Synthesis of the heterogeneous catalyst and active control of the catalytic activity using a porous coordination polymers shows magnetic bistability
Project/Area Number |
24750060
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
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Research Institution | Saga University |
Principal Investigator |
YONEDA Ko 佐賀大学, 工学(系)研究科(研究院), 助教 (50622239)
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Project Period (FY) |
2012-04-01 – 2015-03-31
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Project Status |
Completed (Fiscal Year 2014)
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Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
Keywords | スピン転移 / ホスト-ゲスト / 磁気的双安定性 / 光照射 / 反応制御 |
Outline of Final Research Achievements |
This study was subjected to molecular recognition and controlled release of the reaction substrate using a porous coordination polymer showing a magnetic bistability at room temperature. Moreover, attempts to synthesize new complexes using a complex ligand containing a catalytic active porphyrins, aimed at active control of the catalytic activity which is based on the electronic state control by spin state of host framework.
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Report
(4 results)
Research Products
(5 results)
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[Journal Article] Guest Modulation of Spin Crossover Transition Temperature in a Porous FeII Metal-Organic Framework: Experimental and Periodic DFT Studies2014
Author(s)
Daniel Aravena, Zulema Arcís Castillo, M. Carmen Muñoz, Ana B. Gaspar, Ko Yoneda, Ryo Ohtani, Akio Mishima, Susumu Kitagawa, Masaaki Ohba, José Antonio Real, Eliseo Ruiz
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Journal Title
Chem -Eur J.
Volume: 20
Issue: 40
Pages: 12864-12873
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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