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Synthesis of carbon quantum dots in green solvents and evaluation of optical properties by means of spectromicroscopy

Research Project

Project/Area Number 24760630
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionKanazawa University

Principal Investigator

HIEJIMA Yusuke  金沢大学, 自然システム学系, 助教 (10415789)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsカーボンドット / 発光材料 / ナノカーボン / 分光分析 / 環境低負荷溶媒 / 分光計測
Research Abstract

Carbon dots were synthesized with various methods, and observed with a Raman microscope. It was found that the crude products were inhomogeneous, and the D-band and the G-band were observed in the non-luminescent portion. The sample damage due to the irradiation of the excitation laser was fatal for detailed observation.
We have developed a new method of synthesis, where the pyrolysis was conducted in the droplets generated by a pair of electrosprays. The new method enable us to control the reaction more effectively than the conventional method of pyrolysis. We have found that various parameters to control the droplet size were useful to improve the yields and to control the optical properties of the products.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (13 results)

All 2014 2013 Other

All Presentation (11 results) (of which Invited: 2 results) Patent(Industrial Property Rights) (2 results)

  • [Presentation] エレクトロスプレーによるマイクロ反応場を利用した発光性ナノカーボンの反応制御2014

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大
    • Related Report
      2013 Final Research Report
  • [Presentation] エレクトロスプレーによるマイクロ反応場を利用した発光性ナノカーボンの反応制御2014

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 溶液およびマイクロ液滴を利用した発光性ナノカーボンの合成2013

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      第36回溶液化学シンポジウム・プレシンポジウム
    • Place of Presentation
      北海道大
    • Year and Date
      2013-10-08
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] エレクトロスプレーマイクロリアクターを利用した発光性ナノカーボンの合成と反応制御2013

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      第36回溶液化学シンポジウム
    • Place of Presentation
      北海道大
    • Related Report
      2013 Final Research Report
  • [Presentation] Synthesis of Carbon Dots by Means of Double Electrospray Microreactor2013

    • Author(s)
      Y. Hiejima, K. H-. Nitta, M. Kanakubo and A. Wakisaka
    • Organizer
      33rd. International Conference on Solution Chemistry
    • Place of Presentation
      京都テルサ(京都市)
    • Related Report
      2013 Final Research Report
  • [Presentation] エレクトロスプレーによるマイクロ反応場を利用したカーボンドットの合成2013

    • Author(s)
      比江嶋祐介,金久保光央,脇坂昭弘
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大
    • Related Report
      2013 Final Research Report
  • [Presentation] エレクトロスプレーマイクロリアクターを利用した発光性ナノカーボンの合成と反応制御2013

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      第36回溶液化学シンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of Carbon Dots by Means of Double Electrospray Microreactor2013

    • Author(s)
      Y. Hiejima, K. H-. Nitta, M. Kanakubo and A. Wakisaka
    • Organizer
      33rd. International Conference on Solution Chemistry
    • Place of Presentation
      京都テルサ
    • Related Report
      2013 Annual Research Report
  • [Presentation] エレクトロスプレーによるマイクロ反応場を利用したカーボンドットの合成2013

    • Author(s)
      比江嶋祐介、金久保光弘、脇坂昭弘
    • Organizer
      化学工学会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of Carbon Dots by Means of Double Electrospray Microreactor2013

    • Author(s)
      Y. Hiejima, K. Nitta, M. Kanakubo and A. Wakisaka
    • Organizer
      33th International Conference of Solution Chemistry
    • Place of Presentation
      京都テルサ(京都市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 溶液およびマイクロ液滴を利用した発光性ナノカーボンの合成

    • Author(s)
      比江嶋祐介,新田晃平,金久保光央,脇坂昭弘
    • Organizer
      第36回溶液化学シンポジウム・プレシンポジウム
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Patent(Industrial Property Rights)] 発光性ナノカーボン製造方法および製 造装置2014

    • Inventor(s)
      比江嶋祐介,脇坂昭弘,金久保光央
    • Industrial Property Rights Holder
      比江嶋祐介,脇坂昭弘,金久保光央
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-053564
    • Filing Date
      2014-03-17
    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] 発光性ナノカーボン製造方法および製造装置2014

    • Inventor(s)
      比江嶋祐介、脇坂昭弘、金久保光央
    • Industrial Property Rights Holder
      比江嶋祐介、脇坂昭弘、金久保光央
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-053564
    • Filing Date
      2014
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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