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Development of Chemoselective Carbon-Carbon Bond Formation Reactions Directed toward Synthesis of Functional Molecules

Research Project

Project/Area Number 24685015
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Synthetic chemistry
Research InstitutionHokkaido University

Principal Investigator

OHMIYA Hirohisa  北海道大学, 理学(系)研究科(研究院), 准教授 (40508876)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥26,130,000 (Direct Cost: ¥20,100,000、Indirect Cost: ¥6,030,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Keywords銅触媒 / 不斉合成 / 有機ホウ素化合物 / C-H官能基化 / アリル化 / 有機分子触媒 / 不斉反応 / 機能分子合成 / 炭素-炭素結合形成 / 化学選択性 / 遷移金属触媒 / アリル位置換反応 / 共役付加反応 / 光学活性化合物
Outline of Final Research Achievements

The researcher developed unprecedented synthetic reactions based on the catalyst design focusing on a characteristic feature of copper that is relatively resistant to oxidation state change. Specifically, he developed new types of highly selective carbon-carbon bond formation reactions of organoboron compounds with copper catalyst systems. This research has been expanded to catalytic enantioselective carbon-carbon bond formation reactions. The focus of the research has shifted to catalytic C-H functionalization for stereoselective carbon-carbon bond formation reactions. The achievement has pioneered the potential of copper chemistry, and established new designing concepts of copper catalysis.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (76 results)

All 2015 2014 2013 2012 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results,  Acknowledgement Compliant: 5 results) Presentation (55 results) (of which Invited: 11 results) Remarks (3 results)

  • [Journal Article] Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis2015

    • Author(s)
      長尾一哲、大宮寛久、澤村正也
    • Journal Title

      Organic Letter

      Volume: 17 Issue: 5 Pages: 1304-1307

    • DOI

      10.1021/acs.orglett.5b00305

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes2014

    • Author(s)
      Kentaro Hojoh, Yoshinori Shido, Hirohisa Ohmiya, Masaya Sawamura
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 53 Issue: 19 Pages: 4954-4958

    • DOI

      10.1002/anie.201402386

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes2014

    • Author(s)
      長尾一哲、大宮寛久、澤村正也
    • Journal Title

      Journal of American Chemical Society

      Volume: 136 Issue: 30 Pages: 10605-10608

    • DOI

      10.1021/ja506310v

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles2014

    • Author(s)
      Ayumi Harada, Yusuke Makida, Tatsunori Sato, Hirohisa Ohmiya, Masaya Sawamura
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Pages: 13932-13939

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes2014

    • Author(s)
      Hirohisa Ohmiya, Masaya Sawamura
    • Journal Title

      J. Synth. Org. Chem. Jpn.

      Volume: 72 Pages: 1207-1217

    • NAID

      130004749119

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes2013

    • Author(s)
      Yusuke Makida. Yurie Takayama, Hirohisa Ohmiya, Masaya Sawamura
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 52 Issue: 20 Pages: 5350-5354

    • DOI

      10.1002/anie.201300785

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative Catalysis of Metal and O-H-O/sp3-C-H-O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes2013

    • Author(s)
      Takaoki Ishii, Ryo Watanabe, Toshimitsu Moriya, Hirohisa Ohmiya, Seiji Mori, Masaya Sawamura
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Issue: 40 Pages: 13547-13553

    • DOI

      10.1002/chem.201301280

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.2013

    • Author(s)
      若松鷹道、長尾一哲、大宮寛久、澤村正也
    • Journal Title

      Angewandte Chemie Internationl Edition

      Volume: 52 Issue: 44 Pages: 11620-11623

    • DOI

      10.1002/anie.201305973

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Preparation of β-Branched γ, δ-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal2012

    • Author(s)
      Dong Li, Hirohisa Ohmiya, Masaya Sawamura
    • Journal Title

      Synthesis (PSP article)

      Volume: 44 Issue: 09 Pages: 1304-1307

    • DOI

      10.1055/s-0031-1289712

    • NAID

      120005228671

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.2012

    • Author(s)
      Mingyu Yang
    • Journal Title

      Org. Lett.

