Selective oxidation of assembled perovskite-type oxide catalyst

• Project/Area Number: 24560948
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Ehime University
• Principal Investigator: YAHIRO Hidenori 愛媛大学, 理工学研究科, 教授 (90200568)
• Co-Investigator(Kenkyū-buntansha): YAMAGUCHI Syuhei 愛媛大学, 大学院理工学研究科, 准教授 (50397494)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000); Fiscal Year 2012: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: ペロブスカイト型酸化物 / シアノ錯体 / シアノシリル化反応 / ペロブスカイト / 高表面積 / ペロブスカイト酸化物 / 配位高分子前駆体 / 形態制御 / 熱分解 / CO酸化反応

Outline of Final Research Achievements

Perovskite-type oxide was prepared by the thermal decomposition of cyano complex as a precursor. It was found that the formation of perovskite-type oxide was affected by the oxygen concentration during calcination process of precursor. In addition, the perovskite-type oxide was formed by the heat derived from oxidation of ligands. Catalytic activity for cyanosilylation increased with increasing calcination temperature of perovskite-type oxide catalyst. This result suggests that catalytic activity for cyanosilylation was influenced by increasing with crystallite size.

Research Products

• [Journal Article] Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions (2015)
  • Author(s): Syuhei Yamaguchi, Tomohiro Fukura, Keiko Takiguchi, Chiharau Fujita, Maiko Nishibori, Yasutake Teraoka, Hidenori Yahiro
  • Journal Title: Catalysis Today Volume: 242 Pages: 261-267
  • DOI: 10.1016/j.cattod.2014.07.038
  • Peer Reviewed
• [Journal Article] Cyanosilylation of benzaldehyde with TMSCN over perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano complex precursors (2015)
  • Author(s): Syuhei Yamaguchi, Takahisa Okura, Hiroki Wada, Hiroyuki Yamaura, Hidenori Yahiro
  • Journal Title: Research on Chemical Intermediates Volume: 未定巻 Issue: 12 Pages: 9551-9560
  • DOI: 10.1007/s11164-015-1980-y
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Encapsulation of binuclear manganese (II) complexes with amino acid based ligands in zeolite Y and their catalytic properties for epoxidation of cyclohexene (2013)
  • Author(s): M. Ghorbanloo, S. Rahmani, H. Yahiro
  • Journal Title: Transition Metal Chemistry Volume: 38 Issue: 7 Pages: 725-732
  • DOI: 10.1007/s11243-013-9742-4
  • Peer Reviewed
• [Journal Article] Preparation of perovskite-type oxides from heterometal coordination polymer precursors linked by oxalate ligands, {Sm[M(ox)₃]&middot;nH₂O}<i>_x</i> (M = Fe or Co) (2013)
  • Author(s): Syuhei Yamaguchi, Naoya Kimoto, Hirotoshi Sasagawa, Keiko Takiguchi, Takahisa Okuwa, Makiko Asamoto, Hidenori Yahiro
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 121 Issue: 1409 Pages: 84-88
  • DOI: 10.2109/jcersj2.121.84
  • NAID: 130004950787
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed
• [Journal Article] Synthesis of perovskite-type oxide catalysts, Ln(Fe,Co)O_3 (Ln=La, Pr, Sm, Gd, Dy, Ho, Er, and Yb), from the thermal decomposition of the corresponding cyano complexes (2012)
  • Author(s): M.Asamoto, Y.Iwasaki, S.Yamaguchi, H.Yahiro
  • Journal Title: Catalysis Today Volume: 185 Issue: 1 Pages: 230-235
  • DOI: 10.1016/j.cattod.2011.09.023
  • Peer Reviewed
• [Presentation] 様々な焼成雰囲気下で複核シアノ錯体から調製したペロブスカイト型酸化物触媒を用いたシアノシリル化反応 (2015)
  • Author(s): 和田啓暉・Daniel Sanchez Rodriguez・山口修平・八尋秀典
  • Organizer: 第115回触媒討論会
  • Place of Presentation: 成蹊大学（東京都武蔵野市）
  • Year and Date: 2015-03-23
• [Presentation] シアノ錯体から調製したペロブスカイト型酸化物触媒を用いたシアノシリル化反応 (2014)
  • Author(s): 山口修平・大桑昇久・八尋秀典
  • Organizer: 第114回触媒討論会
  • Place of Presentation: 広島大学 (広島県東広島市)
  • Year and Date: 2014-09-26
• [Presentation] 複核シアノ錯体の配位子酸化による発熱を利用したペロブスカイト型酸化物触媒の合成と触媒活性 (2014)
  • Author(s): 和田啓暉・大桑昇久・山口修平・八尋秀典
  • Organizer: 日本セラミックス協会第２７回秋季シンポジウム
  • Place of Presentation: 鹿児島大学（鹿児島県鹿児島市）
