• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

XAFS investigation for inhomogeneous and irreversible reaction mechanism in hydroxide/sulfide coprecipitation treatment

Research Project

Project/Area Number 24561006
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Earth system and resources enginnering
Research InstitutionWaseda University

Principal Investigator

TOKORO Chiharu  早稲田大学, 理工学術院, 准教授 (90386615)

Co-Investigator(Kenkyū-buntansha) NUMAKO Chiya  千葉大学, 理学研究科, 准教授 (80284280)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords廃水処理 / 固液界面 / 固体分析 / 定量モデル / 表面錯体 / 表面沈殿 / 定量モデル化 / 水酸化物共沈 / ホウ素 / シリカ / 亜鉛 / 水酸化物共沈法 / ヒ素 / フッ素 / XAFS
Outline of Final Research Achievements

Immobilization mechanism of As(V), F, Si(IV), Zn(II) to ferrihydrite and aluminum hydroxide in co-precipitation process was revealed using several solid analysis and basic chemical engineering method, toward construction of efficient treatment process for acid mine drainage. Based on the knowledge obtained from these investigation, a quantitative model was constructed for immobilization of several toxic elements to in wastewater treatment, using chemical equilibrium calculation coupled by surface complexation model between each toxic element and ferrihydrite/aluminum hydroxide and reaction rate model of precipitation. Obtained model could represent experimental neutralization results using real acid mine drainage.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (34 results)

All 2015 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (28 results) (of which Invited: 6 results)

  • [Journal Article] 水酸化マグネシウム共沈法における廃水中のホウ素除去機構の考察2014

    • Author(s)
      井澤 彩・前田 素生・所 千晴・笹木 圭子
    • Journal Title

      Journal of MMIJ

      Volume: 130 Pages: 155-161

    • NAID

      130005070042

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 統計解析と地球化学コードを用いた酸性坑廃水処理の将来予測に関する研究2014

    • Author(s)
      大塚 啓司, 村上進亮, 山冨二郎, 小出 瑠, 所 千晴
    • Journal Title

      Journal of MMIJ

      Volume: 130 Pages: 488-493

    • NAID

      130005102199

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水酸化物共沈法を用いた廃水処理における固液界面での有害元素の不動化機構2014

    • Author(s)
      所千晴
    • Journal Title

      粉体工学会誌

      Volume: 51 Pages: 765-771

    • NAID

      130004856066

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Silicate Removal in Aluminum Hydroxide Co-Precipitation Process2014

    • Author(s)
      C.Tokoro, S.Suzuki, D.Haraguchi, S.Izawa
    • Journal Title

      Materials

      Volume: 7 Issue: 2 Pages: 1084-1096

    • DOI

      10.3390/ma7021084

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 表面沈殿モデルを用いた希薄As(V)廃水の水酸化第二鉄共沈処理に対する定量モデル化2013

    • Author(s)
      原口 大輔・所 千晴・大和田 秀二・井澤 彩
    • Journal Title

      Journal of MMIJ

      Volume: 129 Pages: 158-164

    • NAID

      10031166732

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Sorption Mechanisms of Arsenate in Aqueous Solution during Coprecipitation with Aluminum Hydroxide2013

    • Author(s)
      Daisuke Haraguchi, Chiharu Tokoro, Yuji Oda and Shuji Owada
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: 46 Pages: 173-180

    • NAID

      10031159961

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 反応速度論と表面錯体モデルを用いた希薄Si(IV)廃水の水酸化アルミニウム共沈処理に対する定量モデル化2015

    • Author(s)
      鈴木 慎哉・榊原 泰佑・所 千晴
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水酸化アルミニウムへの表面錯体形成を考慮した酸性抗廃水処理の定量モデル化2015

    • Author(s)
      榊原 泰佑・鈴木 慎哉・所 千晴・迫田 昌敏
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-27 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe(III)担持樹脂によるAs(V)除去機構の把握およびpH特性2014