      Volume: 14 Pages: 816-819

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation2012

    • Author(s)
      槇田祐輔、大宮寛久、澤村正也
    • Journal Title

      Angewandte Chemie

      Volume: 51 Issue: 17 Pages: 4122-4127

    • DOI

      10.1002/anie.201200809

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed g-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes2012

    • Author(s)
      Kazunori Nagao
    • Journal Title

      Synthesis

      Volume: 44(in press) Issue: 10 Pages: 1535-1541

    • DOI

      10.1055/s-0031-1290818

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible 1,3-anti/syn-Stereochemical Courses in Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Chiral Allylic phosphates and Alkyl borans2012

    • Author(s)
      長尾一哲
    • Journal Title

      Journal of The American Chemical Society

      Volume: 134 Issue: 21 Pages: 8982-8987

    • DOI

      10.1021/ja302520h

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper-N-Heterocyclic Carbene Complex.2012

    • Author(s)
      Mika Yoshida
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 29 Pages: 11896-11899

    • DOI

      10.1021/ja304481a

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Allenylsilanes through Copper-Catalyzed γ-Selective Coupling between γ-Silylated Propargylic Phosphates and Alkylboranes.2012

    • Author(s)
      Umi Yokobori
    • Journal Title

      Organometallies

      Volume: 31 Issue: 22 Pages: 7909-7913

    • DOI

      10.1021/om300552f

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rh-Catalyzed Borylation of N-Adjacent C(sp^3)-H Bonds with a Silica-Supported Triarylphosphine Ligands2012

    • Author(s)
      Soichiro Kawamorita, Tatsuya Miyazaki, Tomohiro Iwai, Hirohisa Ohmiya, Masaya, Sawamura.
    • Journal Title

      J.Am. Chem. Soc.

      Volume: 134 Issue: 31 Pages: 12924-12927

    • DOI

      10.1021/ja305694r

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conjugate Reduction of a,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact phosphane-Copper Complex2012

    • Author(s)
      川守田 創一郎
    • Journal Title

      Advanced Synthesis & Catalysis

      Volume: 354 Issue: 18 Pages: 3440-3444

    • DOI

      10.1002/adsc.201200555

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.2012

    • Author(s)
      Yoshinori Shido
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 134 Issue: 45 Pages: 18573-18576

    • DOI

      10.1021/ja3093955

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Construction of Quaternary Stereogenic Carbon Centers through Copper-catalyzed Enantioselective Direct Allylic Alkylation of Heteroarenes2015

    • Author(s)
      Heng Zhang, Ayumi Harada, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部 船橋キャンパス (船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 銅(I)触媒と分子状水素によるアルキンの水素化反応2015

    • Author(s)
      若松鷹道, 大宮寛久, 澤村正也
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部 船橋キャンパス (船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Anti-selective Carboboration, Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis2015

    • Author(s)
      Kazunori Nagao, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部 船橋キャンパス (船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Copper-Catalyzed γ-Selective and Stereospecific Coupling between Secondary Allylic Phosphates and Secondary Alkylboranes2014

    • Author(s)
      Yuto Yasuda, Kazunori Nagao, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      第2回国際シンポジウム “Ambition Across the Disciplines"
    • Place of Presentation
      Hokkaido University (Sapporo)
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Phosphine-Catalyzed Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes2014

    • Author(s)
      Kazunori Nagao, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      The 4th Junior International Conference on Cutting-Edge Organic Chemistry in Asia 2014 (JICCEOCA-4)
    • Place of Presentation
      Chulabhorn Research Institute (CRI) and Chulabhorn Graduate Institute (CGI) (Thailand)
    • Year and Date
      2014-11-28 – 2014-12-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 銅触媒の機能化に基づく高選択的有機合成反応の開発2014

    • Author(s)
      大宮 寛久
    • Organizer
      2014年度 創薬科学フロンティアシンポジウム
    • Place of Presentation
      京都薬科大学 (京都市)
    • Year and Date
      2014-11-22 – 2014-11-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Phosphine-Catalyzed Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes2014

