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Catalytic conversion of lignin-related compounds into useful chemicals

Research Project

Project/Area Number 24760633
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionEhime University

Principal Investigator

HIDETOSHI Ohta  愛媛大学, 理工学研究科, 助教 (90532094)

Research Collaborator FUKUOKA Atsushi  北海道大学, 触媒化学研究センター, 教授 (80189927)
KOBAYASHI Hirokazu  北海道大学, 触媒化学研究センター, 助教 (30545968)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywordsリグニン / フェノール / アルキルベンゼン / 水素化脱酸素 / 白金触媒 / ジルコニア / 水中反応 / 選択的分子変換 / 白金 / レニウム / 芳香族合成 / 触媒 / バイオマス / 資源
Research Abstract

Alkylbenznes are industrially important feedstocks for producing pharmaceuticals, plastics, and organic EL devices etc. However, they are currently obtained from non-renewable petroleum. Biomass lignin is an abundant natural aromatic polymer and considered as a promising renewable resource of alkylbenzenes. In this research, we developed zirconia-supported Pt-Re catalysts for the hydrodeoxygenation of lignin-related phenols in water to give alkylbenzene in excellent yield and selectivity.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (4 results)

  • [Journal Article] Selective hydrodeoxygenation of lignin-related 4-propylphenol into n-propylbenzene in water by Pt-Re/ZrO2 catalysts2014

    • Author(s)
      Hidetoshi Ohta, Bo Feng, Hirokazu Kobayashi, Kenji Hara, Atsushi Fukuoka
    • Journal Title

      Catalysis Today

      Volume: 印刷中 Pages: 139-144

    • DOI

      10.1016/j.cattod.2014.01.022

    • NAID

      120005468152

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective hydrodeoxygenation of lignin-related 4-propylphenol into n-propylbenzene in water by Pt-Re/ZrO_2 catalysts

    • Author(s)
      Hidetoshi Ohta, Bo Feng, Hirokazu Kobayashi, Kenji Hara, Atsushi Fukuoka
    • Journal Title

      Catalysis Today

      Volume: (印刷中)

    • URL

      http://www.sciencedirect.com/science/article/pii/S0920586114000571

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] Selective hydrodeoxygenation of phenols in water by supported Pt-based catalysts2013

    • Author(s)
      Hidetoshi Ohta, Bo Feng, Hirokazu Kobayashi, Kenji Hara, Atsushi Fukuoka
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials, O-04
    • Place of Presentation
      Matsuyama, Japan
    • Year and Date
      2013-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] Selective hydrodeoxygenation of phenols in water by supported Pt-based catalysts2013

    • Author(s)
      Hidetoshi Ohta, Bo Feng, Hirokazu Kobayashi, Kenji Hara, and Atsushi Fukuoka
    • Organizer
      The 6th Japan-China Workshop on Environmental Catalysis and Eco-Materials, Ehime University, Matsuyama, Japan
    • Place of Presentation
      Ehime University
    • Related Report
      2013 Annual Research Report
  • [Presentation] Hydrodeoxygenation of Lignin- Related Compounds by Supported Platinum Catalysts2012

    • Author(s)
      Hidetoshi Ohta, Hirokazu Kobayashi, Kenji Hara, Atsushi Fukuoka
    • Organizer
      15th International Congress on Catalysis 2012, No. 2.04_7380
    • Place of Presentation
      Munich, Germany
    • Year and Date
      2012-07-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Hydrodeoxygenation of Lignin-Related Compounds by Supported Platinum Catalysts2012

    • Author(s)
      Hidetoshi Ohta
    • Organizer
      15th International Congress on Catalysis 2012
    • Place of Presentation
      Munich (Germany)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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