| Project/Area Number |
24750099
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Polymer chemistry
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
YAMASHITA Ken (ALBRECHT Ken) 東京工業大学, 資源化学研究所, 助教 (50599561)
|
|---|
| Project Period (FY) |
2012-04-01 – 2014-03-31
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
|
|---|
| Keywords | デンドリマー / カルバゾール / ベンゾチアジアゾール / ドナー・アクセプタ－連結系 / ドナー・アクセプター連結形 / ドナー・アクセプター構造 / ポテンシャルプログラミング |
|---|
| Research Abstract |
Photoinduced charge transfer between donor and acceptor molecules is an important phenomenon, and several donor-acceptor linked systems are studied. However, dendritic systems with a donor-acceptor dyad as a repeating unit was not well studied. Carbazole and benzothiadiazole was chosen to construct this system, and the synthesis approach was established. The UV-vis absorption and fluorescence spectra were measured. Additionally, the encapsulation of fullerene (acceptor) into a donor-type dendrimer (carbazole-phenylazomethine dendrimer with zinc porphyrin core) was studied, and a new donor-acceptor system was developed.
|