    • Author(s)
      Hirohisa Ohmiya
    • Organizer
      Vietnam Malaysia International Chemical Congress (VMICC)
    • Place of Presentation
      Daewoo Hotel Hanoi (Vietnam)
    • Year and Date
      2014-11-07 – 2014-11-09
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkynes2014

    • Author(s)
      Hirohisa Ohmiya
    • Organizer
      18th Malaysian International Chemical Congress (18MICC)
    • Place of Presentation
      Putra World Trade Centre (Malaysia)
    • Year and Date
      2014-11-03 – 2014-11-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] アルキルボランと第1級塩化アリル類のエナンチオ選択的銅触媒カップリングによる第四級不斉炭素中心の構築2014

    • Author(s)
      北條 健太郎, 志渡 義教, 大宮 寛久, 澤村 正也
    • Organizer
      CSJ 化学フェスタ2014
    • Place of Presentation
      タワーホール船橋 (東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 第2級アルキルボランとリン酸アリルのγ位選択的立体特異的銅触媒カップリング反応2014

    • Author(s)
      安田 優人, 長尾 一哲, 大宮 寛久, 澤村 正也
    • Organizer
      CSJ 化学フェスタ2014
    • Place of Presentation
      タワーホール船橋 (東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 銅(I)触媒を用いた末端アルケンの分子内ヒドロアルコキシ化反応2014

    • Author(s)
      村山 大明, 長尾 一哲, 大宮 寛久, 澤村 正也
    • Organizer
      CSJ 化学フェスタ2014
    • Place of Presentation
      タワーホール船橋 (東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機ボランによるアルキノエートのホスフィン触媒カルボホウ素化反応2014

    • Author(s)
      長尾 一哲, 大宮 寛久, 澤村 正也
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学医学部 百年講堂(福岡市)
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 第2級アルキルボランとリン酸アリルのγ位選択的立体特異的銅触媒クロスカップリング反応2014

    • Author(s)
      安田 優人, 長尾 一哲, 大宮 寛久, 澤村 正也
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学医学部 百年講堂(福岡市)
    • Year and Date
      2014-09-23 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 銅触媒の機能化による高選択的有機合成反応の開発2014

    • Author(s)
      大宮 寛久
    • Organizer
      平成26年度第1回有機金属若手研究者の会
    • Place of Presentation
      九州大学 馬出キャンパス(福岡市)
    • Year and Date
      2014-09-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 銅触媒の機能化による高選択的有機合成反応2014

    • Author(s)
      大宮 寛久
    • Organizer
      第47回有機金属若手の会 夏の学校
    • Place of Presentation
      休暇村 大久野島(竹原市)
    • Year and Date
      2014-09-01 – 2014-09-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes2014

    • Author(s)
      Hiroaki Murayama, Kazunori Nagao, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Royton Sapporo Hotel (Sapporo)
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Copper-Catalyzed γ-Selective and Stereospecific Coupling between Secondary Allylic Phosphates and Secondary Alkylboranes2014

    • Author(s)
      Yuto Yasuda, Kazunori Nagao, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Royton Sapporo Hotel (Sapporo)
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Copper-Catalyzed Stereodivergent Coupling Reactions between Chiral Allylic Phosphates and Alkylboranes2014

    • Author(s)
      Kazunori Nagao, Hirohisa Ohmiya, Seiji Mori, Masaya Sawamura
    • Organizer
      The 3rd Frontier Chemistry Center International Symposium “Challenges at the Frontier of Chemical Sciences”
    • Place of Presentation
      Hokkaido University (Sapporo)
    • Year and Date
      2014-06-13 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes2014

    • Author(s)
      Yurie Takayama, Yusuke Makida, Hirohisa Ohmiya, Masaya Sawamura
    • Organizer
      The 3rd Frontier Chemistry Center International Symposium “Challenges at the Frontier of Chemical Sciences”
    • Place of Presentation
      Hokkaido University (Sapporo)
    • Year and Date
      2014-06-13 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 銅触媒によるアルキルボラン/アルキノエート/求電子剤三成分カップリングを用いた多置換アルケンの合成2014

    • Author(s)
      若松 鷹道
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光学活性ヒドロキシアミノホスフィン-銅錯体触媒による α-ケトエステル誘導体のエナンチオ選択的アルキニル化反応2014

