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Innovative purivication of silicon using liquid phase migration in solid silicon

Research Project

Project/Area Number 24656455
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Metal making engineering
Research InstitutionThe University of Tokyo

Principal Investigator

YOSHIKAWA Takeshi  東京大学, 生産技術研究所, 准教授 (90435933)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords太陽電池用シリコン / マイグレーション / 不純物液相
Research Abstract

To develop the innovative solar cell silicon production, we conducted the following fundamental investigation on the liquid phase migration technique to selectively extract the impurity-concentrated phases in solid silicon.
Thermodynamic analysis was carried out to clarify the purification effect of the migration process, and revealed the decrease the contents of impurity elements excluding P, B, Al and Fe to below 1 ppmw.
Then, silicon sample was subjected to the heat treatment at 1523-1623 K under the temperature gradient. The migration velocity was increased by increasing temperature, and attained 50 µm/min at 1623 K. We found the sufficiently high migration velocity for purification process.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2013 2012 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (5 results)

  • [Journal Article] Purification of Silicon by Using the Liquid Migration Technique under Temperature Gradient2013

    • Author(s)
      Kunitoshi Matsunaga, Takeshi Yoshikawa, Kazuki Morita
    • Journal Title

      Materials Science Forum

      Volume: 750 Pages: 240-243

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 固体Si中不純物液相のマイグレーション挙動の調査2013

    • Author(s)
      松永邦俊, 吉川健, 森田一樹
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2013-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Solar Grade Silicon Purification Using Liquid Phase Migration Technique2013

    • Author(s)
      Kunitoshi Matsunaga, Takeshi Yoshikawa, Kazuki Morita
    • Organizer
      TMS annual meeting, Solar Cell Silicon
    • Place of Presentation
      San Antonio
    • Year and Date
      2013-03-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Purification of Silicon by Using the Liquid Migration Technique under Temperature Gradient2012

    • Author(s)
      Kunitoshi Matsunaga, Takeshi Yoshikawa, Kazuki Morita
    • Organizer
      8th International Forum on Advanced Materials Science and Technology
    • Place of Presentation
      福岡工業大学
    • Year and Date
      2012-08-03
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] Solar Grade Silicon Purification Using Liquid Phase Migration Technique

    • Author(s)
      Kunitoshi Matsunaga, Takeshi Yoshikawa, Kazuki Morita
    • Organizer
      TMS annual meeting, Solar Cell Silicon
    • Place of Presentation
      San Antonio, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] 固体Si中不純物液相のマイグレーション挙動の調査

    • Author(s)
      松永 邦俊, 吉川 健, 森田 一樹
    • Organizer
      日本金属学会
    • Place of Presentation
      東京理科大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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