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Deveropment of analysis method to detect polution record of heavy metal in coral at polution site

Research Project

Project/Area Number 24651009
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionHiroshima University

Principal Investigator

OKUDA TETSUJI  広島大学, 環境安全センター, 助教 (60343290)

Co-Investigator(Kenkyū-buntansha) HAYAKAWA Shinjirou  広島大学, 工学研究科, 准教授 (80222222)
Co-Investigator(Renkei-kenkyūsha) NISHIJIMA Wataru  広島大学, 環境安全センター, 教授 (20243602)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords珊瑚 / 鉛 / 重金属 / 汚染 / 散乱X線 / 蛍光X線 / 定量分析 / 環境計測 / 蛍光X線分析 / 汚染履歴 / 河川水 / 蛍光X線分析 / 散乱X線
Research Abstract

In Dominican Republic, we could find and sample some corals survived from 2000 year in the mouth of river in which watershed areas had extensive lead pollution at around 2000. In addition, we analyzed lead concentration for two corals in captivity by the conventional methods, after one year cultivation with lead polluted artificial seawater of one week. It was found that three conventional methods has enough higher resolution (10 micro meter) but doesn't have sensibility to detect lead accumulated in environ.
Improvements in micro x-ray fluorescence analyzer were carried out to detect Ba L lines in coral under atmospheric condition. A special collimator was placed between a sample and the detector, and the interior of the collimator could be evacuated. The sensitivity for Mg and Ka line was gained more than 1000, and the present instrument can be applied to perform quantitative analysis of Fe in the light matrix down to several ppm levels.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (23 results)

All 2014 2013 2012

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (11 results) (of which Invited: 1 results) Book (4 results)

  • [Journal Article] Chemical Behavior of Sand Alternatives in the Marine Environment2014

    • Author(s)
      Tetsuji Okuda, Satoshi Asaoka, Hitomi Yano, Kouji Yoshitsugu, Satoshi Nakai, Wataru Nishijima, Kenji Sugimoto, Daijirou Matsunami, Yorihide Asaoka, Mitsumasa Okada
    • Journal Title

      Chemosphere

      Volume: (in press) Pages: 164-168

    • DOI

      10.1016/j.chemosphere.2014.03.075

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] SDD用真空コリメーターの開発と大気中での軽元素蛍光X線分析2014

    • Author(s)
      牧野泰希、吉岡剛志、百崎賢二郎、辻笑子、野口直樹、西脇芳典、橋本敬、本多定男、二宮利男、藤原明比古、高田昌樹、早川慎二郎
    • Journal Title

      X線分析の進歩

      Volume: 45 Pages: 317-325

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chlorophyll and suspended sediment mapping to the Caribbean Sea from rivers in the capital city of the Dominican Republic using ALOS AVNIR-2 data, Environmental Monitoring and Assessment2014

    • Author(s)
      Sakuno Y., Miño, E. R. A., Nakai, S., Mutsuda, M., Okuda, T., Nishijima, W., Castro, R., Garcia, A., Peña, R., Rodriguez, M., and Depratt, G. C.
    • Journal Title

      Published online

      Volume: onile Issue: 7 Pages: 4181-4193

    • DOI

      10.1007/s10661-014-3689-6

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact of flood events on macrobenthic community structure on an intertidal flat developing in the Ohta River Estuary2013

    • Author(s)
      Wataru Nishijima, Yoichi Nakano, Satoshi Nakai, Tetsuji Okuda, Tsuyoshi Imai, Mitsumasa Okada
    • Journal Title

      Marine Pollution Bulletin

      Volume: 4, 1 Issue: 1 Pages: 364-373

    • DOI

      10.1016/j.marpolbul.2013.06.028

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of fractional change of niobium ionic species in a solution by means of X-ray absorption fine structure spectroscopy2012

    • Author(s)
      Kubouchi, Y Hayakawa, S Namatame, H Hirokawa, T
    • Journal Title

      X-RAY SPECTROMETRY

      Volume: 41 Issue: 4 Pages: 259-263

    • DOI

      10.1002/xrs.2390

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Vertical profiles of Iodine-131 and Cesium-137 in soils in Fukushima Prefecture related to the Fukushima Daiichi Nuclear Power Station Accident2012

    • Author(s)
      Kazuya Tanaka, Yoshio Takahashi, Aya Sakaguchi, Miyuki Umeo, Shinjiro Hayakawa, Hajime Tanida and Takashi Saito
    • Journal Title

      Geochemical Journal

      Volume: 46 Pages: 73-76

    • NAID

      10030363817

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 単素子SDDを用いる蛍光XAFS測定系とカルシウム水溶液についてのK殻XAFS測定2012

    • Author(s)
      早川慎二郎、島本達也、野崎恭平、生天目博文、廣川健
    • Journal Title

      X線分析の進歩

      Volume: 43 Pages: 465-470

    • NAID

      40019263979

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhanced heavy metal immobilization in soil by grinding with addition of nanometallic Ca/CaO dispersion mixture2012