    • Author(s)
      石井 孝興
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルキルボランと第1級塩化アリル類のエナンチオ選択的銅触媒クロスカップリングによる第四級不斉炭素中心の構築2014

    • Author(s)
      北條 健太郎
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒によるアルキルボランのγ位選択的アリル化反応の機構解析2014

    • Author(s)
      長尾 一哲
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒による高選択的合成反応の開発2014

    • Author(s)
      大宮寛久
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 銅触媒による第2級アルキルボランとリン酸アリルのγ位選択的立体特異的カップリング反応2014

    • Author(s)
      安田 優人
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒による末端アルキンのエナンチオ選択的アリル位アルキル化反応2014

    • Author(s)
      大宮 寛久
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅(I)触媒による分子内アルケンヒドロアルコキシ化反応2014

    • Author(s)
      村山 大明
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of Highly-controlled Allylic Bond Formation Reactions2013

    • Author(s)
      Hirohisa Ohmiya
    • Organizer
      The 1st FCC International Symposium ~Next Generation of Molecular Chemistry~
    • Place of Presentation
      Hokkaido University (札幌市)(招待講演)
    • Year and Date
      2013-02-22
    • Related Report
      2012 Annual Research Report
  • [Presentation] Copper-Catalyzed Enantioselective Conjugate Addition andAllylic Substitution with Alkylboranes2013

    • Author(s)
      Hirohisa Ohmiya
    • Organizer
      OMCOS17
    • Place of Presentation
      Colorado State University(USA)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Copper-Catalyzed Stereodivergent Coupling Reactions between Chiral Allylic Phosphates and Alkylboranes2013

    • Author(s)
      Kazunori Nagao
    • Organizer
      OMCOS17
    • Place of Presentation
      Colorado State University(USA)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enantioselective Alkynylation of Aldehydes Based on Cooperative Catalysis of Copper-Chiral Hydroxy Amino Phosphine Complexes2013

    • Author(s)
      Takaoki Ishii
    • Organizer
      ISHHC-16
    • Place of Presentation
      Hokkaido University(Sapporo)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Copper(I)-Catalyzed Enantioselective Allylic Substitution Reaction with Alkylboranes2013

    • Author(s)
      Kentaro Hojoh
    • Organizer
      ISHHC-16
    • Place of Presentation
      Hokkaido University(Sapporo)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルキルボランと塩化アリル類のエナンチオ選択的銅触媒クロスカップリングによる第四級不斉炭素中心の構築2013

    • Author(s)
      北條 健太郎
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(豊島区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒によるアルキルボラン/アルキノエート/スズアルコキシドの三成分カップリングを用いた三置換ビニルスズ化合物の合成2013

    • Author(s)
      若松 鷹道
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(豊島区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enantioselective Conjugate Addition and Allylic Substitution with Alkylboranes Catalyzed by Copper(I) Complexes2013

    • Author(s)
      Hirohisa Ohmiya
    • Organizer
      ISCC-10
    • Place of Presentation
      Doshisha University(Kyoto)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] キラル銅触媒を用いる末端アルキンとニトロンからのβ-ラクタムの不斉合成2013

    • Author(s)
      石井 孝興
    • Organizer
      第43回複素環化学討論会
    • Place of Presentation
      長良川国際会議場(岐阜市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銅触媒による高選択的炭素骨格構築法の開発2013

    • Author(s)
      大宮 寛久
    • Organizer
      第2回卓越拠点有機若手ワークショップ
    • Place of Presentation
      京都大学(京都市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Hydrogen-bond-assisted Enantiocontrol of Copper-catalyzed Alkyne-Nitrone Coupling: Asymmetric Synthesis of β-Lactams2013

    • Author(s)
      Masaya Sawamura
    • Organizer
      ICCEOCA-8
    • Place of Presentation
      Osaka International Convention Center(Osaka)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 官能基化N-ヘテロサイクリックカルベン-銅錯体触媒による末端アルキンと第1級リン酸アリル類のγ位選択的カップリング反応2013

    • Author(s)
      槇田 祐輔
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒を用いたアルキルボラン、アルキノエート、求電子剤の3成分カップリング反応2013

