume: 21 Issue: 16 Pages: 6257-6264
  • DOI: 10.1002/chem.201406518
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Formation of zeolite-like zinc 1,3,5-benzenetriphosphonate open-frameworks by topotactic pillaring of anionic layers (2013)
  • Author(s): Kazuyuki Maeda, Ryohei Takamatsu, Miki Mochizuki, Kanako Kawawa and Atsushi Kondo
  • Journal Title: Dalton Trans. Volume: 42 Issue: 29 Pages: 10424-10432
  • DOI: 10.1039/c3dt33037k
  • Peer Reviewed
• [Journal Article] 無機－有機ハイブリッドナノシートの創製 (2013)
  • Author(s): 近藤篤、前田和之
  • Journal Title: 表面 Volume: 51 Pages: 307-317
  • NAID: 40019981171
• [Journal Article] The First Lanthanide Organophosphonate Nanosheet by Exfoliation of Layered Compound (2013)
  • Author(s): Takahiro Araki, Atsushi Kondo, Kazuyuki Maeda
  • Journal Title: Chem. Commun. Volume: 49 Issue: 6 Pages: 552-554
  • DOI: 10.1039/c2cc36703c
  • Peer Reviewed
• [Presentation] Anionic Hybrid Nanosheets Obtained from Delamination of Layered Metal Organophosphonates (2014)
  • Author(s): Kazuyuki Maeda, Dam Thien Ngan, Atsushi Kondo
  • Organizer: MOF2014
  • Place of Presentation: 神戸市・神戸国際会議場
  • Year and Date: 2014-09-28 – 2014-10-01
• [Presentation] Influence of Amine Additives in Preparation of Zinc Carboxymethylphosphonate Open-frameworks (2014)
  • Author(s): Kazuyuki Maeda, Yuichi Kurata, Tsutomu Yamazaki
  • Organizer: FEZA2014
  • Place of Presentation: 独国・ライプツィヒ・ライプツィヒ大学
  • Year and Date: 2014-09-08 – 2014-09-11
• [Presentation] ピレンテトラホスホン酸金属塩の合成と蛍光挙動 (2013)
  • Author(s): 黒田友也、近藤篤、前田和之
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津（滋賀）、立命館大学 びわこ・くさつキャンパス
• [Presentation] 亜鉛 1,3,5-ベンゼントリホスホネートナノシートの固定化 (2013)
  • Author(s): Dam Thien Ngan、高松良平、近藤篤、前田和之
  • Organizer: 日本セラミックス協会第51回セラミックス基礎科学討論会
  • Place of Presentation: 仙台、仙台国際センター
• [Presentation] 結晶性アルミニウムフルオロオルガノホスホネートの合成と評価 (2013)
  • Author(s): 川合哲文、近藤篤、前田和之
  • Organizer: 日本セラミックス協会 2013年 年会
  • Place of Presentation: 東京、東京工業大学 大岡山キャンパス
• [Presentation] Preparation of rare-earth 1,3,5-benzenetriphosphonates composed of hybrid nanosheet layers (2012)
  • Author(s): Takahiro Araki, Atsushi Kondo, Kazuyuki Maeda
  • Organizer: ZMPC2012
  • Place of Presentation: 広島、アステールプラザ
• [Presentation] Synthesis of a novel microporous copper 1,3,5-benzenetriphosphonate and adsorption of CO2 and ethanol (2012)
  • Author(s): Tokuya Satomi, Atsushi Kondo, Kanami Azuma, Kazuyuki Maeda
  • Organizer: ZMPC2012
  • Place of Presentation: 広島、アステールプラザ
• [Presentation] Formation of zeolite-like open-framework by spontaneous pillaring of zinc 1,3,5-benzenetriphosphonate layers on cation exchange with alkali metal halides (2012)
  • Author(s): Kazuyuki Maeda, Ryohei Takamatsu, Miki Mochizuki, Kanako Kawawa, Atsushi Kondo
  • Organizer: ZMPC2012
  • Place of Presentation: 広島、アステールプラザ
• [Presentation] Nドナー層間架橋配位子を含む希土類1,3,5-ベンゼントリホスホネートの合成と構造 (2012)
  • Author(s): 荒木孝啓、近藤篤、前田和之
  • Organizer: ゼオライト学会第28回ゼオライト研究発表会
  • Place of Presentation: 東京、タワーホール船堀
• [Presentation] Layered Lanthanide 1,3,5-benzenetriphosphonates Pillared with Organic Cationic Species
  • Author(s): Takahiro Araki, Atsushi Kondo, Kazuyuki Maeda
  • Organizer: 17th International Zeolite Conference
  • Place of Presentation: モスクワ（ロシア）
• [Presentation] Immobilization of zinc 1, 3, 5-benzenetriphosphonate nanosheet
  • Author(s): Dam Thien Ngan, Ryohei Takamatsu, Atsushi Kondo, Kazuyuki Maeda
  • Organizer: International Symposium on Materials Chemistry of Intercalation Compounds (MCIC2013)
  • Place of Presentation: 早稲田大学（東京都新宿区）
• [Presentation] アルミニウムフルオロオルガノホスホネート合成における 第四級アンモニウム塩添加の影響
  • Author(s): 川合哲文、近藤篤、前田和之
  • Organizer: 第52回セラミックス基礎科学討論会
  • Place of Presentation: 愛知県産業労働センター（愛知県名古屋市）
• [Presentation] 層状ランタニド1,3,5-ベンゼントリホスホネートへのインターカレーション及びその層剥離
  • Author(s): 菅原徳朗、荒木孝啓、近藤篤、前田和之
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学（愛知県名古屋市）
• [Remarks] Layered MOF and Conversion to Nanomaterials
  • URL: http://www.tuat.ac.jp/~k-maeda/ZBP_Nanomaterial_Conversion.pdf
• [Remarks] Microporous Pillared Layered Lanthanide Compounds
  • URL: http://www.tuat.ac.jp/~k-maeda/Araki_ChemEurJ.pdf
• [Remarks] 東京農工大学大学院応用化学専攻物質応用化学専修前田研究室
  • URL: http://www.tuat.ac.jp/̃k-maeda/index.html
• [Remarks] 東京農工大学前田研究室
  • URL: http://www.tuat.ac.jp/~k-maeda/index.html