    • Author(s)
      二見 文也・所 千晴
    • Organizer
      粉体工学会秋季研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-25 – 2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] A quantitative modeling for coprecipitation of arsenic with ferrihyfrite in treatment of acid mine drainage2014

    • Author(s)
      C.Tokoro, D.Haraguchi, S.Izawa, S.Suzuki, S.Owada
    • Organizer
      IMPC2014:International Mineral Processing Congress
    • Place of Presentation
      サンチャゴ、チリ
    • Year and Date
      2014-10-20 – 2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Quantitative Modeling for Neutralization / Co-precipitation Treatment of Acid Mine Drainage2014

    • Author(s)
      C.Tokoro, S.Suzuki, T.Sakakibara, S.Owada
    • Organizer
      COM2014-The Conference of Metallurgists
    • Place of Presentation
      バンクーバー、カナダ
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fe(III)を担持させたイオン交換樹脂によるAs(V)除去機構の把握およびpH特性2014

    • Author(s)
      二見 文也・所 千晴
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水酸化アルミニウムによる亜鉛含有廃水の共沈処理に対する定量モデル化2014

    • Author(s)
      榊原 泰佑・所 千晴・鈴木 慎哉
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      福岡
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] RO膜閉塞物質(シリカ)除去技術の開発ー排水中シリカ除去メカニズムの検討ー2014

    • Author(s)
      富田 洋平・平山 敦・山本 浩・鈴木 康夫・鈴木 慎哉・所 千晴
    • Organizer
      第25回廃棄物資源循環学会研究発表会
    • Place of Presentation
      広島
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸性抗廃水処理の将来予測を目的とした水酸化アルミニウムへのZnの表面錯体モデル構築2014

    • Author(s)
      榊原 泰祐・所 千晴・鈴木 慎哉
    • Organizer
      資源・素材2014(熊本)
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-14 – 2014-09-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Removal mechanism in anions co-precipitation process with hydroxides in AMD treatment2014

    • Author(s)
      C.Tokoro
    • Organizer
      The 12th Korean/Japan International Symposium on Resources Recycling and Materials Scinece
    • Place of Presentation
      Daejeon,Korea
    • Year and Date
      2014-04-17 – 2014-04-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 水酸化アルミニウム共沈法による希薄Si含有廃水からのSi除去のプロセス最適化を目的とした除去特性・温度影響の評価2014

    • Author(s)
      鈴木 慎哉・井澤 彩・所 千晴
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] XAFSによるFe(III)担持樹脂を用いた廃水からのAs(V)除去機構の解明2014

    • Author(s)
      二見 文也・井澤 彩・所 千晴
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] 鉱山廃水処理の効率化を目指した有害無機陰イオンの水酸化物共沈機構の解明2014

    • Author(s)
      所千晴
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] The role of surface complexation at the hydroxide/water interface in AMD treatment2014

    • Author(s)
      C. Tokoro
    • Organizer
      WATER DYNAMICS
    • Place of Presentation
      仙台
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Clarification for removal mechanism of Boron usingco-precipitation with magnesium hydroxide2013

    • Author(s)
      S.Izawa, C.Tokoro, K. Sasaki, F. Futami
    • Organizer
      ASEAN++ 2013 Moving Forward
    • Place of Presentation
      Thailand
    • Related Report
      2013 Research-status Report
  • [Presentation] 水酸化物アルミニウムによる希薄Si含有廃水処理における共沈法と吸着法の比較2013

    • Author(s)
      鈴木 慎哉・原口 大輔・所 千晴・井澤 彩・大和田 秀二
    • Organizer
      化学工学会 第45回秋季大会
    • Place of Presentation
      岡山
    • Related Report
      2013 Research-status Report
  • [Presentation] 国内におけるヒ素含有抗廃水処理の現状と展望2013