    • Author(s)
      Srinivasa Reddy Mallampati, Yoshiharu Mitoma, Tetsuji Okuda, Shogo Sakita, Mitsunori Kakeda
    • Journal Title

      Chemosphere

      Volume: 89, 6 Pages: 717-723

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Effect of steelmaking slag on marinebenthos2013

    • Author(s)
      Akiyama Y, Yano H, Katayama T, Okuda T, Nakai S, Nishijima W
    • Organizer
      EMECS10-MEDCOAST2013 Joint Conference. No 42
    • Place of Presentation
      Marmaris, Turkey
    • Related Report
      2013 Final Research Report
  • [Presentation] Impact of steel slag on benthic community under semi-artificial environment2013

    • Author(s)
      Akiyama Y, Yano H, Katayama T, Koba K, Nagao M, Okuda T, Nakai S, Tanimoto T, Yamamoto T, Nishijima W
    • Organizer
      ISWA World Congress Vienna 2013. No 3
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2013 Final Research Report
  • [Presentation] Novel approach for the extraction and immobilization of radioactive cesium from contaminated fly ash with nanometallic Ca/CaO methanol suspension2013

    • Author(s)
      Srinivasa Reddy Mallampati, Tetsuji Okuda, Yoshiharu Mitoma, Shogo Sakita, Mitsunori Kakeda
    • Organizer
      3rd International Conference on Nanotek & Expo
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Contribution of Ozone on the Inactivation of a Plankton in Ballast Water2013

    • Author(s)
      Tetsuji Okuda, Nobuhiko Yanai, Satoshi Nakai, Wataru Nishijima, Yukihiko Tsutsumi
    • Organizer
      IOA & IUVA 2013 World Congress
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Impact of steel slag on2013

    • Author(s)
      Akiyama YB, Yano H, Katayama T, Koba K, Nagao M, Okuda T, Nakai S,
    • Organizer
      ISWA World Congress
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of steelmaking slag on marinebenthos.2013

    • Author(s)
      Akiyama Y, Yano H, Katayama T, Okuda T, Nakai S, Nishijima W
    • Organizer
      EMECS10-MEDCOAST2013 Joint Conference
    • Place of Presentation
      Marmaris, Turkey
    • Related Report
      2013 Annual Research Report
  • [Presentation] 宝石サンゴの顕微蛍光X線分析とSr含有量に関する考察2012

    • Author(s)
      早川慎二郎
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Evaluation of Steel Slag as an Alternative Material of Sand for Coastal Ecosystem Creation2012

    • Author(s)
      Wataru Nishijima, Hitomi Yano, Satoshi Asaoka, Tetsuji Okuda, Satoshi Nakai and Mitsumasa Okada
    • Organizer
      2012 ISWA World Solid Waste, P.8
    • Place of Presentation
      Florence, Italy
    • Related Report
      2013 Final Research Report
  • [Presentation] SIMULATION OF CHLOROPHYLL-A ESTIMATION BY WORLDVIEW-2 IN THE URBAN RIVERS OF THE DOMINICAN REPUBLIC USING FIELD SPECTRAL DATA2012

    • Author(s)
      Yuji SAKUNO, Esteban R. MIÑO A., Satoshi NAKAI, Hidemi MUTSUDA, Tetsushi OKUDA, Wataru NISHIJIMA, Rolando CASTRO, Amarillis GARCÍA, Rosanna PEÑA, Marcos RODRIGUEZ, Conrado DEPRATT, G
    • Organizer
      The 33rd Asian Conference On Remote Sensing
    • Place of Presentation
      Pattaya, Thailand
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] 宝石サンゴの顕微蛍光X線分析とSr含有量に関する考察2012

    • Author(s)
      早川 慎二郎
    • Organizer
      日本分析化学会 第61年会
    • Place of Presentation
      金沢大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Evaluation of Steel Slag as an Alternative Material of Sand for Coastal Ecosystem Creation2012

    • Author(s)
      Wataru Nishijima, Hitomi Yano, Satoshi Asaoka, Tetsuji Okuda, Satoshi Nakai and Mitsumasa Okada
    • Organizer
      2012 ISWA World Solid Waste
    • Place of Presentation
      Florence, Italy
    • Related Report
      2012 Research-status Report
  • [Book] CSJ Current Review 14放射光が拓く化学の現在と未来2014

    • Author(s)
      早川慎二郎(分担執筆)
    • Total Pages
      184
    • Publisher
      化学同人
    • Related Report
      2013 Final Research Report
  • [Book] 放射光が拓く化学の現在と未来2014

    • Author(s)
      早川慎二郎
    • Total Pages
      184
    • Publisher
      化学同人
    • Related Report
      2013 Annual Research Report
  • [Book] 薄膜の評価技術ハンドブック2013

    • Author(s)
      早川慎二郎(分担執筆)
    • Total Pages
      648
    • Publisher
      テクノシステム
    • Related Report
      2013 Final Research Report
  • [Book] 薄膜の評価技術ハンドブック2013

    • Author(s)
      早川 慎二郎 他
    • Total Pages
      620
    • Publisher
      テクノシステム
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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