  • Year and Date: 2014-09-09
• [Presentation] シアノ金属錯体前駆体から調製したペロブスカイト型酸化物触媒を用いたシアノシリル化反応 (2014)
  • Author(s): 山口修平・大桑昇久・和田啓暉・八尋秀典
  • Organizer: 日本セラミックス協会第２７回秋季シンポジウム
  • Place of Presentation: 鹿児島大学（鹿児島県鹿児島市）
  • Year and Date: 2014-09-09
• [Presentation] ペロブスカイト型酸化物触媒の調製とその利用 (2014)
  • Author(s): 八尋秀典
  • Organizer: 第8回触媒道場
  • Place of Presentation: 北九州ハイツ（福岡県北九州市）
  • Year and Date: 2014-09-02
  • Invited
• [Presentation] 複核シアノ錯体の配位子の酸化熱を利用したペロブスカイト型酸化物合成 (2014)
  • Author(s): 和田啓暉・山口修平・八尋秀典
  • Organizer: 第8回触媒道場
  • Place of Presentation: 北九州ハイツ（福岡県北九州市）
  • Year and Date: 2014-09-02
• [Presentation] Cyanosilylation of Benzaldehyde over Perovskite‐Type Oxide Catalysts Prepared by Thermal Decomposition of Heteronuclear Cyano Complex Precursors (2014)
  • Author(s): Syuhei Yamaguchi, Takahisa Okuwa, Hidenori Yahiro
  • Organizer: TOCAT5
  • Place of Presentation: 京都テレサ（京都府京都市）
  • Year and Date: 2014-06-04
• [Presentation] Preparation of Mixed Metal Oxide Nanoparticles and Their Catalytic Properties in Liquid Phase (2014)
  • Author(s): Hidenori Yahiro, Syuhei Yamaguchi, Hiroyuki Yamaura
  • Organizer: EMN Conference
  • Place of Presentation: Las Vegas (USA)
  • Invited
• [Presentation] 複核シアノ錯体の配位子の酸化熱を利用したペロブスカイト型酸化物合成 (2014)
  • Author(s): 和田啓暉, 大桑昇久, 山口修平, 八尋秀典
  • Organizer: 第113回触媒討論会
  • Place of Presentation: ロジワールホテル豊橋（豊橋）
• [Presentation] Preparation of Perovskite-Type Oxide Catalysts from Heterometal Coordination (2013)
  • Author(s): Syuhei Yamaguchi, Naoya Kimoto, Hirotoshi Sasagawa, Makiko Asamoto, Hidenori Yahiro
  • Organizer: The 14th Japan-Korea Symposium on Catalysis
  • Place of Presentation: Wink Aichi (Nagoya)
• [Presentation] ペロブスカイト型 酸化物触媒を用いたシアノシリル化反応 (2013)
  • Author(s): 大桑昇久, 山口修平, 八尋秀典
  • Organizer: 第112回触媒討論会
  • Place of Presentation: 秋田大学（秋田）
• [Presentation] New preparation method of perovskite-type oxide from cyano metal complex and their catalytic activity for gas- and liquid-phase reactions (2013)
  • Author(s): Hidenori Yahiro, Syuhei Yamaguchi
  • Organizer: Composites At Lake Louise 2013
  • Place of Presentation: Lake Louise(Canada)
  • Invited
• [Presentation] Catalytic reaction for cyanosilylation over perovskite-type oxide catalysts (2013)
  • Author(s): akahisa Okuwa, Syuhei Yamaguchi, Hidenori Yahiro
  • Organizer: the 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials
  • Place of Presentation: 愛媛大学（松山）
• [Presentation] Preparation of perovskite-type oxide catalysts, LnFe(X)Co(1-X)O(3) (Ln=La, Pr, Sm, Gd, Dy, Ho, Er, and Yb), by thermal decomposition of cyano complexes (2012)
  • Author(s): Takahisa Okuwa, Yuji Iwasaki, Makiko Asamoto, Syuhei Yamaguchi, and Hidenori Yahiro
  • Organizer: International Symposium on Rare Earths in 2012
  • Place of Presentation: 沖縄ハーバービューホテルクラウンプラザ（沖縄）
• [Presentation] オキサラトで架橋した配位高分子錯体を前駆体としたペロブスカイト型酸化物の調製 (2012)
  • Author(s): 山口修平・佐々川裕敏・記本尚哉・浅本麻紀子・八尋秀典
  • Organizer: 日本セラミックス協会第25回秋季シンポジウム
  • Place of Presentation: 名古屋大学東山キャンパス（名古屋）
• [Presentation] Preparation of Perovskite-type Oxide Catalysts by Thermal Decomposition of Cyano Complexes (2012)
  • Author(s): Hidenori Yahiro
  • Organizer: 8th International Conference on f-Elements
  • Place of Presentation: Udine, ITALY
  • Invited
• [Presentation] Catalytic Activity for CO Oxidation over Perovskite-type Oxide Prepared by Thermal Decomposition of Cyano Complexes
  • Author(s): Takahisa Okuwa, Yuji Iwasaki, Makiko Asamoto, Syuhei Yamaguchi, Hidenori Yahiro
  • Organizer: 平成25年度触媒学会西日本支部第４回触媒科学研究発表会
  • Place of Presentation: 徳島大学（徳島）
• [Book] 触媒の設計・反応制御 事例集 (2013)
  • Author(s): 山口修平，八尋秀典
  • Publisher: 株）技術情報教会
• [Remarks] 愛媛大学教育研究者要覧
  • URL: http://kenqweb.office.ehime-u.ac.jp/yoran/
• [Remarks] 研究室ホームページ
  • URL: http://www.ach.ehime-u.ac.jp/solid/