    • Author(s)
      若松 鷹道
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒による2-ブテン-1,4-ジオール誘導体とアルキルボランの立体収束型アルキル化反応2013

    • Author(s)
      長尾 一哲
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒によるアルキルボランのエナンチオ選択的アリル位置換反応2013

    • Author(s)
      北條 健太郎
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(草津市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒によるキラルリン酸アリル類とアルキルボランの立体分岐型カップリング反応2012

    • Author(s)
      長尾一哲
    • Organizer
      第24回万有札幌シンポジウム
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2012-07-07
    • Related Report
      2012 Annual Research Report
  • [Presentation] REGIO- AND STEREOCONTROLLED INTRODUCTION OF SECONDARY ALKYL GROUPS TO ELECTRONDEFICIENT ARENES THROUGH COPPER-CATALYZED DIRECT ALLYLIC ALKYLATION2012

    • Author(s)
      Yusuke Makida
    • Organizer
      XXV International Conference on Organometallic Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] ENANTIOSELECTIVE ALKYNYLATION OF ALDEHYDES BASED ON COOPERATIVE CATALYSIS OF COPPER-CHIRAL HYDROXY AMINO PHOSPHINE COMPLEXES2012

    • Author(s)
      Takaoki Ishii
    • Organizer
      XXV International Conference on Organometallic Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] RH-CATALYZED DIRECT BORYLATION OF N-ADJACENT C(SP3)-H BONDS WITH SILICA-SUPPORTED CAGE-TYPE TRIARYL MONODENTATE PHOSPHINE LIGAND2012

    • Author(s)
      Soichiro Kawamorita
    • Organizer
      XXV International Conference on Organometallic Chemistry
    • Place of Presentation
      Lisbon, Portugal
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒によるアルキルボランのエナンチオ選択的共役付加とアリル化2012

    • Author(s)
      大宮寛久
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学(吹田市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒による末端アルキンのγ選択的立体特異的アリル化2012

    • Author(s)
      高山ゆりえ
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学(吹田市)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒とアルキルボランを用いるキラルリン酸アリル類の立体分岐型アルキル化反応2012

    • Author(s)
      長尾一哲
    • Organizer
      第102回有機合成シンポジウム
    • Place of Presentation
      早稲田大学国際会議場(東京都)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes2012

    • Author(s)
      Yurie Takayama
    • Organizer
      The Twelfth International Kyoto Conference on New Aspect of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel KYOTO (京都府)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 銅触媒によるアルキルホウ素化合物のリン酸アリル類の立体選択的カップリング反応

    • Author(s)
      長尾 一哲
    • Organizer
      第23回 万有福岡シンポジウム
    • Place of Presentation
      九州大学(福岡市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高選択的アリル系カップリング反応の開発と展開

    • Author(s)
      大宮 寛久
    • Organizer
      第7回日本化学会東海支部若手研究者フォーラム「分子科学のライジングスター」
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 不斉ヒドロキシアミノホスフィンー銅錯体の協同触媒作用に基づくβーラクタムの立体選択的合成

    • Author(s)
      石井 孝興
    • Organizer
      日本化学会北海道支部夏期研究発表会
    • Place of Presentation
      北見工業大学(北見市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] アリル型化合物のクロスカップリング反応

    • Author(s)
      大宮 寛久
    • Organizer
      第10回 北大若手研究者の会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 銅触媒による高選択的炭素骨格構築法の開発

    • Author(s)
      大宮 寛久
    • Organizer
      岡山大学次世代研究者・異分野研究連携育成支援事業シンポジウム 「遷移金属触媒が先導する新しい分子変換」
    • Place of Presentation
      岡山大学(岡山市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] 北海道大学大学院理学研究院化学部門 有機金属化学研究室

    • URL

      http://barato.sci.hokudai.ac.jp/~orgmet/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 北海道大学大学院理学研究院化学部門 有機金属化学研究室

    • URL

      http://wwwchem.sci.hokudai.ac.jp/~orgmet/

    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://wwwchem.sci.hokudai.ac.jp/~orgmet/

    • Related Report
      2012 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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