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Basic Study on Molybdenum Isotope Effects in Oxidation-Reduction Reactions and Molybdenum Isotope Separations

Research Project

Project/Area Number 24656567
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nuclear engineering
Research InstitutionNagaoka University of Technology

Principal Investigator

SUZUKI Tatsuya  長岡技術科学大学, 工学(系)研究科(研究院), 教授 (70323839)

Co-Investigator(Renkei-kenkyūsha) ASANUMA Noriko  東海大学, 工学部, 准教授 (70439660)
NOMURA Masao  東京工業大学, 原子炉工学研究所, 助教 (60100997)
Research Collaborator TACHIBANA Yu  長岡技術科学大学, 大学院工学研究科, 助教 (40634928)
INAKI Masafumi  
YAMASAKI Yuki  
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords同位体効果 / 同位体分離 / モリブデン同位体 / テクネチウム / イオン交換 / 核医学診断 / 原子力応用
Outline of Final Research Achievements

Basic study on molybdenum isotope separation by isotope fractionation effect in isotope exchange reaction among several molybdenum chemical species in hydrochloric acid solution was carried out. In addition, we studied a molybdenum isotope separation by oxidation-reduction reactions, because the isotope fractionation effects in oxidation-reduction reactions is expected to be high in general. In the present study, we started by obtaining the basic data; distribution coefficients of molybdenum on anion exchange resin, the fractionation of molybdenum chemical species, the searching the reductant from molybdenum(VI) to (V), etc. Unfortunately, we cannot found the high isotope fractionation effects in oxidation-reduction reactions. However, we found the isotope fractionation by anion exchange based on the isotope exchange reaction among several molybdenum chemical species in hydrochloric acid solution, and suggested that this fractionation is due to the mass effect of molecular vibration.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (5 results)

All 2015 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (4 results)

  • [Journal Article] Molybdenum isotope fractionation in ion exchange reaction by using anion exchange chromatography2015

    • Author(s)
      Yu Tachibana, Yuki Yamazaki, Masao Nomura, Tatsuya Suzuki
    • Journal Title

      Journal of Radioanalytical and Nuclear Chemistry

      Volume: 303 Issue: 2 Pages: 1429-1434

    • DOI

      10.1007/s10967-014-3510-6

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Molybdenum Isotope Fractionation in Ion Exchange Reaction by Using Anion Exchange Chromatography2013

    • Author(s)
      Yu Tachibana, Yuki Yamazaki, Masao Nomura, Tatsuya Suzuki
    • Organizer
      The 5th Asia-Pacific Symposium on Radiochemistry '13 (APSORC13)
    • Place of Presentation
      Kanazawa, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Masafumi Inaki, Yu Tachibana, Masao Nomura, Tatsuya Suzuki2013

    • Author(s)
      Adsorption behavior of molybdenum species on benzimidazole-type resin in hydrochloric acid solutions
    • Organizer
      The 2nd International Gigaku Conference in Nagaoka
    • Place of Presentation
      Nagaoka University of Technology, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] クロマトグラフィー法を用いたMo(VI)化学種の同位体比変動に関する基礎的研究

    • Author(s)
      立花優,山﨑祐希,野村雅夫,鈴木達也
    • Organizer
      第12回同位体科学研究会
    • Place of Presentation
      産業技術総合研究所臨海副都心センター
    • Related Report
      2013 Research-status Report
  • [Presentation] 塩酸水溶液中における多孔質シリカ担持ベンゾイミダゾリウム型イオン交換樹脂に対するMo(VI)及びMo(V)化学種吸着挙動に関する基礎的研究

    • Author(s)
      稲木雅文、立花優、鈴木達也、野村雅夫
    • Organizer
      日本イオン交換学会年会・第28回日本イオン交換研究発表会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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