Development of Chemoselective Carbon-Carbon Bond Formation Reactions Directed toward Synthesis of Functional Molecules
| Project/Area Number |
24685015
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
OHMIYA Hirohisa 北海道大学, 理学(系)研究科(研究院), 准教授 (40508876)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥26,130,000 (Direct Cost: ¥20,100,000、Indirect Cost: ¥6,030,000)
Fiscal Year 2014: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
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| Keywords | 銅触媒 / 不斉合成 / 有機ホウ素化合物 / C-H官能基化 / アリル化 / 有機分子触媒 / 不斉反応 / 機能分子合成 / 炭素-炭素結合形成 / 化学選択性 / 遷移金属触媒 / アリル位置換反応 / 共役付加反応 / 光学活性化合物 |
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| Outline of Final Research Achievements |
The researcher developed unprecedented synthetic reactions based on the catalyst design focusing on a characteristic feature of copper that is relatively resistant to oxidation state change. Specifically, he developed new types of highly selective carbon-carbon bond formation reactions of organoboron compounds with copper catalyst systems. This research has been expanded to catalytic enantioselective carbon-carbon bond formation reactions. The focus of the research has shifted to catalytic C-H functionalization for stereoselective carbon-carbon bond formation reactions. The achievement has pioneered the potential of copper chemistry, and established new designing concepts of copper catalysis.
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Report
(4 results)
Research Products
(76 results)