    • Author(s)
      所千晴
    • Organizer
      資源・素材学会 秋季大会
    • Place of Presentation
      北海道
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 汚染物質の不動化機構における表面錯体モデルの重要性2013

    • Author(s)
      所千晴
    • Organizer
      資源・素材学会 秋季大会
    • Place of Presentation
      北海道
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Investigation of Sorption Mechanism on Arsenic Co-Precipitation with Ferrihydrite for Quantitative Modelling of AMD Treatment2013

    • Author(s)
      C.Tokoro, D.Haraguchi, S.Izawa
    • Organizer
      European Metallurgical Conference 2013
    • Place of Presentation
      Germany
    • Related Report
      2013 Research-status Report
  • [Presentation] SORPTION MECHANISM OF DILUTE As(V) TO FERRIHYDRITE IN COPRECIPITATION OR ADSORPTION PROCESS IN AQUEOUS SOLUTION2012

    • Author(s)
      C.Tokoto,S.Izawa,D.Haraguchi,S.Owada
    • Organizer
      Water, air & Land: Sustainability Issues in Mineral & Metal Extraction in COM2012
    • Place of Presentation
      Ontario
    • Related Report
      2012 Research-status Report
  • [Presentation] 廃水中の希薄As(V)高度処理を目的とした水酸化物との共沈機構の解明2012

    • Author(s)
      所千晴・原口大輔・井澤彩
    • Organizer
      資源・素材2012秋田
    • Place of Presentation
      秋田
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 水酸化第二鉄によるAs(V)共沈除去機構の解明2012

    • Author(s)
      所千晴・原口大輔・井澤彩・大和田秀二
    • Organizer
      化学工学会 第44回秋季大会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] XRD and XAFS investigation for As(V) co-precipitation mechanism with ferrihydrite2012

    • Author(s)
      Chiharu.Tokoro, Sayaka.Izawa, Daisuke.Haraguchi and Shuji.Owada
    • Organizer
      The 10th Korea/Japan International Symposium on Resources Recycling and Materials Science
    • Place of Presentation
      Deajeon
    • Related Report
      2012 Research-status Report
  • [Presentation] Sorption mechanism of As(V) co-precipitation with ferric or aluminum hydroxide in solution2012

    • Author(s)
      Chiharu Tokoro, Daisuke Haraguchi, Sayaka Izawa AND Shuji Owada
    • Organizer
      第18回ヒ素シンポジウム
    • Place of Presentation
      宮崎
    • Related Report
      2012 Research-status Report
  • [Presentation] マグネシウム塩を用いた共沈法と吸着法の比較によるホウ素除去機構の解明2012

    • Author(s)
      井澤彩・原口大輔・所千晴
    • Organizer
      環境資源工学会大129回例会
    • Place of Presentation
      山口
    • Related Report
      2012 Research-status Report
  • [Presentation] 水酸化物による廃水中有害元素の共沈除去に対する定量モデル化2012

    • Author(s)
      原口大輔・井澤彩・所千晴・大和田秀二
    • Organizer
      資源・素材2012秋田
    • Place of Presentation
      秋田
    • Related Report
      2012 Research-status Report
  • [Presentation] XAFS investigation for sorption mechanism in As(V) coprecipitation with ferrihydrite2012

    • Author(s)
      SAYAKA IZAWA, CHIHARU TOKORO, YUJI ODA, DAISUKE HARAGUCHI, SHUJI OWADA
    • Organizer
      The 22nd V.M. Goldschmidt Conference
    • Place of Presentation
      Montreal
    • Related Report
      2012 Research-status Report
  • [Presentation] Spectrophotometric analysis for As(V) sorption mechanism in the aluminum hydroxide coprecipitation method2012

    • Author(s)
      Daisuke Haraguchi, Chiharu Tokoro, Shuji Owada
    • Organizer
      The 22nd V.M. Goldschmidt Conference
    • Place of Presentation
      Montreal
    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi